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Author：

Zhang, S. (Zhang, S..) | Chen, J. (Chen, J..) | Chen, W. (Chen, W..) | Su, Y. (Su, Y..) | Gou, Q. (Gou, Q..) | Yuan, R. (Yuan, R..) | Wang, Z. (Wang, Z..) | Wang, K. (Wang, K..) | Zhang, W. (Zhang, W..) | Hu, X. (Hu, X..) | Zhang, Z. (Zhang, Z..) | Wang, P. (Wang, P..) | Wan, F. (Wan, F..) | Liu, J. (Liu, J..) | Li, B. (Li, B..) | Wang, Y. (Wang, Y..) | Zheng, G. (Zheng, G..) | Li, M. (Li, M..) | Sun, J. (Sun, J..)

Indexed by：

EI Scopus

Abstract：

The　Zn　metal　anode　in　aqueous　zinc-ion　batteries　(AZIBs)　faces　daunting　challenges　including　undesired　water-induced　parasitic　reactions　and　sluggish　ion　migration　kinetics.　Herein,　we　develop　three-dimensional　covalent　organic　framework　(COF)　membranes　with　bioinspired　ion　channels　toward　stabilized　Zn　anodes.　These　COFs,　featured　by　zincophilic　pyridine-N　sites,　enable　effective　regulation　of　water　molecules　at　the　anode-electrolyte　interphase.　Systematic　experimental　analysis　and　theoretical　simulations　reveal　the　optimized　COF-320N　membrane　functions　as　ion　pumps,　accordingly　facilitating　Zn2+　transport　and　inhibiting　direct　contact　between　Zn　anode　and　free　water　molecules.　Consequently,　the　bio-inspired　strategy　achieves　improved　Zn2+　transference　number　(0.61),　rapid　de-solvation　kinetics,　and　suppressed　hydrogen　evolution.　The　assembled　Zn||MnO2　pouch　cell　integrated　with　COF-320N　membrane　exhibits　favorable　electrochemical　performances.　Such　a　bioinspired　concept　for　optimizing　Zn　anodes　opens　new　pathways　in　developing　advanced　energy　storage　devices.　©　2025　Wiley-VCH　GmbH.

Keyword：

Bioinspired Aqueous zinc-ion batteries Ion channel Water molecule regulation Covalent organic framework

Author Community：

  • [ 1 ] [Zhang S.]State Key Laboratory of Power Transmission Equipment Technology, School of Electrical Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 2 ] [Chen J.]Department of Mechanical Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, 999077, Hong Kong
  • [ 3 ] [Chen J.]College of Semiconductors (College of Integrated Circuits), Hunan University, Changsha, 410082, China
  • [ 4 ] [Chen W.]State Key Laboratory of Power Transmission Equipment Technology, School of Electrical Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 5 ] [Su Y.]Soochow Institute for Energy and Materials Innovation, Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, 215006, China
  • [ 6 ] [Su Y.]Department of Mechanical Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, 999077, Hong Kong
  • [ 7 ] [Gou Q.]School of Building Services Science and Engineering, Xi'an University of Architecture and Technology, Xi'an, 710055, China
  • [ 8 ] [Yuan R.]MOE Key Laboratory of Low-grade Energy Utilization Technologies and Systems, CQU-NUS Renewable Energy Materials & Devices Joint Laboratory, School of Energy and Power Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 9 ] [Wang Z.]State Key Laboratory of Power Transmission Equipment Technology, School of Electrical Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 10 ] [Wang K.]MOE Key Laboratory of Low-grade Energy Utilization Technologies and Systems, CQU-NUS Renewable Energy Materials & Devices Joint Laboratory, School of Energy and Power Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 11 ] [Zhang W.]State Key Laboratory of Power Transmission Equipment Technology, School of Electrical Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 12 ] [Hu X.]State Key Laboratory of Power Transmission Equipment Technology, School of Electrical Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 13 ] [Zhang Z.]School of Electrical and Electronic Engineering, Chongqing University of Technology, Chongqing, 400054, China
  • [ 14 ] [Wang P.]State Key Laboratory of Power Transmission Equipment Technology, School of Electrical Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 15 ] [Wan F.]State Key Laboratory of Power Transmission Equipment Technology, School of Electrical Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 16 ] [Liu J.]College of Semiconductors (College of Integrated Circuits), Hunan University, Changsha, 410082, China
  • [ 17 ] [Li B.]College of Environmental Science and Engineering, National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 18 ] [Wang Y.]College of Environmental Science and Engineering, National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology, Beijing University of Technology, Beijing, 100124, China
  • [ 19 ] [Zheng G.]Department of Mechanical Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, 999077, Hong Kong
  • [ 20 ] [Li M.]MOE Key Laboratory of Low-grade Energy Utilization Technologies and Systems, CQU-NUS Renewable Energy Materials & Devices Joint Laboratory, School of Energy and Power Engineering, National Innovation Center for Industry-Education Integration of Energy Storage, Chongqing University, Chongqing, 400044, China
  • [ 21 ] [Sun J.]Soochow Institute for Energy and Materials Innovation, Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou, 215006, China

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Source ：

Angewandte Chemie - International Edition

ISSN： 1433-7851

Year： 2025

1 6 . 6 0 0

JCR@2022

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 3

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 9

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