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学者姓名:杨艳玲
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Abstract :
In this work, a new ultrasound-assisted heterogeneous activation of persulfate by nano zero-valent iron (USnZVI/PS) technique was employed to regenerate powder activated carbon (PAC) that had been saturated with chloramphenicol (CAP). US-nZVI/PS process can successfully regenerate the CAP-saturated PAC. Response surface methodology was effectively performed and under the specific optimum regeneration conditions the actual experimental regeneration efficiency of PAC reached 93.96%. As evidenced by the results of EPR and quenching experiments, both SO4 center dot- and center dot OH were identified as the main reactive species responsible for the regeneration process. The regeneration process considerably promoted the generation of oxygen-derived surface functional groups.
Keyword :
Activated carbon Activated carbon Nano zero-valent iron Nano zero-valent iron Ultrasound Ultrasound Persulfate Persulfate In-situ regeneration In-situ regeneration
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GB/T 7714 | Zhang, Tingting , Yang, Yanling , Li, Xing et al. Ultrasound-assisted heterogeneous activation of persulfate by nano zero-valent iron (nZVI) for the PAC in-situ regeneration [J]. | APPLIED CATALYSIS O: OPEN , 2024 , 191 . |
MLA | Zhang, Tingting et al. "Ultrasound-assisted heterogeneous activation of persulfate by nano zero-valent iron (nZVI) for the PAC in-situ regeneration" . | APPLIED CATALYSIS O: OPEN 191 (2024) . |
APA | Zhang, Tingting , Yang, Yanling , Li, Xing , Zhou, Zhiwei , Wei, Bigui . Ultrasound-assisted heterogeneous activation of persulfate by nano zero-valent iron (nZVI) for the PAC in-situ regeneration . | APPLIED CATALYSIS O: OPEN , 2024 , 191 . |
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Abstract :
Rural sewage treatment facilitates nitrogen and phosphorus removal yet can be costly. To address this challenge, a cost-effective embedding material mainly consisting of heterotrophic nitrifying bacteria, activated alumina (AA), and a solid carbon source (HPMC) was applied to a tidal flow constructed wetlands (TFCWs); aimed at stable nitrogen and phosphorus removal under low carbon-to-nitrogen (C/N) ratios. The TFCWs could be shortened to 16 d of startup duration time compared with the control group; and improved the ammonia nitrogen (NH4+-N), total nitrogen (TN), and total phosphorus (TP) removal efficiencies to 98 %, 93 %, and 68 %, respectively. Also, effluent NH4+-N, TN, and TP in the enhanced TFCWs could be stable at 0.52 +/- 0.18, 1.23 +/- 0.45, and 0.75 +/- 0.25 mg/L, respectively. Microbial community analysis revealed that AA and HPMC were enriched Pseudomonas sp., which potentially accelerated the NH4+-N assimilation pathway and phosphate biological removal. Embedding materials-TFCWs can provide new solutions for integrated rural sewage technology.
