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学者姓名：陈标华
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Abstract ：
CO2 oxidative dehydrogenation of propane (CO2-ODHP), being not only favorable for olefin production but also beneficial for CO2 emission control, has recently attracted great attention. Here, a series of single metal (Cr) and bimetal (Zr, La, Fe) modified ZSM-5 zeolites were prepared via an impregnation method. It was found that the bimetal modified ZSM-5 possessed much higher C3H8 and CO2 conversion than that of monometallic modified Cr-3%-ZSM-5 (Cr3%-Z5), especially for Cr3%Zr2%-ZSM-5 (Cr3%Zr2%-Z5), which displayed the highest activity (w65.4%) and olefin yield (1.65 x 10(3) mu mol.g(cat)(-1) h(-1)). Various characterizations were performed, including XRD, N-2 adsorption-desorption, H2-TPR, Raman, XPS, HAAD-STEM, and TEM. It was revealed that Zr not only favored an improvement in the redox ability of Cr, but also contributed to the surface dispersion of loaded Cr species, constituting two major reasons explaining the superior activity of Cr3%Zr2%-Z5. To further improve CO2-ODHP catalytic behavior, a series of Cr3%-ZSM-5@SBA-15-n composite zeolite catalysts with diverse (ZSM-5/SBA-15) mass ratios were prepared (Cr-3%-ZS-n, n = 0.5, 2, 6, 16), which screened out an optimum mass ratio of six. Based on this, the Cr-3% Zr2%-ZS-6 compound was further prepared, and it eventually achieved even higher CO2-ODHP activity (76.9%) and olefin yield (1.72 x 10(3) mu mol.g(-1) cat h(-1)). Finally, the CO2-ODHP reaction mechanism was further investigated using in situ FTIR, and it was found that the reaction followed the Mars-van Krevelen mechanism, wherein CO2 participated in the reaction through generation of polydentate carbonates. The Cr6+ constituted as the active site, which was reduced to Cr3+ after the dihydrogen reaction, and was then further oxidized into Cr6+ by CO2, forming polydentate carbonates, and thus cycling the reactive species C-r6+. Additionally, assisted by a Bronsted acid site (favoring breaking of the C-C bond), C2H4 and CH4 were produced.
Keyword ：
propane oxidative to olefin propane oxidative to olefin molecular sieve catalysts molecular sieve catalysts chromium-based catalysts chromium-based catalysts CO2 CO2
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| GB/T 7714 | Xing, Mingqiao , Liu, Ning , Dai, Chengna et al. CO2 Oxidative Dehydrogenation of Propane to Olefin over Cr-M (M = Zr, La, Fe) Based Zeolite Catalyst [J]. | CATALYSTS , 2024 , 14 (6) . |
| MLA | Xing, Mingqiao et al. "CO2 Oxidative Dehydrogenation of Propane to Olefin over Cr-M (M = Zr, La, Fe) Based Zeolite Catalyst" . | CATALYSTS 14 . 6 (2024) . |
| APA | Xing, Mingqiao , Liu, Ning , Dai, Chengna , Chen, Biaohua . CO2 Oxidative Dehydrogenation of Propane to Olefin over Cr-M (M = Zr, La, Fe) Based Zeolite Catalyst . | CATALYSTS , 2024 , 14 (6) . |
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Abstract ：
The escalating emission of CO2 has caused a significant environmental impact. Hydrogenation of CO2 to methanol stands as the primary objective in the liquid sunlight vision, aiming to mitigate CO2 emissions. CuZn-based transition metal catalysts, known for their cost-effectiveness, demonstrate commendable catalytic performance at moderate temperatures and pressures, showcasing considerable potential in industrial applications. Consequently, a series of catalysts, composed of CuZn-based species supported on CeO2 with strategically introduced appropriate oxygen vacancies, were meticulously prepared. It worth to noting that the size of Cu was precisely tuned, along with the enhanced ability to the adsorption and activation of CO2 and H-2. As a result, the optimal CuZn/CeO2 catalyst exhibits high methanol formation rate, recording at 433.4 g(MeOH) kg(cat)(-1) h(-1) with selectivity of 68.5% at 260 degrees C and 3 MPa. Simultaneously, the reaction path and the evolution of intermediates in CO2 hydrogenation was thoroughly delineated.
