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Author:

Tao, Heng (Tao, Heng.) | Wang, Zhaohui (Wang, Zhaohui.) | Wu, Xuming (Wu, Xuming.) | Li, Lincong (Li, Lincong.) | Wang, Yihan (Wang, Yihan.) | Zhao, Chenchen (Zhao, Chenchen.) | Du, Wenbo (Du, Wenbo.)

Indexed by:

EI Scopus SCIE

Abstract:

In this study, the oxidation behavior and mechanism of AlxCoCrFeNi1.5Ti0.1 (x = 0, 0.25, 0.5, 0.75, 1.0) high- entropy alloy (HEA) coatings at high temperatures ranging from 700 degrees C to 900 degrees C were investigated. The microstructure and oxidation products of the HEA coatings were characterized with scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD). In order to elucidate the effect of Al content on the oxidation behavior of HEA coatings, a novel oxidation kinetic model modified by Al content was developed. The results indicate that the oxidation weight gain of the HEA coatings generally follows a parabolic law. With the increase of Al content, the microstructure of HEA coatings transforms into a dual-phase structure (FCC and BCC) containing new BCC phases. When the HEA coatings are composed of the dual-phase structure (FCC and BCC), the oxidation process of the coatings is primarily inhibited by the diffusion of Al and Cr within the oxide layer, and the oxidation rate of the coatings is significantly reduced. The oxide layer of HEA coatings mainly comprises an inner Al2O3 layer and an outer Cr2O3 layer.

Keyword:

High-temperature oxidation Laser cladding High-entropy alloy coatings Aluminum Microstructure

Author Community:

  • [ 1 ] [Tao, Heng]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Zhaohui]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wu, Xuming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Lincong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Zhao, Chenchen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Du, Wenbo]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Wang, Zhaohui]Beijing Univ Technol, Hydrogen Energy Res Inst Daxing, Beijing 100124, Peoples R China
  • [ 8 ] [Wu, Xuming]Beijing Univ Technol, Inst Circular Econ, Beijing 100124, Peoples R China
  • [ 9 ] [Wang, Yihan]Cent Univ Finance & Econ, Sch Stat & Math, Beijing 102206, Peoples R China

Reprint Author's Address:

  • [Wang, Zhaohui]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

SURFACE & COATINGS TECHNOLOGY

ISSN: 0257-8972

Year: 2025

Volume: 502

5 . 4 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 14

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