Keyword :
removal removal Simultaneous nitrogen and phosphorus Simultaneous nitrogen and phosphorus Low C/N ratio Low C/N ratio Heterotrophic nitrifying bacteria Heterotrophic nitrifying bacteria Embedding Embedding Tidal flow constructed wetland Tidal flow constructed wetland
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GB/T 7714 | Wang, Yan-Lin , Yang, Yan-Ling , Tan, Xu et al. Enhanced nutrients removal from low C/N ratio rural sewage by embedding heterotrophic nitrifying bacteria and activated alumina in a tidal flow constructed wetland [J]. | BIORESOURCE TECHNOLOGY , 2024 , 413 . |
MLA | Wang, Yan-Lin et al. "Enhanced nutrients removal from low C/N ratio rural sewage by embedding heterotrophic nitrifying bacteria and activated alumina in a tidal flow constructed wetland" . | BIORESOURCE TECHNOLOGY 413 (2024) . |
APA | Wang, Yan-Lin , Yang, Yan-Ling , Tan, Xu , Li, Xing , Zhao, Li . Enhanced nutrients removal from low C/N ratio rural sewage by embedding heterotrophic nitrifying bacteria and activated alumina in a tidal flow constructed wetland . | BIORESOURCE TECHNOLOGY , 2024 , 413 . |
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Abstract :
Surfactants are increasingly used in systems that come into contact with the human body, such as food, pharmaceuticals, cosmetics and personal hygiene products. Increasing attention is being devoted to the toxic effects of surfactants in various human contact formulations, as well as the removal of residual surfactants. In the presence of ozone (O-3), anion surfactants-a characteristic micro-pollutant-such as sodium dodecylbenzene sulfonate (SDBS) in greywater, can be removed using radical advanced oxidation. Herein, we report a systematic study of the SDBS degradation effect of O-3 activated by vacuum ultraviolet (VUV) irradiation and the influence of water composition on VUV/O-3, and determined the contribution of radical species. We show a synergistic effect of VUV and O-3, while VUV/O-3 reached a higher mineralization (50.37%) than that of VUV (10.63%) and O-3 (29.60%) alone. The main reactive radicals of VUV/O-3 were HO center dot. VUV/O-3 had an optimal pH of 9. The addition of SO42- had almost no effect on the degradation of SDBS by VUV/O-3, Cl- and HCO3- slightly reduced the reaction rate, and NO3- had a significant inhibition on the degradation. In total, SDBS had three isomers, with which the three degradation pathways were very comparable. Compared with SDBS, the toxicity and harmfulness of the degradation by-products of the VUV/O-3 process decreased. Additionally, VUV/O-3 could degrade synthetic anion surfactants from laundry greywater effectively. Overall, the results show the potential of VUV/O-3 in safeguarding humans from residual surfactant hazards.
Keyword :
ozone ozone surfactants surfactants vacuum ultraviolet vacuum ultraviolet toxicological analysis toxicological analysis
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GB/T 7714 | Li, Hang , Yang, Yanling , Li, Xing et al. Remediation of Surfactants Used by VUV/O-3 Techniques: Degradation Efficiency, Pathway and Toxicological Analysis [J]. | MOLECULES , 2023 , 28 (8) . |
MLA | Li, Hang et al. "Remediation of Surfactants Used by VUV/O-3 Techniques: Degradation Efficiency, Pathway and Toxicological Analysis" . | MOLECULES 28 . 8 (2023) . |
APA | Li, Hang , Yang, Yanling , Li, Xing , Ullah, Habib . Remediation of Surfactants Used by VUV/O-3 Techniques: Degradation Efficiency, Pathway and Toxicological Analysis . | MOLECULES , 2023 , 28 (8) . |
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Abstract :
A novel visible photocatalysis nanomaterials Bi2O3/rGO/TiO2 (BRGT) was combined with polyethersulfone membrane (PES) and ceramic membrane (CM), respectively, to investigate the natural organic matter (NOM) removal performance, membrane fouling behavior and interfacial interactions. The results showed that NOM removal mainly by superoxide radical-dominated photocatalysis followed by membrane rejection enhancing the removal of fluorescent humic and proteins. Compared with PES, CM could more effectively retain the low molecular weight acidic intermediates and transitional or/and hydrophilic organic fractionations generated by photocatalysis. The mixture of NOM with BRGT (without photocatalysis) reduced the reversible fouling of the PES, causing an increase in the interfacial energy barrier of the fouling layer, while the opposite phenomenon was observed for CM. The photocatalysis time affected the membrane fouling, with short photocatalysis times (5 min) causing an increase in irreversible fouling. Extending the photocatalysis time, the interfacial interaction of the PES dominated by Lewis acid-base repulsive interaction gradually increased. And the gradual decreased of interfacial interaction of CM dominated by Lewis acid-base and Lifshitz-van der Waals attractive interactions reduced the possibility of reversible and irreversible fouling, respectively. This study provided a deeper mechanistic understanding for the application of a novel photocatalyst in combination with ultrafiltration.
