This　study　investigates　the　anodic　dissolution　and　electrochemical　behavior　of　molybdenum　in　a　NaClKCl　molten　salt　system　at　1023　K.　The　anodic　dissolution　process　was　systematically　analyzed,　revealing　a　sequential　oxidation　pathway　of　molybdenum　into　high-valence　ions　(Mo6+,　Mo5　+,　Mo4+)　under　varying　electrolysis　potentials.　Electrochemical　Impedance　Spectroscopy　(EIS)　demonstrated　that　the　dissolution　is　governed　by　both　charge　transfer　and　diffusion　mechanisms,　with　reduced　impedance　at　higher　potentials　facilitating　molybdenum　dissolution.　The　reduction　behavior　of　dissolved　molybdenum　ions　was　further　explored　using　cyclic　voltammetry　(CV)　and　square　wave　voltammetry　(SWV),　confirming　a　multi-step　reduction　process　controlled　by　diffusion　and　high　reversibility.　Nucleation　studies　using　chronoamperometry　established　that　molybdenum　deposition　follows　an　instantaneous　nucleation　mechanism.　Morphological　analysis　of　cathodic　deposits　revealed　that　current　density　significantly　influences　particle　size,　transitioning　from　nano-sized　spherical　particles　to　larger　equiaxed　crystals　with　increasing　current　density.　These　findings　provide　a　comprehensive　understanding　of　molybdenum＇s　electrochemical　properties　in　molten　salts,　offering　valuable　insights　for　optimizing　electrolysis　processes　and　advancing　molybdenum-based　material　production.　(c)　2025　Published　by　Elsevier　Ltd　on　behalf　of　The　editorial　office　of　Journal　of　Materials　Science　&　Technology.