Keyword ：
Oxygen vacancy Oxygen vacancy CH3OH selectivity CH3OH selectivity CO2 hydrogenation CO2 hydrogenation Copper size effect Copper size effect
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| GB/T 7714 | Zhang, Lan , Hu, Xiaomin , Wang, Ning et al. The copper size effect of CuZn/CeO2 catalyst in CO2 hydrogenation to methanol [J]. | CATALYSIS TODAY , 2024 , 436 . |
| MLA | Zhang, Lan et al. "The copper size effect of CuZn/CeO2 catalyst in CO2 hydrogenation to methanol" . | CATALYSIS TODAY 436 (2024) . |
| APA | Zhang, Lan , Hu, Xiaomin , Wang, Ning , Chen, Biaohua . The copper size effect of CuZn/CeO2 catalyst in CO2 hydrogenation to methanol . | CATALYSIS TODAY , 2024 , 436 . |
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Abstract ：
本发明涉及一种己二酸尾气中N2O的资源化利用方法，在不使用催化剂的条件下，仍可以将已二酸尾气中的N2O进行处理，并且能进一步生产出具有工业价值的硝酸和不会对环境造成影响的氮气与氧气，在达到对己二酸尾气中N2O进行处理的同时产生经济效益，且工艺简单、N2O脱除率高、稳定性高、环境友好和资源化利用率高，还能大幅度降低尾气催化处理的成本。并且本发明的方法能够连续运转，能够持续解决己二酸工业尾气排放问题，使其达到工业排放标准，降低企业处理尾气的成本，具有重要的现实意义和工程应用价值。
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| GB/T 7714 | 陈标华 , 潘磊 , 徐瑞年 . 一种己二酸尾气中N2O的资源化利用方法 : CN202310610004.0[P]. | 2023-05-26 . |
| MLA | 陈标华 et al. "一种己二酸尾气中N2O的资源化利用方法" : CN202310610004.0. | 2023-05-26 . |
| APA | 陈标华 , 潘磊 , 徐瑞年 . 一种己二酸尾气中N2O的资源化利用方法 : CN202310610004.0. | 2023-05-26 . |
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Abstract ：
本发明公开了一种H2分子原位调控Pt/M‑CeO2催化剂的制备方法及其在制烯烃中的应用。本发明在100ml四氟内衬中加入6mol/L的NaOH溶液及铈源，按照Pt : M质量比为1 : 3，加入铂源以及一定量的金属源(Sn, Fe, Cu，Co, Zn)形成悬浮液，搅拌30min后原位通入1MPa H2，于100℃晶化24小时，制得系列Pt/M‑CeO2催化剂，本发明合成方法简便，可制备低Pt负载量的催化材料，大大降低了成本，且具有大量的活性位点, 在一定程度上提高了催化活性。本发明制得的Pt/M‑CeO2催化剂应用于CO2氧化丙烷制烯烃过程中，表现出优异的催化性能，具有很高的应用价值。
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| GB/T 7714 | 刘宁 , 牛宇琪 , 代成娜 et al. 一种H2分子原位调控Pt/M-CeO2催化剂的制备方法及其在制烯烃中的应用 : CN202310097577.8[P]. | 2023-01-19 . |
| MLA | 刘宁 et al. "一种H2分子原位调控Pt/M-CeO2催化剂的制备方法及其在制烯烃中的应用" : CN202310097577.8. | 2023-01-19 . |
| APA | 刘宁 , 牛宇琪 , 代成娜 , 陈标华 . 一种H2分子原位调控Pt/M-CeO2催化剂的制备方法及其在制烯烃中的应用 : CN202310097577.8. | 2023-01-19 . |
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Abstract ：
一种离子液体作为催化剂醇解回收废弃PET聚酯的方法涉及聚酯纺织品醇解回收领域。本发明以PET聚酯材料为原料，以乙二醇为醇解剂，以离子液体作为催化剂，在170‑220℃下将聚酯为对苯二甲酸双羟乙酯(BHET)。本发明利用离子液体作为催化剂，可有效降低聚酯解聚反应温度，缩短反应时间，提高对苯二甲酸双羟乙酯(BHET)产率，降低化学回收工艺技术成本，同时所得产物纯度高。
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| GB/T 7714 | 刘宁 , 王星丽 , 于刚强 et al. 一种离子液体作为催化剂醇解回收废弃PET聚酯的方法 : CN202310075211.0[P]. | 2023-02-07 . |
| MLA | 刘宁 et al. "一种离子液体作为催化剂醇解回收废弃PET聚酯的方法" : CN202310075211.0. | 2023-02-07 . |
| APA | 刘宁 , 王星丽 , 于刚强 , 代成娜 , 陈标华 , 徐瑞年 et al. 一种离子液体作为催化剂醇解回收废弃PET聚酯的方法 : CN202310075211.0. | 2023-02-07 . |
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Abstract ：
