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Author:

Zhang, Ningqiang (Zhang, Ningqiang.) | Li, Lingcong (Li, Lingcong.) | Wu, Rui (Wu, Rui.) | Song, Liyun (Song, Liyun.) | Zheng, Lirong (Zheng, Lirong.) | Zhang, Guizhen (Zhang, Guizhen.) | He, Hong (He, Hong.) (Scholars:何洪)

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EI Scopus SCIE

Abstract:

Low-temperature oxidation of carbon monoxide (CO) is one of the most studied reactions because of its scientific and industrial applications. In this study, we discovered that the low-temperature CO oxidation activity over Pt/MnOx catalyst could be enhanced by a novel beta-MnO2 support material. Nearly complete CO conversion was obtained over the Pt/MnOx catalyst below 100 degrees C under our catalysis conditions. TOF (turnover frequency) of Pt/MnOx was five and nine times that of Pt/MnOx-COM (COM, commercial) and Pt/Al2O3 at 150 degrees C, respectively. The combined results of X-ray diffraction (XRD) Rietveld refinement of fresh and spent catalysts, CO-temperature-programmed desorption (CO-TPD) and diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy allowed us to conclude that the O-2 molecules exhibited strong adsorption and activation ability on the surface of Pt/MnOx compared to that on the surface of Pt/MnOx-COM. From the H-2-TGA (weight loss) and DTGA results, we confirmed that strong metal-support interactions exist between Pt and MnOx via formation of Mn-O-Pt bonds for both catalysts. Moreover, by combining the results of Rietveld refinement of XRD, Raman, CO-TPD and O-2-TPD (inlet CO and inlet CO/O-2 mixture gases as adsorbates, respectively) analyses, we inferred that the interfacial lattice oxygen in Pt/MnOx might be the active oxygen species for low-temperature CO oxidation.

Keyword:

Author Community:

  • [ 1 ] [Zhang, Ningqiang]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Lingcong]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Wu, Rui]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Song, Liyun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, Guizhen]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [He, Hong]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 7 ] [Zhang, Ningqiang]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 8 ] [Li, Lingcong]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 9 ] [Wu, Rui]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 10 ] [Song, Liyun]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 11 ] [Zhang, Guizhen]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 12 ] [He, Hong]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 13 ] [He, Hong]Collaborat Innovat Ctr Elect Vehicles Beijing, Beijing 100081, Peoples R China
  • [ 14 ] [Zheng, Lirong]Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China

Reprint Author's Address:

  • 何洪

    [Li, Lingcong]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[He, Hong]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Li, Lingcong]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[He, Hong]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China;;[He, Hong]Collaborat Innovat Ctr Elect Vehicles Beijing, Beijing 100081, Peoples R China

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Source :

CATALYSIS SCIENCE & TECHNOLOGY

ISSN: 2044-4753

Year: 2019

Issue: 2

Volume: 9

Page: 347-354

5 . 0 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:166

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 43

SCOPUS Cited Count: 43

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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