Air　pollution,　typically　＂haze　air,＂　is　getting　worse　in　the　urban　areas　of　many　countries　worldwide.　The　development　of　advanced　materials　for　the　removal　of　air　pollutants　is　of　great　significance　for　protecting　public　health.　We　herein　present　two　promising　metal-organic　frameworks　(MOFs)　that　show　high　capture　capacities　for　aromatic　volatile　organic　compounds　even　at　low　pressure　and　high　temperature,　e.g.　benzene　uptakes　of　1.65　and　0.71　mmol　g(-1)　at　0.12　kPa　and　80　degrees　C.　Breakthrough　experiments　verify　their　excellent　performance　in　capturing　trace　benzene　in　humid　air,　also　showing　them　to　be　comparable　with　some　benchmark　materials,　including　Carboxen　1000,　PAF-1,　MIL-101　(Cr),　and　so　on.　Furthermore,　the　capture　performance　is　well　interpreted　by　the　single-crystal　structures　of　guest-loaded　phases,　where　distinct　adsorption　sites,　multiple　synergistic　host-guest　and　guest-guest　interactions,　and　adaptive　local　flexibility　are　disclosed.