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Author:

Yu Zhang (Yu Zhang.) | Zhaoheng Tang (Zhaoheng Tang.) | Zhongyang Zhang (Zhongyang Zhang.) | Jiahong Tang (Jiahong Tang.) | Minghua Li (Minghua Li.) | Siyuan Zhu (Siyuan Zhu.) | Wenyan Tan (Wenyan Tan.) | Xi Jin (Xi Jin.) | Tongsheng Chen (Tongsheng Chen.) | Jinsong Hu (Jinsong Hu.) | Chao Zhou (Chao Zhou.) | Chunlei Yang (Chunlei Yang.) | Qijie Liang (Qijie Liang.) | Xugang Guo (Xugang Guo.) | Weimin Li (Weimin Li.) | Weiqiang Chen (Weiqiang Chen.) | Yan Jiang (Yan Jiang.)

Abstract:

Near-infrared(NIR)transparent inverted all-inorganic perovskite solar cells(PSCs)are excellent top cell candidates in tandem applications.An essential challenge is the replacement of metal contacts with transparent conductive oxide(TCO)electrodes,which requires the introduction of a buffer layer to pre-vent sputtering damage.In this study,we show that the conventional buffers(i.e.,small organic mole-cules and atomic layer deposited metal oxides)used for organic-inorganic hybrid perovskites are not applicable to all-inorganic perovskites,due to non-uniform coverage of the vulnerable layers underneath,deterioration upon ion bombardment and moisture induced perovskite phase transition.A thin film of metal oxide nanoparticles by the spin-coating method serves as a non-destructive buffer layer for inor-ganic PSCs.All-inorganic inverted near-infrared-transparent PSCs deliver a PCE of 17.46%and an average transmittance of 73.7%between 780 and 1200 nm.In combination with an 18.56%Cu(In,Ga)Se2 bottom cell,we further demonstrate the first all-inorganic perovskite/CIGS 4-T tandem solar cell with a PCE of 24.75%,which exhibits excellent illumination stability by maintaining 86.7%of its initial efficiency after 1400 h.The non-destructive buffer lays the foundation for efficient and stable NIR-transparent inverted inorganic perovskite solar cells and perovskite-based tandems.

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Author Community:

  • [ 1 ] [Chunlei Yang]Shenzhen Institute of Advanced Technology,Chinese Academy of Sciences,Shenzhen 18055,Guangdong,China
  • [ 2 ] [Zhongyang Zhang]北京工业大学
  • [ 3 ] [Yu Zhang]MOE Key Laboratory of Laser Life Science & Guangdong Provincial Key Laboratory of Laser Life Science,Guangzhou Key Laboratory of Spectral Analysis and Functional Probes,College of Biophotonics,South China Normal University,Guangzhou 510631,Guangdong,China;School of Materials Science and Engineering,Beijing Institute of Technology,Beijing 100081,China;Songshan Lake Materials Laboratory,Dongguan 523429,Guangdong,China
  • [ 4 ] [Jinsong Hu]中国科学院化学研究所
  • [ 5 ] [Qijie Liang]Songshan Lake Materials Laboratory,Dongguan 523429,Guangdong,China
  • [ 6 ] [Chao Zhou]Songshan Lake Materials Laboratory,Dongguan 523429,Guangdong,China;School of Physics and Materials Science,Guangzhou University,Guangzhou 510006,Guangdong,China
  • [ 7 ] [Zhaoheng Tang]Songshan Lake Materials Laboratory,Dongguan 523429,Guangdong,China;Department of Materials Science and Engineering,Guangdong Provincial Key Laboratory of Functional Oxide Materials and Devices,Southern University of Science and Technology,Shenzhen 518055,Guangdong,China
  • [ 8 ] [Minghua Li]Beijing Advanced Innovation Center for Soft Matter Science and Engineering,College of Chemical Engineering,College of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China
  • [ 9 ] [Xi Jin]MOE Key Laboratory of Laser Life Science & Guangdong Provincial Key Laboratory of Laser Life Science,Guangzhou Key Laboratory of Spectral Analysis and Functional Probes,College of Biophotonics,South China Normal University,Guangzhou 510631,Guangdong,China;Songshan Lake Materials Laboratory,Dongguan 523429,Guangdong,China
  • [ 10 ] [Weimin Li]Shenzhen Institute of Advanced Technology,Chinese Academy of Sciences,Shenzhen 18055,Guangdong,China
  • [ 11 ] [Jiahong Tang]北京工业大学
  • [ 12 ] [Tongsheng Chen]MOE Key Laboratory of Laser Life Science & Guangdong Provincial Key Laboratory of Laser Life Science,Guangzhou Key Laboratory of Spectral Analysis and Functional Probes,College of Biophotonics,South China Normal University,Guangzhou 510631,Guangdong,China
  • [ 13 ] [Yan Jiang]北京工业大学
  • [ 14 ] [Siyuan Zhu]Songshan Lake Materials Laboratory,Dongguan 523429,Guangdong,China;Department of Physics,Liaoning University,Shenyang 110036,Liaoning,China
  • [ 15 ] [Wenyan Tan]MOE Key Laboratory of Laser Life Science & Guangdong Provincial Key Laboratory of Laser Life Science,Guangzhou Key Laboratory of Spectral Analysis and Functional Probes,College of Biophotonics,South China Normal University,Guangzhou 510631,Guangdong,China;Songshan Lake Materials Laboratory,Dongguan 523429,Guangdong,China
  • [ 16 ] [Weiqiang Chen]MOE Key Laboratory of Laser Life Science & Guangdong Provincial Key Laboratory of Laser Life Science,Guangzhou Key Laboratory of Spectral Analysis and Functional Probes,College of Biophotonics,South China Normal University,Guangzhou 510631,Guangdong,China
  • [ 17 ] [Xugang Guo]Department of Materials Science and Engineering,Guangdong Provincial Key Laboratory of Functional Oxide Materials and Devices,Southern University of Science and Technology,Shenzhen 518055,Guangdong,China

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能源化学

ISSN: 2095-4956

Year: 2024

Issue: 10

Volume: 97

Page: 622-629

1 3 . 1 0 0

JCR@2022

Cited Count:

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SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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