The　polypyrrole　(PPy)　nanowires　are　conducting　1D　materials,　which　can　significantly　improve　the　electrical　conductivity　of　the　composites.　A　novel　Li1.26Fe0.22Mn0.52O2　(LFMO)　@　PPy　nanowire　composites　were　synthesized　by　simply　ultrasonic　dispersing　LFMO　and　PPy　nanowires　in　aqueous　ethanol.　The　structure　and　morphology　of　pristine　LFMO　and　LFMO@PPy　are　investigated　by　XRD,　SEM,　and　TEM.　The　elemental　mapping　and　FTIR　results　demonstrate　the　conductive　network　of　PPy　nanowires　exists　in　the　composites　and　the　LFMO　particles　uniformly　distribute　on　the　PPy　nanowires.　LFMO　combined　with　PPy　nanowires　exhibits　better　rate　capability,　higher　capacity,　coulombic　efficiency,　and　cycleability　than　the　pristine.　The　rate　performance　of　composites　with　10　wt%　PPy　nanowires　shows　the　discharge　capacities　of　132.2　mAh/g　and　98　mAh/g　at　1C　and　3C　rate　after　50　cycles,　respectively.　Electrochemical　impedance　spectroscopy　test　suggests　that　the　conductive　PPy　nanowires　can　significantly　decrease　the　charge-transfer　resistance　of　LFMO.　The　composite　with　10　wt%　PPy　nanowires　shows　a　discharge　capacity　retention　of　71%　after　50　cycles　at　1C,　while　the　pristine　sample　only　has　50%　capacity　retention.