• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Zhao, Xinran (Zhao, Xinran.) | He, Xiaobo (He, Xiaobo.) | Chen, Biaohua (Chen, Biaohua.) (Scholars:陈标华) | Yin, Fengxiang (Yin, Fengxiang.) | Li, Guoru (Li, Guoru.)

Indexed by:

EI Scopus SCIE

Abstract:

In this work, a series of metallic Co-ZnO encapsulated in N-doped carbon/carbon nanotubes (Co-ZnO@NC/CNT-T) for the electrochemical oxygen reduction reaction (ORR) were synthesized by annealing bimetallic metal-organic frameworks (MOFs) containing Co and Zn in N-2 atmosphere. Within the hybrid, metallic Co was integrated with ZnO and encapsulated by NC, while coral-like CNTs grew out of the obtained Co-ZnO@NC nanoparticles. When applied in ORR catalysis, the optimized Co-ZnO@NC/CNT-700 obtained in 700 degrees C displayed a half-wave potential of similar to 0.86 V and a limiting current density of similar to-5.98 mA cm(-2), which were even superior to 20 wt% Pt/C. Further results demonstrated that the presence of ZnO was closely related with the high ORR catalytic activity from two aspects. (i) ZnO catalyzed the formation of Co-0, Co2+, pyridinic and graphitic N as the main active species for ORR. (ii) ZnO promoted the growth of CNTs and micro/mesoporous structure, which improved the electrochemical active surface area (ECSA) and mass transfer during the ORR process.

Keyword:

Carbon nanotubes Oxygen reduction reaction N-doped carbon Zinc oxide Metallic cobalt

Author Community:

  • [ 1 ] [Chen, Biaohua]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [He, Xiaobo]Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
  • [ 3 ] [Yin, Fengxiang]Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
  • [ 4 ] [Li, Guoru]Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
  • [ 5 ] [Zhao, Xinran]Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China
  • [ 6 ] [He, Xiaobo]Beijing Univ Chem Technol, Changzhou Inst Adv Mat, Changzhou 213164, Peoples R China
  • [ 7 ] [Yin, Fengxiang]Beijing Univ Chem Technol, Changzhou Inst Adv Mat, Changzhou 213164, Peoples R China

Reprint Author's Address:

  • 陈标华

    [Chen, Biaohua]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China;;[Yin, Fengxiang]Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

Show more details

Related Keywords:

Source :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

Year: 2019

Volume: 487

Page: 1049-1057

6 . 7 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:211

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 27

SCOPUS Cited Count: 30

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

Online/Total:735/10708467
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.