Keyword :
Visible light photocatalysis Visible light photocatalysis Polyethersulfone membrane Polyethersulfone membrane Membrane fouling Membrane fouling Interface energy Interface energy Ceramic membrane Ceramic membrane
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GB/T 7714 | Yu, Rui , Yang, Yanling , Tian, Liping et al. Revealing the membrane fouling behavior and interfacial interaction mechanism in a combined visible light photocatalysis-ultrafiltration system for advanced purification of NOM [J]. | JOURNAL OF WATER PROCESS ENGINEERING , 2023 , 57 . |
MLA | Yu, Rui et al. "Revealing the membrane fouling behavior and interfacial interaction mechanism in a combined visible light photocatalysis-ultrafiltration system for advanced purification of NOM" . | JOURNAL OF WATER PROCESS ENGINEERING 57 (2023) . |
APA | Yu, Rui , Yang, Yanling , Tian, Liping , Li, Xing , Liu, Chunjiao , Sun, Tianjie et al. Revealing the membrane fouling behavior and interfacial interaction mechanism in a combined visible light photocatalysis-ultrafiltration system for advanced purification of NOM . | JOURNAL OF WATER PROCESS ENGINEERING , 2023 , 57 . |
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Abstract :
一种改性沸石除锰滤料的制备及快速启动方法,属于饮用水净化领域,所述的改性沸石除锰滤料是以天然沸石为原料,依次与一定浓度NaOH溶液、MnCl2·4H2O溶液以及KMnO4溶液震荡接触并沥水烘干而制得,快速启动方法是在接触氧化除锰滤池运行的初期,依次通过改性沸石除锰滤料的吸附耦合催化氧化除锰、高锰酸钾的强化氧化除锰,以及锰质活性滤膜的接触氧化除锰与高锰酸钾的强化氧化除锰的交替进行而实现的。本发明可解决天然锰砂产量不足、成本高、现有的接触氧化除锰滤池启动期长、启动期间存在锰超标风险等问题,不受地区、原水水质、滤池滤速的影响,可灵活应对各种锰超标的水源水,保障接触氧化除锰滤池在整个运行期间出水锰的稳定达标。
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GB/T 7714 | 李星 , 朱文博 , 杨艳玲 . 一种改性沸石除锰滤料的制备及快速启动方法 : CN202211022655.X[P]. | 2022-08-24 . |
MLA | 李星 et al. "一种改性沸石除锰滤料的制备及快速启动方法" : CN202211022655.X. | 2022-08-24 . |
APA | 李星 , 朱文博 , 杨艳玲 . 一种改性沸石除锰滤料的制备及快速启动方法 : CN202211022655.X. | 2022-08-24 . |
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Abstract :
Pre-ozonation is often used as an effective method to assist coagulation in removing organic contaminants. In this study, a new process that combining ozone (O-3) with vacuum ultraviolet (VUV/UV) process (VUV/UV/O-3) is investigated to enhance the removal of organic matters in greywater from public buildings or household. The influence of organic characteristics (molecular weight distribution, hydrophobicity, and fluorescence) in grey water on VUV/UV/O-3 enhanced coagulation has not been fully studied. Herein, organic matters of greywater were separated and classified, and fates of organic fractions by VUV/UV/O-3 enhanced coagulation were clarified. Greywater contains tryptophan-like and tyrosine-like proteins, and terrestrially derived humic-like substances. The highest UV254, LAS, DOC and CODCr removal efficiency from greywater could reach up to 47.54%, 58.92%, 17.96% and 15.76% in VUV/UV/O-3 enhanced coagulation, respectively. The removal efficiency of tryptophanlike and tyrosine-like in filtrates of varied molecular weight ranges by VUV/UV/O-3 enhanced coagulation was 93.59%-98.13% and 89.86%-95.53%, respectively. VUV/UV/O-3 enhanced coagulation was effective for the removal of bio-polymers, humic substances and low molecular weight acid <=& nbsp;30 kDa, while it was insignificant for that of 0.22 mu m 100 kDa. Particle size of flocs increased significantly in filtrates obtained from increasing membrane pore size, indicating that macromolecular organic matter was more likely to form flocs. Finally, the VUV/UV/O-3 could improve coagulation on the removal of varied organic pollutants and improve sedimentation by changing the flaky flocs to dense ones. Therefore, the results demonstrate VUV/UV/O-3 is an effective pre oxidation method to enhance the effect of coagulation on greywater treatment.
