In　this　study,　WC-10Co　was　used　as　a　consumable　anode　for　the　direct　preparation　of　cobalt　and　tungsten　from　NaF-KF　molten　salt　at　1023　K.　Electrochemical　analysis　was　performed　via　cyclic　and　square　wave　voltammetry.　Results　showed　that　cobalt　and　tungsten　ions　possess　different　precipitation　potentials　in　the　molten　salt,　thus　theoretically　proving　the　feasibility　of　preparing　separating　metallic　cobalt　and　tungsten　respectively.　Tungsten　and　cobalt　ions　exist　as　W2+　and　Co2+,　and　the　reaction　is　reversible　and　controlled　by　diffusion.　The　effects　of　electrolytic　current,　duration,　and　temperature　on　anodic　dissolution　mass,　dissolution　rate,　and　cathode　composition　and　morphology　were　studied　via　electrochemical　analysis.　The　cathode　product　was　analyzed　by　XRD　and　SEM.　The　results　further　showed　that　cobalt　powder　can　be　obtained　when　the　electrolytic　current　was　12　mA　for　a　short　period　of　time.　Tungsten　powder　can　be　obtained　by　increasing　electrolytic　current　and　duration.　Furthermore,　tungsten　powder　with　a　particle　diameter　of　less　than　1　inn　can　be　obtained　under　the　following　electrolysis　conditions:　current　of　88　mA,　duration　of　7　h,　and　temperature　of　1023　K.