本发明开发了一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法。该方法以磷酸三辛酯为萃取剂、离子液体1‑(2‑羟基乙基)‑3‑甲基咪唑双(三氟甲磺酰基)亚胺([HOEMIM][Tf2N])为协同萃取剂、(水)为反萃剂组成萃取体系，在有机相与水相体积比0.5：1 5：1，单次萃取时间15 60min, 萃取温度20 35℃，经过萃取、反萃和深度除镁后制备碳酸锂。本发明具备如下优势：一是该萃取体系在中性卤水中锂萃取率较高，同时锂镁分离系数较大，能够达到较好的锂镁分离效果，无需加酸碱调控pH值；二是萃取过程无乳化现象及第三相出现；三是离子液体作为绿色溶剂，具有高稳定性、不可燃性、几乎不挥发等特点，绿色环保。
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| GB/T 7714 | 刘宁 , 张薪和 , 于刚强 et al. 一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法 : CN202310475637.5[P]. | 2023-04-28 . |
| MLA | 刘宁 et al. "一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法" : CN202310475637.5. | 2023-04-28 . |
| APA | 刘宁 , 张薪和 , 于刚强 , 代成娜 , 陈标华 , 徐瑞年 et al. 一种使用离子液体/磷酸三辛酯从高镁锂比盐湖卤水中分离锂镁的协同溶剂萃取方法 : CN202310475637.5. | 2023-04-28 . |
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Abstract ：
本发明涉及一种用于提高轮胎裂解油中BTX含量的方法，包括如下步骤：(1)将废旧轮胎用去离子水祛除其表面污垢，置于破碎机中破碎后过筛，得到轮胎颗粒；将废旧轮胎去除钢丝后用去离子水祛除其表面污垢，置于破碎机中破碎后过筛，得到轮胎颗粒；(2)将步骤(1)中轮胎颗粒放入裂解反应器的样品室中，持续通入氮气排除裂解反应器内残留的空气；(3)对步骤(2)中排净空气的裂解反应器进行参数调节，所述参数包括裂解温度、裂解室压力、载气空速，待参数稳定后，打开样品室的放料阀，使轮胎颗粒从样品室落入恒温段的反应室进行反应，得到生成物，生成物含有BTX，所述BTX的产率为19.30‑26.52g/100g轮胎颗粒。
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| GB/T 7714 | 陈标华 , 郑大海 , 徐瑞年 et al. 一种用于提高轮胎裂解油中BTX含量的方法 : CN202310264747.7[P]. | 2023-03-13 . |
| MLA | 陈标华 et al. "一种用于提高轮胎裂解油中BTX含量的方法" : CN202310264747.7. | 2023-03-13 . |
| APA | 陈标华 , 郑大海 , 徐瑞年 , 代成娜 , 于刚强 , 刘宁 et al. 一种用于提高轮胎裂解油中BTX含量的方法 : CN202310264747.7. | 2023-03-13 . |
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Abstract ：
本发明涉及一种加氢脱硫催化剂及其制备方法和应用，利用气体小分子CO作为结构导向剂，使现有技术中的Co‑MoS2催化剂由传统的球形结构变为比表面积更大，活性位点更多的非球形结构，所述1T相MoS2在催化剂中的摩尔占比为62.6‑77.6％，所述催化剂中的MoS2为二维层状材料，每层均由MoS2组成，层与层之间的距离为层间距，所述层间距的范围为Co元素均匀分布在MoS2中，所述催化剂比表面积为65.9‑142.4m2/g，所述催化剂的活性位点在催化剂中的摩尔占比为62.3‑63.9％，1T相的高占比、MoS2的高层间距及高活性位点相互结合，共同提升所述催化剂加氢脱硫的性能。
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| GB/T 7714 | 陈标华 , 刘磊 , 刘宁 et al. 一种加氢脱硫催化剂及其制备方法和应用 : CN202310296350.6[P]. | 2023-03-24 . |
| MLA | 陈标华 et al. "一种加氢脱硫催化剂及其制备方法和应用" : CN202310296350.6. | 2023-03-24 . |
| APA | 陈标华 , 刘磊 , 刘宁 , 代成娜 . 一种加氢脱硫催化剂及其制备方法和应用 : CN202310296350.6. | 2023-03-24 . |
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Abstract ：
一种从废旧锂电池萃取液中高效回收钴镍的方法，属湿法冶金技术领域。本发明解决的技术问题是提供一种从废旧锂电池萃取液中低成本、低污染、高效率回收钴镍的方法，具体公开了一种使用草酸钠溶液，从含镍钴的萃取液中反萃后得到反萃液，再通过调节pH的方法沉淀，经烘干后最终得到草酸钴和草酸镍产品的回收方法，所述方法包括如下步骤：(1)配制草酸钠溶液；(2)反萃取；(3)钴沉淀；(4)镍沉淀；(5)沉淀的洗涤与烘干。该方法不仅操作简单、效率高、成本低、环境友好并且能再生萃取液，适合工业化生产。
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| GB/T 7714 | 于刚强 , 郭宇 , 陈标华 et al. 一种从废旧锂电池萃取液中高效回收钴镍的方法 : CN202310138587.1[P]. | 2023-02-20 . |
| MLA | 于刚强 et al. "一种从废旧锂电池萃取液中高效回收钴镍的方法" : CN202310138587.1. | 2023-02-20 . |
| APA | 于刚强 , 郭宇 , 陈标华 , 代成娜 , 刘宁 , 徐瑞年 et al. 一种从废旧锂电池萃取液中高效回收钴镍的方法 : CN202310138587.1. | 2023-02-20 . |