Keyword :
Vacuum ultraviolet Vacuum ultraviolet Pre-oxidation Pre-oxidation Coagulation Coagulation Ozone Ozone Greywater Greywater
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GB/T 7714 | Li, Hang , Yang, Yanling , Ren, Jiawei et al. Fate of organic fractions of greywater in combined process of vacuum-ultraviolet (VUV/UV)/ozone pre-oxidation with enhanced coagulation [J]. | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2022 , 10 (3) . |
MLA | Li, Hang et al. "Fate of organic fractions of greywater in combined process of vacuum-ultraviolet (VUV/UV)/ozone pre-oxidation with enhanced coagulation" . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 10 . 3 (2022) . |
APA | Li, Hang , Yang, Yanling , Ren, Jiawei , Zhou, Zhiwei , Li, Xing , Liu, Yuankun et al. Fate of organic fractions of greywater in combined process of vacuum-ultraviolet (VUV/UV)/ozone pre-oxidation with enhanced coagulation . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2022 , 10 (3) . |
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Abstract :
In-situ collection, purification and reuse of indoor greywater of public buildings or household is an effective way to save water resources. Refractory organic micropollutants in greywater, such as antibiotic sulfamethazine (SMT), can be potentially removed by sulfate radical-advanced oxidation process (SR-AOP) in the presence of peroxymonosulfate (PMS) or peroxydisulfate. Herein, vacuum ultraviolet (VUV) with irradiation at 185 nm and 254 nm activating PMS was systematically investigated in terms of degradation efficacy and influences of water constituents, and the contribution of photolysis and radical oxidative species was determined. We show that SMT removal efficiency and PMS photolysis efficiency of VUV/PMS were 2.2-fold and 1.45-fold compared to UV/PMS, respectively, and VUV/PMS reached a higher mineralization. The main active radicals of VUV/PMS were HO center dot, SO4 center dot-, and center dot O-2(-) . Compared to UV/PMS, VUV/PMS resulted in a higher proportion of oxidative degradation and a lower proportion of photolysis. Higher SMT concentrations competed for absorption of VUV or UV-generated photons with H2O and PMS molecules, resulting in a less efficient reaction. VUV/PMS was more efficient at lower initial SMT concentrations and had an optimal pH of 5. The presence of SO42- slightly accelerated degradation performance while HCO3- and NO3- inhibited both processes; the inhibitory effect of HCO3- and NO3- on VUV/ PMS are more significant than on UV/PMS. In contrast, the presence of Cl- had no significant effect on each process. In total, 13 intermediates of SMT were identified and four degradation pathways were proposed. VUV/PMS had an advantage over UV/PMS in removing the produced harmful and toxic intermediates. Furthermore, VUV/PMS could remove SMT from real water matrix more effectively than UV/PMS. Generally, the results demonstrate the potential of VUV to displace UV for more effective in-situ treatment of indoor greywater.
Keyword :
Sulfamethazine degradation Sulfamethazine degradation Indoor greywater Indoor greywater Vacuum ultraviolet Vacuum ultraviolet Peroxymonosulfate Peroxymonosulfate
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GB/T 7714 | Li, Hang , Yang, Yanling , Li, Xing et al. Degradation of sulfamethazine by vacuum ultraviolet-activated sulfate radical-advanced oxidation: efficacy, mechanism and influences of water constituents [J]. | SEPARATION AND PURIFICATION TECHNOLOGY , 2021 , 282 . |
MLA | Li, Hang et al. "Degradation of sulfamethazine by vacuum ultraviolet-activated sulfate radical-advanced oxidation: efficacy, mechanism and influences of water constituents" . | SEPARATION AND PURIFICATION TECHNOLOGY 282 (2021) . |
APA | Li, Hang , Yang, Yanling , Li, Xing , Zhou, Zhiwei , Feng, Jianyong , Dai, Yining et al. Degradation of sulfamethazine by vacuum ultraviolet-activated sulfate radical-advanced oxidation: efficacy, mechanism and influences of water constituents . | SEPARATION AND PURIFICATION TECHNOLOGY , 2021 , 282 . |
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Abstract :
