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Author:

Hu, Xintao (Hu, Xintao.) | Ren, Bo (Ren, Bo.) | Zhang, Li (Zhang, Li.) | Sun, Jihong (Sun, Jihong.) (Scholars:孙继红)

Indexed by:

EI Scopus PKU CSCD

Abstract:

Ti/BMMs mesoporous catalysts were synthesized by using self-assembly route combined with ship-in-a-bottle method and their catalytic performances were tested by epoxidation of cyclohexene. The prepared Ti/BMMs catalysts were characterized with ICP-AES, XRD, TEM, N2 adsorption-desorption and UV-Vis. The effects of solvent, content of Ti, reaction temperature and time on the catalytic activity and product selectivity were investigated in details. The results showed that as the amount of added Ti increased in the BMMs catalysts, the mesoporous structure became somewhat disordered. The cyclohexene conversion and the selectivity of cyclohexene oxide increased with the reaction temperature and the catalyst had an optimum activity using chloroform as the solvent.

Keyword:

Olefins Synthesis (chemical) Vehicle performance Mesoporous materials Bottles Epoxidation Ionic liquids Organic solvents Ships Catalyst activity Catalyst selectivity Atomic emission spectroscopy Chlorine compounds

Author Community:

  • [ 1 ] [Hu, Xintao]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Ren, Bo]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 3 ] [Zhang, Li]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 4 ] [Sun, Jihong]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

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Source :

Acta Petrolei Sinica (Petroleum Processing Section)

ISSN: 1001-8719

Year: 2012

Issue: SUPPL. 1

Volume: 28

Page: 102-106

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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