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学者姓名：庄春强
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Abstract ：
Thedesign of photocatalysts plays a central role in determiningthe photocatalytic H-2 yield. Here, we used a design strategythat is different from conventional methods to prepare our photocatalyticsystems. Large porous carbon aerogels (CA) with rich surface areaswere used to receive photogenerated electrons. TiO2 quantumdots were used as photocatalysts and anchored on large porous CAsto form CA@TiO2 systems. The H-2 yield of theoptimized CA@TiO2 composite is & SIM;2.1 mmol/g, & SIM;11times higher than that of pure TiO2 quantum dots. High-resolutionX-ray photoelectron spectroscopy and high-angle annular dark-fieldscanning transmission electron microscopy demonstrate that the photogeneratedelectrons can be easily transferred from TiO2 quantum dotsto porous CAs. Thus, efficient charge separation can be realized forthe succeeding highly efficient H-2 evolution. Our resultshere provide a different way from conventional methods to design photocatalyticsystems with high H-2 yield.
Keyword ：
large cocatalyst large cocatalyst photocatalyticH(2) photocatalyticH(2) ultra-small TiO2 ultra-small TiO2 porous carbon aerogel porous carbon aerogel smallphotocatalyst smallphotocatalyst
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| GB/T 7714 | Zhang, Hang , Li, Yuanli , Deng, Lichun et al. Porous Carbon Aerogel Decorated with TiO2 Quantum Dots for Highly Improved Photocatalytic H-2 Evolution [J]. | ACS APPLIED ENERGY MATERIALS , 2023 , 6 (13) : 7274-7282 . |
| MLA | Zhang, Hang et al. "Porous Carbon Aerogel Decorated with TiO2 Quantum Dots for Highly Improved Photocatalytic H-2 Evolution" . | ACS APPLIED ENERGY MATERIALS 6 . 13 (2023) : 7274-7282 . |
| APA | Zhang, Hang , Li, Yuanli , Deng, Lichun , Zhong, Jiaxing , Zhang, Zhenghan , Zhang, Yihong et al. Porous Carbon Aerogel Decorated with TiO2 Quantum Dots for Highly Improved Photocatalytic H-2 Evolution . | ACS APPLIED ENERGY MATERIALS , 2023 , 6 (13) , 7274-7282 . |
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Abstract ：
To realize the rapid separation of photogenerated carriers in photocatalytic reactions, large-sized porous carbon nanosheets with Pt dots were utilized as cocatalysts and coupled with TiO2 particles to construct photocatalytic systems. The optimized photocatalytic H-2 yield is similar to 108 times higher than that of TiO2, fully demonstrating the important role of large-sized porous carbon nanosheets with Pt dots for fast charge separation. The shift of the main peak in high-resolution X-ray photoelectron spectroscopies (XPS) verifies the electron transfer from TiO2 to porous carbon nanosheets. The dense distribution of photo-induced Pt deposition on porous carbon nanosheets confirms that active centers for H-2 evolution are mainly located on porous carbon nanosheets. Our work here provides the practicability of constructing large-sized conductive materials as cocatalysts for fast charge separation in photocatalytic reactions.
