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学者姓名：李建荣
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Abstract ：
As a class of functional crystalline porous materials, metal-organic frameworks (MOFs) gained rapid development in the past three decades and a large number of MOFs with ordered structures, high surface areas, and functionalized channels have been investigated. MOFs and MOF-derived/composite materials show great potential in many application fields. In this review, we discussed the main applications of MOFs and MOF-derived/composite materials in small molecule storage, separation, luminescence, sensing, multitype catalysis, and energy storage. In addition, challenges and problems in the future research of MOFs-related fields are also discussed.
Keyword ：
multitype catalysis multitype catalysis metal-organic frameworks metal-organic frameworks sensing and detection sensing and detection storage and separation storage and separation energy storage energy storage
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| GB/T 7714 | Pang, Jiandong , Jiang, Wentao , Zhang, Xue-Wen et al. Recent progress in metal-organic frameworks (Part II-material application) [J]. | SCIENCE CHINA-CHEMISTRY , 2025 . |
| MLA | Pang, Jiandong et al. "Recent progress in metal-organic frameworks (Part II-material application)" . | SCIENCE CHINA-CHEMISTRY (2025) . |
| APA | Pang, Jiandong , Jiang, Wentao , Zhang, Xue-Wen , Zhou, Hao-Long , Sun, Yuxiu , Gong, Wei et al. Recent progress in metal-organic frameworks (Part II-material application) . | SCIENCE CHINA-CHEMISTRY , 2025 . |
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Abstract ：
Rational regulation of interface structure in photocatalysts is a promising strategy to improve the photocatalytic performance of carbon dioxide (CO2) reduction. However, it remains a challenge to modulate the interface structure of multi-component heterojunctions. Herein, a strategy integrating heterojunction with facet engineering is developed to modulate the interface structure of metal-organic frameworks (MOF)-based heterojunctions. A series of core-shell UiO-66 (Zr-MOF)-loaded MIL-125 (Ti-MOF) heterojunctions with exposed specific facets were prepared to enhance the separation efficiency of photogenerated electrons-holes in CO2 photoreduction. Impressively, MIL-125to@UiO-66 with exposed {1 1 1} facet exhibits an excellent CO production rate (56.4 mu mol g- 1 h- 1) and selectivity (99 %) under visible light irradiation without any photosensitizers/ sacrificial agents, being 1.4 and 11.3 times higher than individual MIL-125to and UiO-66, respectively. The typeII heterojunction significantly enhances the separation of photogenerated electrons-holes in physical space. The photogenerated electrons migrate from Zr in UiO-66 to Ti in MIL-125to, promoting a spatial synergy between CO2 reduction on MIL-125to and H2O oxidation on UiO-66. Compared with MIL-125rd@UiO-66 with exposed {1 1 0} facet and MIL-125ds@UiO-66 with exposed {0 0 1} facet, MIL-125to@UiO-66 with exposed {1 1 1} facet improves the exposure of surface-active Ti sites, thereby enhancing the adsorption/activation of CO2 to generate the *COOH intermediate. This work provides an effective strategy for designing MOF-based heterojunction photocatalysts to improve photocatalytic performance.
