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学者姓名:王如志
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Abstract :
Adopting noble metals on non-noble metals is an effective strategy to balance the cost and activity of electrocatalysts. Herein, a thorough analysis of the synergistic OER is conducted at the heterogeneous interface formed by Ir clusters and NiCo2O4 based on DFT calculations. Specifically, the electrons spontaneously bring an e(g) occupancy of interfacial Ir close to unity after the absorbed O, providing more transferable electrons for the conversion of the absorbed O-intermediates. Besides, the diffuse distribution of electrons in the Ir 5d orbital fills the antibonding orbital after O is absorbed, avoiding the desorption difficulties caused by the stronger Ir-O bonds. The electrons transfer from Ir to Co atoms at the heterogeneous interface and fill the Co 3d band near the Fermi level, stimulating the interfacial Co to participate in the direct O-O coupling (DOOC) pathway. Experimentally, the ultrathin-modulated NiCo2O4 nanosheets are used to support Ir clusters (Ir-cluster-E-NiCo2O4) by the electrodeposition method. The as-synthesized Ir-cluster-E-NiCo2O4 catalyst achieves a current density of 10 mA cm(-2) at an ultralow overpotential of 238 mV and works steadily for 100 h under a high current of 100 mA cm(-2), benefiting from the efficient DOOC pathway during the OER.
Keyword :
heterogeneous interfaces heterogeneous interfaces NiCo2O4 NiCo2O4 oxygen evolution reaction oxygen evolution reaction Ir clusters Ir clusters direct O-O coupling direct O-O coupling
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GB/T 7714 | Yang, Meng-Qi , Zhou, Kai-Ling , Zhao, Wei et al. Synergistic Assistance of Ir Clusters and NiCo2O4 Nanosheets Interfaces in Direct O-O Coupling for High-Efficiency Alkaline Oxygen Evolution [J]. | ACS APPLIED MATERIALS & INTERFACES , 2024 . |
MLA | Yang, Meng-Qi et al. "Synergistic Assistance of Ir Clusters and NiCo2O4 Nanosheets Interfaces in Direct O-O Coupling for High-Efficiency Alkaline Oxygen Evolution" . | ACS APPLIED MATERIALS & INTERFACES (2024) . |
APA | Yang, Meng-Qi , Zhou, Kai-Ling , Zhao, Wei , Wang, Changhao , Chen, Ge , Wang, Ru-Zhi . Synergistic Assistance of Ir Clusters and NiCo2O4 Nanosheets Interfaces in Direct O-O Coupling for High-Efficiency Alkaline Oxygen Evolution . | ACS APPLIED MATERIALS & INTERFACES , 2024 . |
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Abstract :
金属-半导体-金属(MSM)型氧化镓薄膜探测器的性能高度依赖于氧化镓薄膜的均匀性,工艺难度较高,对规模化、量产化薄膜探测器提出了挑战.本文首次在量产化悬臂式薄膜芯片表面物理沉积氧化镓薄膜,实现了一个五对叉指电极结构的MSM型氧化镓薄膜日盲探测器.得益于微机电系统(MEMS)工艺制备的悬臂式电极结构保护了内部电路与探测薄膜的完整均匀性,所获得的氧化镓薄膜虽然是非晶结构,但探测器仍然具备良好的紫外探测性能.在18 V偏压下其探测率达到7.9×1010 Jones,外量子效率达到1779%,上升和下降时间分别为1.22 s和0.24 s,接近晶体氧化镓薄膜的探测性能.该探测器在无任何光学聚焦系统的情况下,实现了对户外日光环境下脉冲电弧的灵敏检测,将在日盲探测领域具有良好的潜在应用价值.本工作基于MEMS工艺的悬臂式电极结构开发的敏感功能薄膜沉积技术,避免了功能薄膜大面积均匀性对刻蚀电路的影响,为MSM型薄膜探测器的制备提供了新的技术方法和工艺路线.
