To　systematically　investigate　the　magnetic　anisotropy　of　NiFeMo　alloy　fabricated　via　Selective　Laser　Melting　(SLM)　and　to　elucidate　the　role　of　metallurgical　structure　on　its　magnetic　performance,　soft　magnetic　NiFeMo　alloy　specimens　were　synthesized　under　a　variety　of　conditions,　including　varying　substrate　preheating　temperatures,　laser　scanning　strategies,　and　tilting　angles.　The　microstructural　and　magnetic　characterizations　were　conducted　using　a　suite　of　analytical　techniques:　optical　microscopy　(OM),　microhardness　testing,　X-ray　diffraction　(XRD),　scanning　electron　microscopy　(SEM),　and　electron　backscatter　diffraction　(EBSD).　The　magnetization　curves　and　soft　magnetic　parameters　were　derived　utilizing　a　DC　measuring　instrument.　Our　findings　reveal　that　the　NiFeMo　alloy　is　predominantly　composed　of　the　γ-(Ni,　Fe)　phase,　with　grain　size,　boundary,　and　orientation　playing　pivotal　roles　in　determining　its　magnetic　performance.　At　a　substrate　preheating　temperature　of　160°C,　employing　an　island　rotation　strategy　of　67°　in　conjunction　with　a　30°　tilt　angle　for　the　fabrication　of　NiFeMo　alloy　specimens,　optimal　soft　magnetic　performance　was　achieved.　This　enhancement　in　performance　is　credited　to　the　reduced　temperature　gradient　and　cooling　rate　facilitated　by　substrate　preheating,　coupled　with　the　＜　111　＞　grain　orientation　induced　by　the　30°　tilt　angle.　Furthermore,　the　increase　in　large-angle　grain　boundaries,　a　consequence　of　substrate　preheating,　diminishes　the　resistance　to　domain　wall　motion,　thereby　further　enhancing　the　soft　magnetic　characteristics　of　the　specimens.　The　coercivity　(Hc)　of　these　specimens　was　measured　at　27.5　A/m,　which　is　notably　lower　than　that　of　conventional　processes　(390.13　A/m)　and　post-annealing　processes　following　Selective　Laser　Melting　(SLM)　(79　A/m).　Concurrently,　the　initial　magnetic　permeability　(μi)　of　the　specimens　reached　1.485　mH/m.　©　2025　Elsevier　B.V.