Keyword ：
CO2 photoreduction CO2 photoreduction Metal-organic framework Metal-organic framework MOF-based photocatalyst MOF-based photocatalyst Charge transfer Charge transfer Interface structure Interface structure
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| GB/T 7714 | Ma, Xiaoyu , Zhang, Yan , Zhou, Awu et al. Modulation of interface structure on titanium-based metal-organic frameworks heterojunctions for boosting photocatalytic carbon dioxide reduction [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2025 , 685 : 696-705 . |
| MLA | Ma, Xiaoyu et al. "Modulation of interface structure on titanium-based metal-organic frameworks heterojunctions for boosting photocatalytic carbon dioxide reduction" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 685 (2025) : 696-705 . |
| APA | Ma, Xiaoyu , Zhang, Yan , Zhou, Awu , Jia, Yutong , Xie, Zhenghe , Ding, Lifeng et al. Modulation of interface structure on titanium-based metal-organic frameworks heterojunctions for boosting photocatalytic carbon dioxide reduction . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2025 , 685 , 696-705 . |
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Abstract ：
Metal-organic frameworks (MOFs), as an emerging class of porous materials, demonstrated substantial potential for applications in chemical engineering processes. However, their production often generates significant waste including ionic residues and organic solvents, posing considerable environmental concerns. Herein, we report the environmentally benign MOF synthesis with metal oxides precursors, yielding water as the exclusive by-product. This approach not only enhances atom economy but also promotes solvent recycling by preventing anion accumulation, significantly reducing waste generation. The synthesis can be easily scaled up in a 10-L reactor with an impressive space-time yield of 608 kgm-3day-1. Furthermore, MOF-76(Y) was implemented in a reactor for catalytic cycloaddition reaction at kg-scale. Through optimization of the interfacial contact between CO2 and the reaction liquid phase, a yield of 96.7% was achieved under mild conditions. This work demonstrates a rare example of scalable and sustainable synthesis of MOF materials coupled with catalysis implementation at kilogram scale.
Keyword ：
metal-organic framework metal-organic framework solvent recycling solvent recycling scalable synthesis scalable synthesis cycloaddition cycloaddition catalysis catalysis
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| GB/T 7714 | Zhang, Xin , Bai, Xuefeng , Li, Yi et al. An atomically economical and environmentally benign approach for the scalable synthesis of rare-earth metal-organic framework catalysts [J]. | AICHE JOURNAL , 2025 , 71 (5) . |
| MLA | Zhang, Xin et al. "An atomically economical and environmentally benign approach for the scalable synthesis of rare-earth metal-organic framework catalysts" . | AICHE JOURNAL 71 . 5 (2025) . |
| APA | Zhang, Xin , Bai, Xuefeng , Li, Yi , Xie, Yabo , Zhang, Run-Ji , Chen, Da-Yu et al. An atomically economical and environmentally benign approach for the scalable synthesis of rare-earth metal-organic framework catalysts . | AICHE JOURNAL , 2025 , 71 (5) . |
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Abstract ：
Nitrous oxide (N2O) is a potent greenhouse gas and a major contributor to ozone depletion. Its primary industrial emission source is tail gas from adipic acid production, which typically comprises a mixture of N2O, CO2, N2, and O2. Current technologies for the removal of N2O and CO2 from tail gas are energy-intensive and operationally complex. Herein, for the first time, simultaneous capture of N2O and CO2 from the quaternary mixture is achieved using a Ni(II)-pyrazolecarboxylate framework, BUT-167. This material demonstrated an exceptional adsorption capacity (135.8 cm3 cm-3 at 40 kPa) and a high packing density (790 mg cm-3) for N2O, outperforming reported sorbents. Moreover, BUT-167 also exhibits a remarkable CO2 adsorption capacity (101.5 cm3 cm-3 at 4 kPa), achieving simultaneously high selectivity values of 257.6 for CO2/N2 (4:96, v/v) and 135.7 for N2O/N2 (40/60). Importantly, BUT-167 exhibits robust and outstanding dual-gas removal performance across multiple adsorption-desorption breakthrough cycles under both dry and humid conditions. The strong affinity toward CO2 and N2O could be attributed to multiple hydrogen bonding interactions facilitated by its highly confined channel structure, as confirmed through single-crystal X-ray diffraction analysis.