Keyword ：
Photocatalytic H-2 Photocatalytic H-2 Efficient charge separation Efficient charge separation Porous carbon nanosheet Porous carbon nanosheet Large-sized cocatalyst Large-sized cocatalyst
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| GB/T 7714 | Zhong, Jiaxing , Li, Yuanli , Zhang, Hang et al. Porous carbon nanosheets coupled with TiO2 particles for efficient photocatalytic H-2 production [J]. | SEPARATION AND PURIFICATION TECHNOLOGY , 2023 , 324 . |
| MLA | Zhong, Jiaxing et al. "Porous carbon nanosheets coupled with TiO2 particles for efficient photocatalytic H-2 production" . | SEPARATION AND PURIFICATION TECHNOLOGY 324 (2023) . |
| APA | Zhong, Jiaxing , Li, Yuanli , Zhang, Hang , Li, Shijie , Sun, Zaicheng , Zhuang, Chunqiang . Porous carbon nanosheets coupled with TiO2 particles for efficient photocatalytic H-2 production . | SEPARATION AND PURIFICATION TECHNOLOGY , 2023 , 324 . |
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Abstract ：
Cocatalysts in photocatalytic systems play an important role in achieving efficient charge separation. These cocatalysts usually have a small size and are generally anchored onto main catalysts. They are taken as active centers to receive photogenerated electrons for water splitting. However, their high loading concentration usually leads to the degradation of water splitting. Here, we present a different strategy for the design of the main catalyst and cocatalyst. We used small-sized ultrathin cadmium sulfide (CdS) nanosheets as the main catalysts and anchored them onto large-sized N -doped carbon nanotubes with encapsulated cobalts. The photocatalytic hydrogen production of our optimized composite is similar to 21.8 mmol/g, similar to 3 times higher than that of pure CdS. Mechanism study shows that photoelectrons can be transferred from CdS to N-doped carbon nanotubes, thus achieving fast charge separation and efficient hydrogen production.
Keyword ：
fast charge transfer fast charge transfer ultrathin CdS nanosheet ultrathin CdS nanosheet N-doped carbon nanotubes N-doped carbon nanotubes large-sized cocatalysts large-sized cocatalysts photocatalytic hydrogen production photocatalytic hydrogen production
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| GB/T 7714 | Zhang, Zhenghan , Li, Yuanli , Zhang, Hang et al. Ultrathin CdS Nanosheets Grown on N-Doped Carbon Nanotubes with Encapsulated Cobalts for Highly Improved Visible-Light-Driven Hydrogen Production [J]. | ACS APPLIED ENERGY MATERIALS , 2022 , 5 (12) : 15680-15688 . |
| MLA | Zhang, Zhenghan et al. "Ultrathin CdS Nanosheets Grown on N-Doped Carbon Nanotubes with Encapsulated Cobalts for Highly Improved Visible-Light-Driven Hydrogen Production" . | ACS APPLIED ENERGY MATERIALS 5 . 12 (2022) : 15680-15688 . |
| APA | Zhang, Zhenghan , Li, Yuanli , Zhang, Hang , Zhong, Jiaxing , Li, Weiming , Gao, Chunlang et al. Ultrathin CdS Nanosheets Grown on N-Doped Carbon Nanotubes with Encapsulated Cobalts for Highly Improved Visible-Light-Driven Hydrogen Production . | ACS APPLIED ENERGY MATERIALS , 2022 , 5 (12) , 15680-15688 . |
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Abstract ：
Sonochemical synthesis has flourished significantly in the last few decades for the preparation of pho-tocatalysts. A large number of photocatalysts have been prepared through sonochemical techniques. This review highlights the scope of sonochemistry in the preparation of photocatalysts, and their applications in energy production and environmental remediation. Beside, the sonochemical degradation of pollutants is discussed in detail. The progress made in sonochemical synthesis and the future perspective for this technique are summarized here. This review may create more enthusiasm among researchers to pay extra attention to the sonochemical synthesis of materials and add their useful contribution to the investiga-tion of new materials for photocatalytic and other applications. This will propel this technique toward commercial sonosynthesis of nanomaterials. (c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
Keyword ：
Photocatalysis Photocatalysis Sonochemistry Sonochemistry Energy production Energy production Environmental remediation Environmental remediation Acoustic cavitation Acoustic cavitation
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| GB/T 7714 | Qi, Kezhen , Zhuang, Chunqiang , Zhang, Manjie et al. Sonochemical synthesis of photocatalysts and their applications [J]. | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY , 2022 , 123 : 243-256 . |
| MLA | Qi, Kezhen et al. "Sonochemical synthesis of photocatalysts and their applications" . | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 123 (2022) : 243-256 . |
| APA | Qi, Kezhen , Zhuang, Chunqiang , Zhang, Manjie , Gholami, Peyman , Khataee, Alireza . Sonochemical synthesis of photocatalysts and their applications . | JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY , 2022 , 123 , 243-256 . |
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Abstract ：
Small-sized particles are usually used as cocatalysts and anchored onto a large-sized photocatalyst for fast charge separation. However, the current problem for the design of photocatalysts is that a high loading of small-sized particles leads to full coverage of photocatalysts, resulting in the decrease of hydrogen production. Here, we propose a different way to construct photocatalytic systems. Large-scale carbon nanotubes with doped nitrogen (N-CNTs) are used to couple with TiO2 quantum dots. The H-2 yield for our optimized photocatalytic system is similar to 146 mmol/g. With further considering the light-induced thermal effect, the H-2 yield reaches up to similar to 320.6 mmol/g. Electrochemical and spectroscopic data show that large-sized N-CNTs can offer abundant active sites to realize the rapid carrier separation for tremendously improved hydrogen production.
