Hazardous　wastes　from　the　production　of　cleaner　fuels,　spent　hydrodesulfurization　(HDS)　catalysts,　pose　a　threat　to　the　environment　and　the　sustainability　of　rare　metal　resources.　However,　conventional　recovery　approaches　are　limited　by　long　processes,　easy　generation　of　waste　liquids,　and　difficult　reuse　of　recovery　products.　Herein,　a　SiO2-Na2O-B2O3-MgO-TiO2　glass　phase　extraction　system　was　proposed　for　the　full-component　recycle　from　spent　MoNi/gamma-Al2O3　catalysts　to　the　materials,　including　the　individual　recovery　of　Mo　and　the　synthesis　of　Ni2+-doped　glass-ceramics.　96.7%　of　Ni　and　99.8%　of　Al　were　extracted　into　the　loaded　glass　in　one　step,　while　95.3%　of　Mo　was　precipitated　as　molybdate　and　directly　recovered　with　high　separation　factors　(SFMo/Ni　594.8,　SFMo/Al　8718.2)　in　one　step.　Moreover,　the　broadband　near-infrared　luminescence　(1150　-　1700　nm)　of　glass-ceramics　was　triggered　by　Ni2+　in　the　octahedral　crystal　structure　of　Me3O5　(Me　=　Mg,　Al,　Ti)　by　melting-annealing-crystallization　processes,　which　provided　it　the　potential　to　be　applied　in　tunable　lasers　and　broadband　optical　amplifiers　for　the　wavelength-division-multiplexing　transmission　systems.　The　Ni2+-doping　mechanism　was　calculated　using　molecular　dynamics　simulations.　This　work　emphasized　the　maximization　of　the　reuse　value　for　each　metal　resource　from　hazardous　wastes　while　reducing　the　burden　on　the　environment　and　achieving　the　recycling　of　rare　metal　resources　with　re-valorization.　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(HDS)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)SiO2-Na2O-B2O3-MgO-TiO2(sic)(sic)(sic)(sic)(sic)(sic)(sic),　(sic)(sic)(sic)(sic)　MoNi/gamma-Al2O3(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)　Mo(sic)(sic)(sic)(sic)(sic)Ni2+(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic)(sic)(sic),　96.7%(sic)Ni(sic)(sic)(sic)99.8%(sic)Al(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),　(sic)(sic)95.3%(sic)Mo(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(SF,　SFMo/Ni　=　594.8,　SFMo/Al　=　8718.2)(sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic)(sic)(sic)(sic)(sic)(sic)-(sic)(sic)-(sic)(sic)(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)Ni2+(sic)(sic)　Me3O5(Me　=　Mg,Al,Ti)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(1150　-　1700　nm),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)Ni2+(sic)(sic)(sic)(sic).(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),　(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic),(sic)(sic)(sic)(sic)(sic).