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| GB/T 7714 | Zhang, Xin , Li, Muzi , Zhao, Yan-long et al. Simultaneous Capture of N2O and CO2 from a N2O/N2/CO2/O2 Mixture with a Ni(II)-Pyrazolecarboxylate Framework [J]. | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2025 . |
| MLA | Zhang, Xin et al. "Simultaneous Capture of N2O and CO2 from a N2O/N2/CO2/O2 Mixture with a Ni(II)-Pyrazolecarboxylate Framework" . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2025) . |
| APA | Zhang, Xin , Li, Muzi , Zhao, Yan-long , Li, Xiang-Yu , Fang, Yu , Xie, Lin-Hua et al. Simultaneous Capture of N2O and CO2 from a N2O/N2/CO2/O2 Mixture with a Ni(II)-Pyrazolecarboxylate Framework . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2025 . |
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Abstract ：
Framework materials (FMs) have been extensively investigated with a plethora of literature documenting their unique properties and potential applications. Despite this, a comprehensive knowledge graph for this emerging field has not yet been constructed. In this study, by utilizing the natural language processing capabilities of large language models (LLMs), we have established a comprehensive knowledge graph (KG-FM). It covers synthesis, properties, applications, and other aspects of FMs including metal-organic frameworks (MOFs), covalent-organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs). The knowledge graph was constructed through the analysis of over 100,000 articles, resulting in 2.53 million nodes and 4.01 million relationships. Subsequently, its application has been explored for enhancing data retrieval, mining, and the development of sophisticated question-answering systems. Especially when integrating the KGs with LLMs, resulted Qwen2-KG not only achieves a higher accuracy rate of 91.67% in question-answering than existing models but also provides precise information sources.
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| GB/T 7714 | Bai, Xuefeng , He, Song , Li, Yi et al. Construction of a knowledge graph for framework material enabled by large language models and its application [J]. | NPJ COMPUTATIONAL MATERIALS , 2025 , 11 (1) . |
| MLA | Bai, Xuefeng et al. "Construction of a knowledge graph for framework material enabled by large language models and its application" . | NPJ COMPUTATIONAL MATERIALS 11 . 1 (2025) . |
| APA | Bai, Xuefeng , He, Song , Li, Yi , Xie, Yabo , Zhang, Xin , Du, Wenli et al. Construction of a knowledge graph for framework material enabled by large language models and its application . | NPJ COMPUTATIONAL MATERIALS , 2025 , 11 (1) . |
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Abstract ：
As the focus evolves from structure discovery/characterization (what it is) to property/performance exploration (what it is for), the pursuit of stable functional metal-organic frameworks (MOFs) has been ongoing in terms of both fundamental research and industrial implementation. Under the guidance of crystal engineering principles, a plethora of research has developed pyrazolate MOFs (metal pyrazaolate frameworks, MPFs) featuring strong coordination M-N bonding. This attribution helps them retain their structures and functions under the alkaline conditions required for practical use. Based on poly-topic pyrazolate ligands, various classic MOFs, such as Co(bdp), Fe2(BDP)3, Ni8L6, PCN-601, and BUT-55, to name a few, have revealed fascinating architectures, intriguing properties, and record-breaking performances in applications during the past decade. This review will present the full scope of MPFs to date: (1) the superiority and significance of constructing MPFs through the crystal engineering approach, (2) synthetic strategies adopted in building and/or modifying MPFs, (3) structural features and stability of the MPF community, and (4) potential applications in energy and environmental related fields. The future opportunities of MPFs are also discussed for designing the next-generation of smart materials. Overall, this review attempts to provide insights and guidelines for the customization of pyrazolate-based MOFs for specific purposes, which would also promote the development of stable functional porous materials for addressing societal challenges.
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| GB/T 7714 | Kong, Xiang-Jing , Si, Guang-Rui , He, Tao et al. Metal pyrazolate frameworks: crystal engineering access to stable functional materials [J]. | CHEMICAL SOCIETY REVIEWS , 2025 , 54 (8) . |
| MLA | Kong, Xiang-Jing et al. "Metal pyrazolate frameworks: crystal engineering access to stable functional materials" . | CHEMICAL SOCIETY REVIEWS 54 . 8 (2025) . |
| APA | Kong, Xiang-Jing , Si, Guang-Rui , He, Tao , Li, Jian-Rong . Metal pyrazolate frameworks: crystal engineering access to stable functional materials . | CHEMICAL SOCIETY REVIEWS , 2025 , 54 (8) . |
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Abstract ：
The newly reported crystalline phosphorus nanosheets (cryst-P NSs) exhibit promising features for industrial applications, including outstanding air-water stability and facile large-scale production. However, their complex crystallization impedes a priori tailoring. Herein, the temporal evolution of cryst-P NSs was investigated with the optimized synthesis parameters. The occurrence of self-assembly and solid-state rearrangement unveiled the existence of an intermediate phase as the bulk crystalline precursor and the predominance of nonclassical crystallization pathway(s). With the upgraded synthesis protocol simultaneously strengthening the merits of cryst-P NSs, their catalytic performances were evaluated in various electro- and/or photocatalytic reactions spanning hydrogen and oxygen evolution, full water splitting, CO2 reduction, and organic pollutant decomposition. Superior catalytic activities and orders of magnitude longer lifetimes were consistently discerned compared with the widely employed black phosphorus nanosheets with similar size and thickness. The exciting discoveries in both fundamental crystallization and catalytic applications drastically thrust the comprehension of elemental phosphorus, shedding light on the encouraging capabilities of solvothermal synthesis strategies in the design and systematic tailoring of phosphorus materials.