Keyword :
氧化镓 氧化镓 电弧检测 电弧检测 日盲探测器 日盲探测器
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GB/T 7714 | 张裕 , 刘瑞文 , 张京阳 et al. 氧化镓悬臂式薄膜日盲探测器及其电弧检测应用 [J]. | 物理学报 , 2024 , 73 (9) : 279-286 . |
MLA | 张裕 et al. "氧化镓悬臂式薄膜日盲探测器及其电弧检测应用" . | 物理学报 73 . 9 (2024) : 279-286 . |
APA | 张裕 , 刘瑞文 , 张京阳 , 焦斌斌 , 王如志 . 氧化镓悬臂式薄膜日盲探测器及其电弧检测应用 . | 物理学报 , 2024 , 73 (9) , 279-286 . |
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Abstract :
近年来,基于超材料的电磁吸波器件由于其宽带、易制备等优势而备受各国研究者的广泛关注.本文为实现宽带电磁低可探测,提出一种渐变电阻膜-介质复合结构的超材料吸波器.基于传输线理论和阻抗匹配原理,对强吸波条件进行了分析.在单元结构设计方面,采用遗传算法在多变量域内全局搜索最优解,快速地确定出能够兼顾低频与宽带吸波性能的超材料单元结构与电阻参数,并对器件吸波性能与吸波机理进行了深入的探讨.仿真结果表明,在垂直入射下,所设计的超材料吸波器对1.62—19.16 GHz (相对带宽168.8%)之间的入射波吸收率均大于90%,有效地向L和K波段拓展了吸收带宽.虽然在部分频段测试和仿真结果之间存在一定偏差,但两种类型的曲线随频率的变化趋势基本一致,这充分证明了所设计的超材料吸波器在低频宽带吸波领域具有潜在应用价值.
Keyword :
渐变电阻膜 渐变电阻膜 遗传算法 遗传算法 超材料吸波体 超材料吸波体
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GB/T 7714 | 王超 , 李绣峰 , 张生俊 et al. 基于遗传算法的宽带渐变电阻膜超材料吸波器设计 [J]. | 物理学报 , 2024 , 73 (07) : 117-127 . |
MLA | 王超 et al. "基于遗传算法的宽带渐变电阻膜超材料吸波器设计" . | 物理学报 73 . 07 (2024) : 117-127 . |
APA | 王超 , 李绣峰 , 张生俊 , 王如志 . 基于遗传算法的宽带渐变电阻膜超材料吸波器设计 . | 物理学报 , 2024 , 73 (07) , 117-127 . |
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Abstract :
采用基于密度泛函理论的投影平面波方法,对Ruddlesden-Popper(RP)层状钙钛矿结构Bi8Ba4Mn8O28的电子结构和磁学性质进行了自旋极化计算.由于A位Ba的替位掺杂,造成MnO6八面体发生显著旋转、倾斜等畸变,会对电子结构与磁性产生较大影响,对此进行了充分的讨论.考虑在位库伦作用修正的广义梯度近似(GGA+U)的计算表明,Bi8Ba4Mn8O28基态为铁磁半金属,其半金属能隙3.07 eV,晶胞总磁矩为31μB.Bi8Ba4Mn8O28的晶胞磁矩主要来自Mn原子磁矩的贡献,而Bi、Ba与O原子磁矩相对较小;而半金属性则主要源于Mn 3d自旋向上与自旋向下电子间存在较大的交换劈裂所致.使晶胞承受均匀变形,当其晶格常数在-10%~14%较大范围变化时,半金属性均可得到保持,且其晶胞总磁矩可始终稳定于31μB.