As a key parameter in the adsorption process, removal rate is not available under most operating conditions due to the time and cost of experimental testing. To address this issue, evaluation of the efficiency of NH4+ removal from stormwater by coal-based granular activated carbon (CB-GAC), a novel approach, the response surface methodology (RSM), back-propagation artificial neural network (BP-ANN) coupled with genetic algorithm (GA), has been applied in this research. The sorption process was modeled based on Box-Behnben design (BBD) RSM method for independent variables: Contact time, initial concentration, temperature, and pH; suggesting a quadratic polynomial model with p-value 2 = 0.9762. The BP-ANN with a structure of 4-8-1 gave the best performance. Compared with the BBD-RSM model, the BP-ANN model indicated better prediction of the response with R2 = 0.9959. The weights derived from BP-ANN was further analyzed by Garson equation, and the results showed that the order of the variables’ effectiveness is as follow: Contact time (31.23%) > pH (24.68%) > temperature (22.93%) > initial concentration (21.16%). The process parameters were optimized via RSM optimization tools and GA. The results of validation experiments showed that the optimization results of GA-ANN are more accurate than BBD-RSM, with contact time = 899.41 min, initial concentration = 17.35 mg/L, temperature = 15 °C, pH = 6.98, NH4+ removal rate = 63.74%, and relative error = 0.87%. Furthermore, the CB-GAC has been characterized by Scanning electron microscopy (SEM), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET). The isotherm and kinetic studies of the adsorption process illustrated that adsorption of NH4+ onto CB-GAC corresponded Langmuir isotherm and pseudo-second-order kinetic models. The calculated maximum adsorption capacity was 0.2821 mg/g. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
Keyword :
Storms Storms Genetic algorithms Genetic algorithms Granular materials Granular materials Backpropagation Backpropagation Scanning electron microscopy Scanning electron microscopy Isotherms Isotherms Neural networks Neural networks Kinetic theory Kinetic theory Activated carbon Activated carbon Adsorption Adsorption
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GB/T 7714 | Yu, Aixin , Liu, Yuankun , Li, Xing et al. Modeling and optimizing of NH4+ removal from stormwater by coal-based granular activated carbon using RSM and ANN coupled with GA [J]. | Water (Switzerland) , 2021 , 13 (5) . |
MLA | Yu, Aixin et al. "Modeling and optimizing of NH4+ removal from stormwater by coal-based granular activated carbon using RSM and ANN coupled with GA" . | Water (Switzerland) 13 . 5 (2021) . |
APA | Yu, Aixin , Liu, Yuankun , Li, Xing , Yang, Yanling , Zhou, Zhiwei , Liu, Hongrun . Modeling and optimizing of NH4+ removal from stormwater by coal-based granular activated carbon using RSM and ANN coupled with GA . | Water (Switzerland) , 2021 , 13 (5) . |
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Abstract :
Vacuum ultraviolet/persulfate (VUV/PS) has been a prospective method for antibiotics removal, however, the enhanced degradation mechanism is still unclear. This study compared the sulfamethazine (SMT) degradation by VUV/PS and ultraviolet/persulfate (UV/PS) processes using a photoreaction system. Results showed that the SMT degradation rate and PS activation rate by VUV/PS was 1.36 times and 1.39 times those of the conventional UV/PS process under the same dosage of PS, respectively. VUV/PS also achieved a high SMT mineralization. SO4 center dot(-) and HO center dot played important roles in the degradation of SMT by both processes, while the role of center dot O-2(-) was little. SMT concentration changed the distributions of 185 nm and 254 nm photons absorbed by solution components and altered the initiated photolysis reaction. Both processes had faster degradation rates at low initial SMT concentrations and the optimum reaction condition was at solution pH of 5. The inhibited level of the SMT degradation in both processes by four anions was in the following order: NO3- > Cl- > HCO3- > SO42-. VUV/PS process was also more efficient than UV/PS for degrading environmental (200 mu g/L) and high (5 mg/L) concentration of SMT from three kinds of typical water matrices (tap, river and lake water). Finally, ten photo-products of SMT degradation by VUV (or UV) were identified, which were mainly the oxidized products of C-N, -NH2 and S-C on SMT molecules, and four degradation pathways were proposed. Overall, these findings could provide useful insights into the application of VUV/PS in efficient antibiotics removal from water.