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| GB/T 7714 | Batur, Jenaidullah , Duan, Zunbin , Jin, Ruipeng et al. Enhanced Catalytic Activity of Crystalline Phosphorus Nanosheets Fabricated via Solvothermal Phase Transformation [J]. | INORGANIC CHEMISTRY , 2024 , 63 (25) : 11860-11869 . |
| MLA | Batur, Jenaidullah et al. "Enhanced Catalytic Activity of Crystalline Phosphorus Nanosheets Fabricated via Solvothermal Phase Transformation" . | INORGANIC CHEMISTRY 63 . 25 (2024) : 11860-11869 . |
| APA | Batur, Jenaidullah , Duan, Zunbin , Jin, Ruipeng , Li, Rui , Xie, Yabo , Yu, Xue-Feng et al. Enhanced Catalytic Activity of Crystalline Phosphorus Nanosheets Fabricated via Solvothermal Phase Transformation . | INORGANIC CHEMISTRY , 2024 , 63 (25) , 11860-11869 . |
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Sulfur hexafluoride (SF6) is extensively employed in the power industry. However, its emissions significantly contribute to the greenhouse effect. The direct recovery of high purity SF6 from industrial waste gases would benefit its sustainable use, yet this represents a considerable challenge. Herein, we report the enrichment of SF6 from SF6/N-2 mixtures via adsorptive separation in a stable Co(II)-pyrazolate MOF BUT-53 (BUT: Beijing University of Technology), which features dynamic molecular traps. BUT-53 exhibits an excellent SF6 adsorption uptake of 2.82 mmol/g at 0.1 bar and 298 K, as well as an unprecedented SF6/N-2 (10:90) selectivity of 2485. Besides, the remarkable SF6/N-2 selectivity of BUT-53 enables recovery of high purity (>99.9%) SF6 from a low concentration (10%) mixture through a breakthrough experiment. The excellent SF6/N-2 separation efficiency was also well maintained under humid conditions (RH = 90%) over multiple cycles. Molecular simulation, single-crystal diffraction, and adsorption kinetics studies elucidate the associated adsorption mechanism and water tolerance.