Keyword :
半金属 半金属 电子结构 电子结构 晶格形变 晶格形变 层状钙钛矿 层状钙钛矿 磁性 磁性 第一性原理 第一性原理
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GB/T 7714 | 张铭 , 张持 , 王朝 et al. Ruddlesden-Popper层状钙钛矿Bi8Ba4Mn8O28的电子结构与磁性的第一性原理 [J]. | 北京工业大学学报 , 2024 , 50 (6) : 665-673 . |
MLA | 张铭 et al. "Ruddlesden-Popper层状钙钛矿Bi8Ba4Mn8O28的电子结构与磁性的第一性原理" . | 北京工业大学学报 50 . 6 (2024) : 665-673 . |
APA | 张铭 , 张持 , 王朝 , 彭铠 , 李赛楠 , 马林昊 et al. Ruddlesden-Popper层状钙钛矿Bi8Ba4Mn8O28的电子结构与磁性的第一性原理 . | 北京工业大学学报 , 2024 , 50 (6) , 665-673 . |
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Abstract :
The wideband absorption and transmission of frequency-selective rasorber (FSR) remain a persistent challenge in the application of radar devices. In this article, a novel high performance wideband FSR design based on cross bend resonators was proposed. The FSR consists of an upper absorption lossy layer, which offers broad absorption and transmission bands, and a lower bandpass frequency-selective surface that enables a highly selective transmission of incident electromagnetic wave. Full wave simulation results showed that this novel design achieves an absorption bandwidth of 83.7% with more than 90% absorptivity in the frequency range of 5.2-12.7 GHz. Furthermore, the passband's fractional bandwidth for the insertion loss (IL) less than -3 dB is 33.9%, ranging from 14.9 to 21 GHz, with the minimum IL recorded at 0.69 dB at 17.7 GHz. To further verify the proposed method, a prototype FSR with 10 x 10 units of 120 mm x 120 mm was fabricated and the performance of the FSR was tested. The experiment results were in good agreement with the simulated results, and it showed a significant monostatic radar cross-section reduction in the frequency range of 5.3 GHz to 18.3 GHz compared with a metallic plane of the same size.
Keyword :
wideband transmission wideband transmission cross bend resonators (CBR) cross bend resonators (CBR) radar cross-section (RCS) reduction radar cross-section (RCS) reduction absorption absorption frequency selective rasorber (FSR) frequency selective rasorber (FSR)
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GB/T 7714 | Li, Xiu-Feng , Wang, Chao , Wang, Bing et al. Frequency selective rasorber based on cross bend resonators for wideband transmission and absorption [J]. | JOURNAL OF PHYSICS D-APPLIED PHYSICS , 2024 , 57 (34) . |
MLA | Li, Xiu-Feng et al. "Frequency selective rasorber based on cross bend resonators for wideband transmission and absorption" . | JOURNAL OF PHYSICS D-APPLIED PHYSICS 57 . 34 (2024) . |
APA | Li, Xiu-Feng , Wang, Chao , Wang, Bing , Du, JunZhao , Zhang, Sheng-Jun , Wang, Ru-Zhi . Frequency selective rasorber based on cross bend resonators for wideband transmission and absorption . | JOURNAL OF PHYSICS D-APPLIED PHYSICS , 2024 , 57 (34) . |
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Abstract :
The distinctive characteristics of alloy catalysts, encompassing composition, structure, and modifiable adsorption sites, present significant potential for the development of highly efficient electrocatalysts for oxygen evolution/reduction reactions [oxygen evolution reactions (OERs)/oxygen reduction reactions (ORRs)]. Machine learning (ML) methods can quickly establish the relationship between material features and catalytic activity, thus accelerating the development of alloy electrocatalysts. However, the current abundance of features presents a crucial challenge in selecting the most pertinent ones. In this study, we explored seven intrinsic features directly derived from the material's structure, with a specific focus on the chemical environment of active sites and their nearest neighbors. An accurate and efficient ML model to predict potential bifunctional oxygen electrocatalysts based on the intrinsic features of AB-type alloy active sites and intermediate free energies in the OERs/ORRs was established. These features possess clear physical and chemical meanings, closely linked to the electronic and geometric structures of active sites and neighboring atoms, thereby providing indispensable insights for the discovery of high-performance electrocatalysts. The ML model achieved R-2 scores of 0.827, 0.913, and 0.711 for the predicted values of the three intermediate (OH, O, OOH) free energies, with corresponding mean absolute errors of 0.175, 0.242, and 0.200 eV, respectively. These results indicate that the ML model exhibits high accuracy in predicting the intermediate free energies. Furthermore, the ML model exhibited a prediction efficiency 150,000 times faster than traditional density functional theory calculations. This work will offer valuable insights and a framework for facilitating the rapid design of potential catalysts by ML methods.
