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Author:

Meng, Fanwei (Meng, Fanwei.) | Qu, Chao (Qu, Chao.) | Wang, Lanyang (Wang, Lanyang.) | Yang, Decai (Yang, Decai.) | Luo, Youguo (Luo, Youguo.) | Zhao, Zezhong (Zhao, Zezhong.) | Ye, Qing (Ye, Qing.) (Scholars:叶青)

Indexed by:

EI Scopus SCIE

Abstract:

Graphitic carbon nitride (g-C3N4), because of its appropriate band gap, is a prospective option for photocatalytic CO2 reduction. Nevertheless, the rapid recombination of photogenerated charge carriers restricts the photocatalytic efficiency of CN. In this study, a one-step chemical reaction followed by low-temperature calcination method was innovatively used to anchor zero-dimensional (0D) Ni-Fe bimetallic oxide quantum dots (NFO QDs) onto the surface of two-dimensional (2D) porous CN nanosheets. Under visible light irradiation, a CO yield of 1571.55 mu mol g- 1 h- 1 was achieved by the composite catalyst (NFO QDs/CN). Ultraviolet photoelectron spectroscopy (UPS) and in situ X-ray photoelectron spectroscopy (XPS) confirmed the existence of an in-built electric field at the interface between NFO QDs and CN, which performed as a Z-scheme heterojunction. Photoluminescence spectroscopy (PL), electrochemical impedance spectroscopy (EIS), and UV-visible diffuse reflectance spectroscopy (UV-Vis DRS) all showed that improved spatial separation of photogenerated electron-hole pairs and increased light absorption were responsible for the improved photocatalytic performance. Moreover, morphological characterization revealed that CN possessed a lamellar porous structure, coupled with the small size of the NFO QDs, which resulted in an increased specific surface area. This study offers fresh perspectives on the design of high-performance CN-based composite photocatalysts for energy production.

Keyword:

Photocatalytic CO 2 reduction Graphitic carbon nitride Ni-Fe bimetallic oxide quantum dots Z -scheme heterojunction

Author Community:

  • [ 1 ] [Meng, Fanwei]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Qu, Chao]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Lanyang]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Yang, Decai]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Luo, Youguo]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Zhao, Zezhong]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 7 ] [Ye, Qing]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 叶青

    [Qu, Chao]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Ye, Qing]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Sci, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2025

Volume: 366

8 . 6 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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