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Abstract ：
The present work theoretically investigated propane oxidation dehydrogenation by utilizing N2O as an oxidant (N2O-ODHP) over Cu-BEA with three different types of active site, including monomeric Cu ([Cu](+)), dimeric Cu ([Cu-Cu](2+)), and distant monomeric Cu sites ([Cu](+)-[Cu](+)). Energetically, we calculated that the monomeric [Cu]+ is favorable for the aH dehydrogenation step (6E = 0.05 eV), which, however, suffers from high barriers of N2O dissociation and (3H dehydrogenation steps of 1.40 and 1.94 eV, respectively. Although the dimeric [Cu-Cu](2+) site with a Cu-Cu distance of 4.91 & Aring; is much more favorable for N2O dissociation (0.95 eV), it still needs to overcome an extremely high barrier (6E = 2.15 eV) for (3H dehydrogenation. Interestingly, the distant [Cu](+)-[Cu](+) site with the Cu-Cu distance of 5.82 & Aring; exhibits low energy barriers for N2O dissociation (0.89 eV) and ODHP steps (0.01 and 0.33 eV) due to the synergistic effect of distant [Cu](+). The microkinetic analyses quantitatively verified the superior activity of the distant [Cu](+)-[Cu](+) site with a reaction rate being eight to nine orders of magnitude higher than those of the monomeric and the dimeric Cu sites, and this is related to its ready charge-transfer ability, as shown by the partial Density of State (PDOS) analysis and the static charge differential density analysis in this study. Generally, the present work proposes that the distance between the [Cu](+) sites plays a significant and important role in N2O-ODHP over the Cu-based zeolite catalyst and modulates Cu-Cu distance, and this constitutes a promising strategy for highly-efficient Cu-zeolite catalyst design for N2O-ODHP.
Keyword ：
Cu-BEA Cu-BEA N2O N2O propane oxidation dehydrogenation (ODHP) propane oxidation dehydrogenation (ODHP) density functional theory (DFT) density functional theory (DFT) microkinetic modelling microkinetic modelling
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| GB/T 7714 | Wu, Ruiqi , Liu, Ning , Dai, Chengna et al. Mechanistic Insight into the Propane Oxidation Dehydrogenation by N2O over Cu-BEA Zeolite with Diverse Active Site Structures [J]. | CATALYSTS , 2023 , 13 (8) . |
| MLA | Wu, Ruiqi et al. "Mechanistic Insight into the Propane Oxidation Dehydrogenation by N2O over Cu-BEA Zeolite with Diverse Active Site Structures" . | CATALYSTS 13 . 8 (2023) . |
| APA | Wu, Ruiqi , Liu, Ning , Dai, Chengna , Xu, Ruinian , Yu, Gangqiang , Wang, Ning et al. Mechanistic Insight into the Propane Oxidation Dehydrogenation by N2O over Cu-BEA Zeolite with Diverse Active Site Structures . | CATALYSTS , 2023 , 13 (8) . |
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