Keyword :
density functional theory density functional theory intrinsicfeatures intrinsicfeatures alloy catalysts alloy catalysts machine learning machine learning bifunctionaloxygen electrocatalyst bifunctionaloxygen electrocatalyst active sites active sites
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GB/T 7714 | Wang, Chao , Wang, Bing , Wang, Changhao et al. Efficient Machine Learning Model Focusing on Active Sites for the Discovery of Bifunctional Oxygen Electrocatalysts in Binary Alloys [J]. | ACS APPLIED MATERIALS & INTERFACES , 2024 , 16 (13) : 16050-16061 . |
MLA | Wang, Chao et al. "Efficient Machine Learning Model Focusing on Active Sites for the Discovery of Bifunctional Oxygen Electrocatalysts in Binary Alloys" . | ACS APPLIED MATERIALS & INTERFACES 16 . 13 (2024) : 16050-16061 . |
APA | Wang, Chao , Wang, Bing , Wang, Changhao , Chang, Zhipeng , Yang, Mengqi , Wang, Ruzhi . Efficient Machine Learning Model Focusing on Active Sites for the Discovery of Bifunctional Oxygen Electrocatalysts in Binary Alloys . | ACS APPLIED MATERIALS & INTERFACES , 2024 , 16 (13) , 16050-16061 . |
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Abstract :
一种多场景环境自适应气体半导体阵列气体传感装置涉及气体组分传感技术领域。传统的气体检测仪器通常只能检测一种或少数几种气体成分,而且受环境影响较大,检测精度和灵敏度有限;同时,在未知突发情况的使用具有极大的限制性。记忆合金片以及空心合金杆;该装置包括多个记忆合金片相互重叠包覆于所述空心合金杆的侧壁上;每个所述记忆合金片上设置有半导体气体传感阵列。多个所述记忆合金片相互重叠包覆于所述空心合金杆的侧壁上;该装置能够同时检测多种气体成分,具有快速响应、高稳定性等优点,同时能够适用多种使用环境。
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GB/T 7714 | 姚远舟 , 张京阳 , 王如志 . 一种多场景环境自适应气体半导体阵列气体传感装置 : CN202321427272.0[P]. | 2023-06-06 . |
MLA | 姚远舟 et al. "一种多场景环境自适应气体半导体阵列气体传感装置" : CN202321427272.0. | 2023-06-06 . |
APA | 姚远舟 , 张京阳 , 王如志 . 一种多场景环境自适应气体半导体阵列气体传感装置 : CN202321427272.0. | 2023-06-06 . |
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Abstract :
本实用新型提供一种吸水材料吸水性检测装置,包括收集箱和检测装置,收集箱的内壁插设有塞子;收集箱的表面设有检测装置,检测装置包括放置板,放置板位于收集箱的表面,放置板的两侧均固定连接有转盘,收集箱表面靠近转盘的位置开设有转孔,收集箱的侧壁设有配重装置,配重装置包括收纳箱,收纳箱的侧壁和收集箱侧壁固定连接,收纳箱的内壁插设有多个配重块;通过设置放置板和框架能够在一定程度上固定吸水材料位置,同时转盘和定位销的设置能够调节放置板的角度,以此适配不同需求,同时水箱也能够持续性对吸水材料加水,从而方便对吸水材料吸水性进行检测。
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GB/T 7714 | 姚远舟 , 王如志 . 一种吸水材料吸水性检测装置 : CN202321163133.1[P]. | 2023-05-15 . |
MLA | 姚远舟 et al. "一种吸水材料吸水性检测装置" : CN202321163133.1. | 2023-05-15 . |
APA | 姚远舟 , 王如志 . 一种吸水材料吸水性检测装置 : CN202321163133.1. | 2023-05-15 . |
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一种钙钛矿‑晶硅叠层太阳能电池结构,属于太阳能电池领域。包括钙钛矿顶电池、晶硅底电池与复合结层。所述钙钛矿顶电池依次设置为金属电极、透明电极层、空穴传输层、钙钛矿光吸收层、电子传输层;所述晶硅底电池依次设置为氧化钼空穴传输层、本征氢化非晶硅钝化层、晶硅光吸收层、本征氢化非晶硅钝化层、氟化锂/铝复合电极层;钙钛矿电池与底电池之间通过复合结相联结。本实用新型使用氧化钼作为晶硅底电池的空穴传输层,具有更好的空穴选择性以及更小的寄生吸收,使用氟化锂/铝作为晶硅底电池的复合电极,可以降低晶硅与电极间的肖特基势垒,有利于电子的传输,提升了单个太阳能电池器件的光电转换效率。
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GB/T 7714 | 郑子龙 , 杨熙其 , 严辉 et al. 一种钙钛矿-晶硅叠层太阳能电池结构 : CN202320566535.X[P]. | 2023-03-21 . |