Keyword :
Vacuum ultraviolet Vacuum ultraviolet Ultraviolet Ultraviolet Persulfate Persulfate Sulfamethazine Sulfamethazine Degradation pathway Degradation pathway
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GB/T 7714 | Li, Hang , Yang, Yan-Ling , Li, Xing et al. Enhanced degradation mechanism of sulfamethazine by vacuum ultraviolet/persulfate [J]. | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2021 , 9 (6) . |
MLA | Li, Hang et al. "Enhanced degradation mechanism of sulfamethazine by vacuum ultraviolet/persulfate" . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 9 . 6 (2021) . |
APA | Li, Hang , Yang, Yan-Ling , Li, Xing , Fan, Xiao-Yan , Wang, Nan . Enhanced degradation mechanism of sulfamethazine by vacuum ultraviolet/persulfate . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2021 , 9 (6) . |
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Abstract :
Constructed wetlands (CWs) usually exhibit limits in functional redundancy and diversity of microbial community contributing to lower performances of nutrients removal in decentralized domestic sewage treatment. To address this quandary, heterotrophic nitrification-aerobic denitrification (HN-AD) bacteria was added in tidal flow CWs (TFCWs) developing for nitrogen (N) and phosphorus (P) removal. With addition of HN-AD bacteria, TFCWs could be setup more rapidly and obtained better removal efficiencies of 66.9%-70.1% total nitrogen (TN), and 88.2%-92.4% total phosphorus (TP) comparing with control systems (TN: 53.9%; TP: 83.9%) during stable operation. Typical-cycles variations showed that TFCWs with addition of HN-AD bacteria promoted NO3--N and NH4+-N removal respectively under hydraulic retention time (HRT) of 14 h and 8 h with slight NO2--N accumulation. Activated alumina (AA) coupled with HN-AD bacteria decreased P release and relieved its poor removal performance in CWs. Based on metagenomic taxa and functional annotation, Pseudomonas and Thauera played pivotal roles in N removal in TFCWs. Furthermore, gradient oxic environments by 8 h-HRT promoted co-occurrence of heterotrophic nitrifiers (mostly Pseudomonas stutzeri) and autotrophic nitrifiers (mostly Nitrosomonas europaea. and Nitrospira sp.) which potentially accelerated NH4+-N transformation by elevated nitrification and denitrification related genes (e.g. amoABC, hao, napA and nirS genes). Meanwhile, the addition of HN-AD bacteria stimulated nirA and gltD genes of N assimilation processes probably leading to NH4+-N directly removal. The conceptual model of multi-metabolism regulation by HN-AD process highlighted importance of glk, gap2 and PK genes in glycolysis pathway which were vital drivers to nutrients metabolism. Overall, this study provides insights into how ongoing HN-AD bacteria addition effected microbial consortia and metabolic pathways, serving theoretical basis for its engineered applications of TFCWs in decentralized domestic sewage treatment. (C) 2021 Elsevier B.V. All rights reserved.
Keyword :
Tidal flow constructed wetlands Tidal flow constructed wetlands Heterotrophic nitrification-aerobic denitrification bacteria Heterotrophic nitrification-aerobic denitrification bacteria Metagenomics Metagenomics Enhanced N and P removal Enhanced N and P removal
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GB/T 7714 | Tan, Xu , Yang, Yan-Ling , Li, Xing et al. Multi-metabolism regulation insights into nutrients removal performance with adding heterotrophic nitrification-aerobic denitrification bacteria in tidal flow constructed wetlands [J]. | SCIENCE OF THE TOTAL ENVIRONMENT , 2021 , 796 . |
MLA | Tan, Xu et al. "Multi-metabolism regulation insights into nutrients removal performance with adding heterotrophic nitrification-aerobic denitrification bacteria in tidal flow constructed wetlands" . | SCIENCE OF THE TOTAL ENVIRONMENT 796 (2021) . |
APA | Tan, Xu , Yang, Yan-Ling , Li, Xing , Gao, Yu-Xi , Fan, Xiao-Yan . Multi-metabolism regulation insights into nutrients removal performance with adding heterotrophic nitrification-aerobic denitrification bacteria in tidal flow constructed wetlands . | SCIENCE OF THE TOTAL ENVIRONMENT , 2021 , 796 . |
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