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The work aims to prepare in situ carbide enhanced BCC structure high-entropy alloy cladding layers, and study the effect of design content of carbide on their microstructure and mechanical properties. Therefore, in situ VC enhanced Al1.5CoCrFeNi(VC)x (x=0, 0.1, 0.2, 0.3, mole ratio) high-entropy alloy were manufactured on the Q235 steel by plasma cladding. The effect of VC design content on their phases, microstructure, and mechanical properties were analyzed. Al, Co, Cr, Fe, Ni, vanadium-iron alloy (50% V, 50% Fe) and high carbon ferrochrome (7% C, 30% Fe, 63% Cr) powders were mixed according to the atomic ratio of Al1.5CoCrFeNi(VC)x (x=0, 0.1, 0.2, 0.3, mole ratio). The particle size range of the above powders was 100-200 mesh. Q235 steel was selected as substrate, whose surface was polished and rinsed with acetone before plasma cladding. A plasma spray welding machine (PT-400E4-ST) was used to produce cladding layers. The phases, morphologies, and element compositions of cladding layers were analyzed by X-ray diffractometer (XRD, XRD-7000), scanning electron microscope (SEM, S-3400), energy dispersive spectrometer (EDS) and transmission electron microscope (TEM, JEM2100), respectively. The microhardness of cladding layers were measured by microhardness tester (HXD-1000). The wear properties of cladding layers were evaluated by abrasive wear testing machine (MLS-225). The results indicated that when x=0, the cladding layer was BCC solid-solution and its microstructure was typical dendrite structure. The dendrite was BCC solid-solution rich in Al and Ni, and the interdendrite was BCC solid-solution rich in Cr and Fe. After adding V and C (x=0.1, 0.2, 0.3), the diffraction peaks of cladding layers were composed of BCC solid-solution, VC and a few σ phases. The shape of VC was polygonal granular, long striplight and cross-dendrite. The VC mostly segregated at interdendrite, but only a few inside the dendrite. And with the increase of V and C content, the precipitation amount of VC also increased. TEM results indicated that the interface between the in situ VC and the matrix was clean without other reacting products. With the increase of VC design content from x=0 to x=0.3, the hardness of cladding layers increased from 529.3HV to 829.8HV, and weight loss rate reduced from 34.88 mg/min to 2.45 mg/min. When x=0, the wear mechanism of the cladding layer was mainly microscopic cutting, supplemented by repeated plastic deformation. After adding V and C (x=0.1, 0.3), the wear mechanism of cladding layers was mainly microscopic cutting. In situ VC plays an obvious strengthening role in the high-entropy alloy. With the increase of VC design content from x=0 to x=0.3, the hardness and wear resistance of the cladding layers are increased. © 2025 Chongqing Wujiu Periodicals Press. All rights reserved.
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Surface Technology
Year: 2025
Issue: 3
Volume: 54
Page: 110-117
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 10
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