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Abstract:
The outstanding high-strength of high-entropy alloys (HEAs) depends on a synergistic effect of various strengthened methods, such as precipitation strengthening. However, the precipitates hamper the corrosion resistance by common understanding, leading to a reduced ability of these precipitation strengthened HEAs to withstand complex environments. In this work, we proposed a boron-doping strategy to regulate the conflict between mechanical properties and corrosion resistance in an equiatomic FeCrNiCoMn HEA, and revealed the role of boron in microstructure and properties. As expected, as the boron-doping content raised from 1 to 4 at%, the strengths gradually enhanced, due to the strengthening effect of boride precipitates at grain boundaries in addition to grain refinement. Particularly, the yield strength (YS) increased twice compared to that of boron-free reference alloy, reaching similar to 425 MPa. Different from the conventional experience in the effect of precipitates, the addition of boron led to the decreases in both corrosion potential (E-corr) and current density (I-corr) values in 3.5 wt% NaCl solution. Among these HEAs, the FeCrNiCoMn HEA with 1 at% boron doping exhibited the best corrosion resistance, which was attributed to the competition between grain refinement and boride precipitation. The proper boron doping led to pronounced grain refinement by more than 20 %, which promoted the rapid formation of a less defective and more stable passive film, thus prevailing over the detrimental effect of boride precipitates by inducing Cr-depleted zones. Therefore, the strength and corrosion resistance of the FeCrNiCoMn HEA were simultaneously improved by doping 1 at% boron. The present results demonstrate an effective strategy to regulate the balanced properties of precipitation strengthened HEAs and provide an inspiration for future works aiming to develop these materials with adequate suitability in various applications.
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JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
Year: 2025
Volume: 1022
6 . 2 0 0
JCR@2022
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 8
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