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Author:

Wei, Qiumei (Wei, Qiumei.) | Zhu, Mankang (Zhu, Mankang.) | Zheng, Mupeng (Zheng, Mupeng.) | Hou, Yudong (Hou, Yudong.) (Scholars:侯育冬)

Indexed by:

EI Scopus SCIE

Abstract:

A giant field-induced strain of 0.65% with excellent temperature insensitivity and fatigue resistance was achieved by introducing 1.5 mol.% B-site complex cations (Zn1/3Nb2/3)(4+) into the 0.93(Bi1/2Na 1/2)TiO3-0.07BaTiO(3) lead-free ferroelectric ceramics. (Bi1/2Na1/2)(0.93)Ba-0.07(Zn1/3Nb2/3)(x)Tit-xO(3) (0 <= x <= 0.025) ceramics were prepared by the columbite route, their microstructure, electric properties, and field-induced strain behavior were systematically investigated. XRD analysis reveals that the B-site substitution by complex cations (Zn1/3Nb2/3)(4+) induces the phase transition from R3c to pseudocubic structures, and demonstrates different phase evolution under field applied. At the composition x= 0.015, a composition-driven boundary between the nonergodic state and ergodic state is observed. Meanwhile, the substitution by complex cations (Zn1/3Nb2/3 )(4+) reduces the dimension of polar nanoregions (PNRs) due to the destruction of the long-range ferroelectric ordering. A phenomenological illustration based on Bokov's suggestion and Landau-Devenshire theory suggests the relationship between the size of PNRs and field-induced strain behavior. (C) 2018 Elsevier B.V. All rights reserved.

Keyword:

Electroceramics Strain Phase transition Nanodomains Ferroelectric

Author Community:

  • [ 1 ] [Wei, Qiumei]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhu, Mankang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zheng, Mupeng]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Hou, Yudong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Zhu, Mankang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2019

Volume: 782

Page: 611-618

6 . 2 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:211

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 45

SCOPUS Cited Count: 45

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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