Keyword ：
N-CNTs N-CNTs TiO2 quantum dot TiO2 quantum dot photocatalytic H-2 photocatalytic H-2 light-thermal effect light-thermal effect effective carrier separation effective carrier separation
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| GB/T 7714 | Zhang, Zhenghan , Li, Yuanli , Zhong, Jiaxing et al. N-Doped Carbon Nanofibers Coupled with TiO2 Quantum Dots for Photocatalytic Hydrogen Production [J]. | ACS APPLIED NANO MATERIALS , 2022 , 6 (1) : 453-460 . |
| MLA | Zhang, Zhenghan et al. "N-Doped Carbon Nanofibers Coupled with TiO2 Quantum Dots for Photocatalytic Hydrogen Production" . | ACS APPLIED NANO MATERIALS 6 . 1 (2022) : 453-460 . |
| APA | Zhang, Zhenghan , Li, Yuanli , Zhong, Jiaxing , Zhang, Hui , Gao, Chunlang , Zhuang, Chunqiang . N-Doped Carbon Nanofibers Coupled with TiO2 Quantum Dots for Photocatalytic Hydrogen Production . | ACS APPLIED NANO MATERIALS , 2022 , 6 (1) , 453-460 . |
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Abstract ：
CO2 transports in the Earth's interior play a crucial role in understanding the deep carbon cycle and the global climate changes. Currently, CO2 transports inside of the Earth under extreme condition of pressure and temperature have not been understood well. In this study, the molecular dynamics (MD) calculations were performed to study CO2 transports under different CO2 pressures in slit-like magnesite pores with different pore sizes at 350 similar to 2500 K and 3 similar to 50 GPa are presented. Diffusion of CO2 in magnesite was improved as the temperature increases but showed the different features as a function of pressure. The diffusion coefficients of CO2 in magnesite were found in the range of 9x10(-12) m(2) s(-1) similar to 28000x10(-12) m(2) s(-1). Magnesite with the pore size of 20 similar to 25 angstrom corresponds to the highest transports. Anisotropic diffusion of CO2 in magnesite may help to understand the inhomogeneous distribution of carbon in the upper mantle. The time of CO2 diffusion from the mantle to Earth surface was estimated to be around several tens of Ma and has an important effect on deep carbon cycle. The simulation of CO2 transports based on the Earth condition provides new insights to revealing the deep carbon cycle in the Earth's interiors.