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| GB/T 7714 | Zhang, Xin , Zhao, Yan-Long , Li, Xiang-Yu et al. Recovery of High-Purity SF6 from Humid SF6/N2 Mixture within a Co(II)-Pyrazolate Framework [J]. | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2024 , 146 (28) : 19303-19309 . |
| MLA | Zhang, Xin et al. "Recovery of High-Purity SF6 from Humid SF6/N2 Mixture within a Co(II)-Pyrazolate Framework" . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 146 . 28 (2024) : 19303-19309 . |
| APA | Zhang, Xin , Zhao, Yan-Long , Li, Xiang-Yu , Bai, Xuefeng , Chen, Qiancheng , Li, Jian-Rong . Recovery of High-Purity SF6 from Humid SF6/N2 Mixture within a Co(II)-Pyrazolate Framework . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2024 , 146 (28) , 19303-19309 . |
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Abstract ：
Transformation between oxidation states is widespread in transition metal coordination chemistry and biochemistry, typically occurring in solution. However, air-induced oxidation in porous crystalline solids with retention of crystallinity is rare due to the dearth of materials with high structural stability that are inherently redox active. Herein, we report a new family of such materials, four isostructural cobalt-pyrazolate frameworks of face-centered cubic, fcu, topology, fcu-L-Co, that are sustained by Co8 molecular building blocks (MBBs) and dipyrazolate ligands, L. fcu-L-Co were observed to spontaneously transform from Co(II)8 to Co(III)8 MBBs in air with retention of crystallinity, marking the first such instance in metal-organic frameworks (MOFs). This transformation can also be achieved through water vapor sorption cycling, heating, or chemical oxidation. The reverse reactions were conducted by exposure of fcu-L-Co(III) to aqueous hydrazine. fcu-L-Co(II) exhibited high gravimetric water vapor uptakes of 0.55-0.68 g(-1) at 30% relative humidity (RH), while in fcu-L-Co(III) the inflection point shifted to lower RH and framework stability improved. Insight into the transformation between fcu-L-Co(II) and fcu-L-Co(III) was gained from single crystal X-ray diffraction and in situ spectroscopy. Overall, the crystal engineering approach we adopted has afforded a new family of MOFs that exhibit cobalt redox chemistry in a confined space coupled with high porosity.
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| GB/T 7714 | Kong, Xiang-Jing , He, Tao , Bezrukov, Andrey A. et al. Reversible Co(II)-Co(III) Transformation in a Family of Metal-Dipyrazolate Frameworks [J]. | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2024 , 146 (41) : 28320-28328 . |
| MLA | Kong, Xiang-Jing et al. "Reversible Co(II)-Co(III) Transformation in a Family of Metal-Dipyrazolate Frameworks" . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 146 . 41 (2024) : 28320-28328 . |
| APA | Kong, Xiang-Jing , He, Tao , Bezrukov, Andrey A. , Darwish, Shaza , Si, Guang-Rui , Zhang, Yong-Zheng et al. Reversible Co(II)-Co(III) Transformation in a Family of Metal-Dipyrazolate Frameworks . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2024 , 146 (41) , 28320-28328 . |
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Abstract ：
Along with the development of machine learning, deep learning, and large language models (LLMs) such as GPT-4 (GPT: Generative Pre-Trained Transformer), artificial intelligence (AI) tools have been playing an increasingly important role in chemical and material research to facilitate the material screening and design. Despite the exciting progress of GPT-4 based AI research assistance, open-source LLMs have not gained much attention from the scientific community. This work primarily focused on metal-organic frameworks (MOFs) as a subdomain of chemistry and evaluated six top-rated open-source LLMs with a comprehensive set of tasks including MOFs knowledge, basic chemistry knowledge, in-depth chemistry knowledge, knowledge extraction, database reading, predicting material property, experiment design, computational scripts generation, guiding experiment, data analysis, and paper polishing, which covers the basic units of MOFs research. In general, these LLMs were capable of most of the tasks. Especially, Llama2-7B and ChatGLM2-6B were found to perform particularly well with moderate computational resources. Additionally, the performance of different parameter versions of the same model was compared, which revealed the superior performance of higher parameter versions.
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| GB/T 7714 | Bai, Xuefeng , Xie, Yabo , Zhang, Xin et al. Evaluation of Open-Source Large Language Models for Metal-Organic Frameworks Research [J]. | JOURNAL OF CHEMICAL INFORMATION AND MODELING , 2024 , 64 (13) : 4958-4965 . |
| MLA | Bai, Xuefeng et al. "Evaluation of Open-Source Large Language Models for Metal-Organic Frameworks Research" . | JOURNAL OF CHEMICAL INFORMATION AND MODELING 64 . 13 (2024) : 4958-4965 . |
| APA | Bai, Xuefeng , Xie, Yabo , Zhang, Xin , Han, Honggui , Li, Jian-Rong . Evaluation of Open-Source Large Language Models for Metal-Organic Frameworks Research . | JOURNAL OF CHEMICAL INFORMATION AND MODELING , 2024 , 64 (13) , 4958-4965 . |
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