MLA | 郑子龙 et al. "一种钙钛矿-晶硅叠层太阳能电池结构" : CN202320566535.X. | 2023-03-21 . |
APA | 郑子龙 , 杨熙其 , 严辉 , 张永哲 , 陈小青 , 王如志 . 一种钙钛矿-晶硅叠层太阳能电池结构 : CN202320566535.X. | 2023-03-21 . |
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Abstract :
Selective infrared radiation is crucial for achieving infrared stealth and heat dissipation. Artificially designed superstructure film (SF) provides several advantages for controlling and modulating infrared radiation, making them a promising solution for these applications. The research described in this work has successfully produced broadband selective infrared radiation by using a surface made up of circular patches that are combined. Numerical simulations show that this SF can achieve broadband selective radiation with 3-5 mu m mid-wave infrared (MWIR) suppression and 8-14 mu m long-wave infrared (LWIR) emission. The spectral selectivity can be easily switched to high emissivity in MWIR and low emissivity in LWIR by simply changing the basal layer. The resonance mechanism for achieving broadband spectral selectivity in the SF may be due to a combination of multimode plasmon resonances that are induced by the structural nonrotational symmetry of the circular patches. By applying the selective radiation SF on the tail nozzle or the vehicle, the effect of thermal management is very significant. Selective radiation SF can reduce radiant energy in the 3-5 mu m band by a significant amount at 500 degrees C, resulting in a 46 degrees C cooler temperature than that at the body without the SF. At 80 degrees C, radiated energy in the 8-14 mu m band is also considerably reduced and the temperature is 10 degrees C lower than that of the body without the SF. There will be obvious advantages in potential applications for infrared stealth and heat dissipation by the designed SF, a simple and convenient manufacturing process.
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GB/T 7714 | An, Ze-Lin , Liu, Li , Liu, Li-Ying et al. Broadband spectrally selective infrared radiation and its applications of a superstructure film of combined circular patches [J]. | JOURNAL OF APPLIED PHYSICS , 2023 , 133 (24) . |
MLA | An, Ze-Lin et al. "Broadband spectrally selective infrared radiation and its applications of a superstructure film of combined circular patches" . | JOURNAL OF APPLIED PHYSICS 133 . 24 (2023) . |
APA | An, Ze-Lin , Liu, Li , Liu, Li-Ying , Wang, Chao , Ai, Li-Hong , Zhang, Sheng-Jun et al. Broadband spectrally selective infrared radiation and its applications of a superstructure film of combined circular patches . | JOURNAL OF APPLIED PHYSICS , 2023 , 133 (24) . |
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