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| GB/T 7714 | Liu, Lei , Yang, Longxing , Zhuang, Chunqiang et al. Diffusion of CO2 in Magnesite under High Pressure and High Temperature from Molecular Dynamics Simulations [J]. | GEOFLUIDS , 2021 , 2021 . |
| MLA | Liu, Lei et al. "Diffusion of CO2 in Magnesite under High Pressure and High Temperature from Molecular Dynamics Simulations" . | GEOFLUIDS 2021 (2021) . |
| APA | Liu, Lei , Yang, Longxing , Zhuang, Chunqiang , Yang, Guangshu , Yi, Li , Liu, Hong et al. Diffusion of CO2 in Magnesite under High Pressure and High Temperature from Molecular Dynamics Simulations . | GEOFLUIDS , 2021 , 2021 . |
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Abstract ：
Recently, there are significant progresses in the growth of organic-inorganic lead halide perovskite single crystals, however, due to their susceptible nucleation and growth mechanisms and solvent requirements, the efficient and generalized growth for these single crystals is still challenging. Here we report the work towards this target with a polymer-controlled nucleation process for the highly efficient growth of large-size high-quality simple ternary, mixed-cations and mixed-halide perovskite single crystals. Among them, the carrier lifetime of FAPbBr3 single crystals is largely improved to 10199 ns. Mixed MA/FAPbBr3 single crystals are synthesized. The crucial point in this process is suggested to be an appropriate coordinative interaction between polymer oxygen groups and Pb2+, greatly decreasing the nuclei concentrations by as much as 4 orders of magnitudes. This polymer-controlled route would help optimizing the solution-based OIHPs crystal growth and promoting applications of perovskite single crystals.
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| GB/T 7714 | Ma Lin , Yan Zhengguang , Zhou Xiaoyuan et al. A polymer controlled nucleation route towards the generalized growth of organic-inorganic perovskite single crystals. [J]. | Nature communications , 2021 , 12 (1) : 2023 . |
| MLA | Ma Lin et al. "A polymer controlled nucleation route towards the generalized growth of organic-inorganic perovskite single crystals." . | Nature communications 12 . 1 (2021) : 2023 . |
| APA | Ma Lin , Yan Zhengguang , Zhou Xiaoyuan , Pi Yiqun , Du Yiping , Huang Jie et al. A polymer controlled nucleation route towards the generalized growth of organic-inorganic perovskite single crystals. . | Nature communications , 2021 , 12 (1) , 2023 . |
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Abstract ：
The common strategy for the design of photocatalytic materials is to load small-sized cocatalysts onto large-sized photocatalysts for efficient charge separation. In this study, a new design strategy is presented to anchor smallsized TiO2 photocatalysts onto large-sized Ti3C2-Mxene cocatalysts, which can provide enriched active sites to receive photo-generated electrons, thus achieving fast charge separation. Based on this strategy, the 4h-hydrogen production rate of the optimized photocatalytic system (62.5 mu mol) is 15.2 times higher than that of pure TiO2 (4.1 mu mol), strongly demonstrating the feasibility of our design strategy. The strategy here presents an effective way to design novel photocatalytic systems with superior photocatalytic properties.
Keyword ：
Photocatalytic water splitting Photocatalytic water splitting Design strategy Design strategy Large-sized cocatalyst Large-sized cocatalyst Ultra-small photocatalyst Ultra-small photocatalyst
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| GB/T 7714 | Li, Weiming , Zhuang, Chunqiang , Li, Yuanli et al. Anchoring ultra-small TiO2 & nbsp;quantum dots onto ultra-thin and large-sized Mxene nanosheets for highly efficient photocatalytic water splitting [J]. | CERAMICS INTERNATIONAL , 2021 , 47 (15) : 21769-21776 . |
| MLA | Li, Weiming et al. "Anchoring ultra-small TiO2 & nbsp;quantum dots onto ultra-thin and large-sized Mxene nanosheets for highly efficient photocatalytic water splitting" . | CERAMICS INTERNATIONAL 47 . 15 (2021) : 21769-21776 . |
| APA | Li, Weiming , Zhuang, Chunqiang , Li, Yuanli , Gao, Chunlang , Jiang, Wenshuai , Sun, Zaicheng et al. Anchoring ultra-small TiO2 & nbsp;quantum dots onto ultra-thin and large-sized Mxene nanosheets for highly efficient photocatalytic water splitting . | CERAMICS INTERNATIONAL , 2021 , 47 (15) , 21769-21776 . |
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Abstract ：
Photocatalytic hydrogen production from water splitting has received considerable attention in recent years. The bottle-neck issue for hydrogen production efficiency is the relative slow charge separation and efficient hydrogen evolution. Currently, the major strategy for developing catalysts is to anchor small noble-metal cocatalysts onto relatively large photocatalysts. In this study, extremely small photocatalysts of TiO2 quantum dots were loaded onto the low-cost micro-sized cocatalysts of porous NiO/NiS2 nanosheets, promoting the rapid charge separation of photogenerated electrons from small-sized photocatalysts to large-sized cocatalysts. The size of cocatalysts is three orders of magnitude larger than that of photocatalysts. The hydrogen production of designed catalysts is similar to 16 times higher than that of pure TiO2 photocatalysts, clearly demonstrating the critical role of large-sized porous cocatalysts. Our game-changing strategy provides a distinctive approach to design new kinds of photocatalysts with rapid charge separation and highly efficient hydrogen evolution.
