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To improve the hardness and wear properties of titanium alloy, TiB, TiC and B4C multi-ceramic phases reinforced titanium matrix composite (TMC) coatings were successfully prepared by laser cladding using Ti6Al4V and B4C mixed powders as raw materials. The effects of B4C content (3, 6, 7 and 9 wt.%) on the phase composition, microstructure, hardness and wear properties of the TMC coatings were systematically investigated. The results showed that the TMC coating was mainly composed of in-situ synthesized TiB and TiC reinforcements, retained B4C and α-Ti matrix. The sizes and quantities of the in-situ synthesized TiB and TiC reinforcements increased with increasing B4C content, and TiB/TiC intergrowth structures composed of TiC dendrites and TiB hollow prisms were observed in the coatings with a B4C content exceeding 7 %. In addition, the calculated two-dimensional lattice matching at the (111)TiB//(101)TiC interface was only 4.97 %, which improved the interfacial stability of the TiB/TiC intergrowth structure. The Rockwell hardness and microhardness of the TMC coatings increased with increasing B4C content, and nanoindentation tests demonstrated that the nano-hardness and elastic modulus of retained B4C, TiB/TiC intergrowth structures, primary TiB, and TiBw or TiCp eutectic regions were higher than those of the coating matrix and Ti6Al4V substrate in turn. The four TMC coatings exhibited elevated wear resistance, with abrasive wear identified as the dominant wear mechanism, and the superior wear resistance of the C7 and C9 TMC coatings was primarily attributable to the load transfer strengthening effect of the TiB/TiC intergrowth structure, primary TiB and retained B4C. © 2024 Elsevier B.V.
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Surface and Coatings Technology
ISSN: 0257-8972
Year: 2025
Volume: 496
5 . 4 0 0
JCR@2022
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 7
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