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Abstract:
This study proposes an innovative ethylenediaminetetraacetic acid disodium salt (EDTA-2Na) pretreatment strategy for simultaneous methane and phosphorus (P) recovery from waste activated sludge (WAS). Pretreatment with 7.5 mmol/L EDTA-2Na disrupted sludge floc structures via metal-chelating effects, enhancing shortchain fatty acids (SCFAs) by 1.4-fold and methane production by 1.3-fold during anaerobic digestion. After EDTA-2Na pretreatment, 48.9 % of total phosphorus (TP) was released from the sludge in the methaneproduction phase, and in the phosphorus recovery phase, another 32.3 % of TP was released under the synergistic promotion of EDTA-2Na pretreatment and acidification. Recovered P crystallized as vivianite with 81.1 % efficiency and 73.1 % purity. This approach demonstrates sustainable sludge management by integrating methane and P recovery through EDTA-2Na pretreatment in anaerobic digestion.
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BIORESOURCE TECHNOLOGY
ISSN: 0960-8524
Year: 2025
Volume: 428
1 1 . 4 0 0
JCR@2022
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 7
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