Keyword ：
Cocatalyst Cocatalyst Photocatalyst Photocatalyst Fast charge separation Fast charge separation Micro-sized porous nanosheet Micro-sized porous nanosheet Quantum dot Quantum dot
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| GB/T 7714 | Li, Yuanli , Gao, Chunlang , Jiang, Wenshuai et al. A game-changing design of low-cost, large-size porous cocatalysts decorated by ultra-small photocatalysts for highly efficient hydrogen evolution [J]. | APPLIED CATALYSIS B-ENVIRONMENTAL , 2021 , 286 . |
| MLA | Li, Yuanli et al. "A game-changing design of low-cost, large-size porous cocatalysts decorated by ultra-small photocatalysts for highly efficient hydrogen evolution" . | APPLIED CATALYSIS B-ENVIRONMENTAL 286 (2021) . |
| APA | Li, Yuanli , Gao, Chunlang , Jiang, Wenshuai , Zhuang, Chunqiang , Tan, Wuyuan , Li, Weiming et al. A game-changing design of low-cost, large-size porous cocatalysts decorated by ultra-small photocatalysts for highly efficient hydrogen evolution . | APPLIED CATALYSIS B-ENVIRONMENTAL , 2021 , 286 . |
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Abstract ：
A key challenge in photocatalysts is their rapid recombination of photo-generated elec-tron-hole pairs. To decrease the recombination probability, significant studies have been devoted to increasing potential active sites of photocatalytic systems for fast charge separation. Here we demonstrate a strategy to boost active sites that is different from conventional approaches, in which large-sized Mxene nanosheets were employed as co-catalysts, while small-sized CdS nanosheets were used as photocatalysts forming effec-tive nanocomposites. Based on our designed strategy, the enrichment of transfer routes guides the fast separation of electrons from CdS nanosheets and transferred onto large-sized Mxene nanosheets. The visible-light-driven hydrogen production of our innova-tively designed composites has been improved from 2.8 mmol/g of pure CdS nanosheets to 17.5 mmol/g of the CdS@Mxene optimized composite. The obvious improvement of hydrogen production verifies the feasibility of our design strategy as a unique way to our tactic here can be extended to the design of other kinds of photocatalytic systems.
Keyword ：
Improved hydrogen evolution Improved hydrogen evolution Booming active sites Booming active sites Small-sized photocatalyst Small-sized photocatalyst Fast charge separation Fast charge separation Large-sized cocatalyst Large-sized cocatalyst
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| GB/T 7714 | Zhang, Hang , Li, Yuanli , Li, Weiming et al. Designing large-sized cocatalysts for fast charge separation towards highly efficient visible-light-driven hydrogen evolution [J]. | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2021 , 46 (56) : 28545-28553 . |
| MLA | Zhang, Hang et al. "Designing large-sized cocatalysts for fast charge separation towards highly efficient visible-light-driven hydrogen evolution" . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 46 . 56 (2021) : 28545-28553 . |
| APA | Zhang, Hang , Li, Yuanli , Li, Weiming , Zhuang, Chunqiang , Gao, Chunlang , Jiang, Wenshuai et al. Designing large-sized cocatalysts for fast charge separation towards highly efficient visible-light-driven hydrogen evolution . | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY , 2021 , 46 (56) , 28545-28553 . |
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