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学者姓名：谢亚勃
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Abstract ：
作为一类新型多孔材料，金属有机骨架(MOFs)常被开发作为荧光传感器用来监测水中的污染物，开发稳定且易制备的MOFs材料实现选择性检测有毒的Fe~(3+)仍具有较高挑战。本工作中，我们报道一例水稳定的二重穿插In基MOF:(NH_2Me_2)[In(fdc)_2]·2H_2O(BUT-205,BUT代表北京工业大学，H_2fdc=呋喃-2,5-二羧酸)。BUT-205的构筑采用生物质衍生配体，其结构通过单晶X射线衍射确立。这个材料可作为高效的水相Fe~(3+)离子传感器，具有高的灵敏度和选择性。检测限达到1.3μmol·L~(-1)，低于美国环保局规定的饮用水中安全标准(15.7μmol·L~...
Keyword ：
金属有机骨架 金属有机骨架 金属阳离子 金属阳离子 荧光检测 荧光检测 水安全 水安全 阴离子框架 阴离子框架
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| GB/T 7714 | Alamgir , 赵砚珑 , Khalid Talha et al. 一例互穿的阴离子型In(Ⅲ)金属有机骨架用于选择性检测水中Fe~(3+)离子（英文） [J]. | 无机化学学报 , 2022 , 38 (09) : 1817-1824 . |
| MLA | Alamgir et al. "一例互穿的阴离子型In(Ⅲ)金属有机骨架用于选择性检测水中Fe~(3+)离子（英文）" . | 无机化学学报 38 . 09 (2022) : 1817-1824 . |
| APA | Alamgir , 赵砚珑 , Khalid Talha , 谢亚勃 , 王璐 , 谢林华 et al. 一例互穿的阴离子型In(Ⅲ)金属有机骨架用于选择性检测水中Fe~(3+)离子（英文） . | 无机化学学报 , 2022 , 38 (09) , 1817-1824 . |
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Abstract ：
In this work, a UiO-66-diatomite composite was synthesized and used as sorbent to sample benzene, toluene and xylene (BTX) in indoor air. The physicochemical features of the as-prepared composite were deeply characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermo-gravimetric analysis (TGA) and nitrogen adsorption-desorption isotherm analysis. Moreover, an efficient analysis method for the enriched BTX compounds by the UiO-66-diatomite composite was successfully developed using thermal desorption (TD)GC-MS technique. The influence of desorption temperature was investigated to optimize the operation conditions. Under the desorption temperature of 180 ?, the method depicted good linearity (R-2 > 0.99) in the range of 5 ng to 1000 ng as well as excellent reproducibility with relative standard deviation (RSD) between 0.6% and 3.5%, in which the satisfactory recovery was achieved from 75.2% to 115%. More importantly, the developed method also exhibited high sensitivity with the method detection limit (MDL) in the range of 0.04-0.09 mu gm(-3). Hence, the findings evidence that this method might be one of the promising routes to detect trace levels of BTX compounds in indoor air and the MOF-based composite is feasible to be used as sorbent for the capture of volatile organic compounds in air.
Keyword ：
UiO-66 UiO-66 Sorbent Sorbent Diatomite Diatomite Thermal desorption Thermal desorption BTX BTX
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| GB/T 7714 | Lin, Xingtao , Tang, Lingli , Zhao, Jingqiang et al. Efficient determination of BTX compounds based on UiO-66-diatomite composite enrichment and thermal desorption GC-MS [J]. | MICROCHEMICAL JOURNAL , 2022 , 181 . |
| MLA | Lin, Xingtao et al. "Efficient determination of BTX compounds based on UiO-66-diatomite composite enrichment and thermal desorption GC-MS" . | MICROCHEMICAL JOURNAL 181 (2022) . |
| APA | Lin, Xingtao , Tang, Lingli , Zhao, Jingqiang , Liu, Shuzhen , Xie, Yabo . Efficient determination of BTX compounds based on UiO-66-diatomite composite enrichment and thermal desorption GC-MS . | MICROCHEMICAL JOURNAL , 2022 , 181 . |
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Abstract ：
The rational design of mixed matrix membranes (MMMs) combining appropriate additives and industrial process-able polymers offers a new prospect for highly efficient membrane separations. However, the difficulty in their fabrication due to the lack of processability of most additives and the formation of segregated filler domains in polymer matrices hampers the development and application of MMMs. Herein, we present two new zirconocene-based metallocavitands (ZRA and ZRT) and a series of MMMs fabricated by blending ZRA, ZRT, and MOC-1-NH2 (a zirconocene-based metal-organic cage) with the polyimide (6FDA-DAM), respectively. It was found that ZRA exhibited high thermal stability and good solubility in various solvents, which can be homogeneously mixed with polymers to prepare ZRA-based MMMs without any indication of filler agglomeration. Compared to the pure 6FDA-DAM membrane, a low ZRA-loading MMM (ZRA-2.2%) exhibited better mechanical properties and 50% improved CO2 permeability for CO2/CH4 separation. ZRA-2.2% also exhibited a good performance after 6 months of aging and significantly alleviated the plasticization effect under high pressures. These results suggest the great potential of the ZRA-2.2% for CO2/CH4 separation and that the simple metallocavitands may serve as promising additives in fabricating MMMs for gas separations.
Keyword ：
6FDA-DAM 6FDA-DAM mixed matrix membrane mixed matrix membrane molecularly homogenized composite membrane molecularly homogenized composite membrane metallocavitands metallocavitands gas separation gas separation
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| GB/T 7714 | Liu, Tongxin , Zhang, Ruili , Si, Guang-Rui et al. Molecularly Homogenized Composite Membranes Containing Solvent-Soluble Metallocavitands for CO2/CH4 Separation [J]. | ACS SUSTAINABLE CHEMISTRY & ENGINEERING , 2022 , 10 (40) : 13534-13544 . |
| MLA | Liu, Tongxin et al. "Molecularly Homogenized Composite Membranes Containing Solvent-Soluble Metallocavitands for CO2/CH4 Separation" . | ACS SUSTAINABLE CHEMISTRY & ENGINEERING 10 . 40 (2022) : 13534-13544 . |
| APA | Liu, Tongxin , Zhang, Ruili , Si, Guang-Rui , Liu, Bin , Xie, Yabo , Xie, Lin-Hua et al. Molecularly Homogenized Composite Membranes Containing Solvent-Soluble Metallocavitands for CO2/CH4 Separation . | ACS SUSTAINABLE CHEMISTRY & ENGINEERING , 2022 , 10 (40) , 13534-13544 . |
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Abstract ：
CO_2的资源化转化与利用是“双碳”目标达成的重要途径之一.金属-有机框架(metal-organic framework, MOF)因其充足的孔结构、丰富的活性位和可功能化等特性，在CO_2催化还原反应中展现出良好的应用前景.总结了基于MOF的新型功能材料依托光、电清洁能源，绿色催化CO_2还原的最新研究进展，分别探讨了活性MOF、MOF复合物和MOF衍生物的催化性能，并从理化特性上分析了材料性能优势的成因.在此基础上，对这类新型催化剂面临的主要问题和未来发展做出了总结与展望.
Keyword ：
MOF复合物 MOF复合物 金属-有机框架(metal-organic framework 金属-有机框架(metal-organic framework MOF) MOF) 碳中和 碳中和 电催化 电催化 CO_2还原 CO_2还原 光催化 光催化 MOF衍生物 MOF衍生物
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| GB/T 7714 | 王英杰 , 董辰 , 谢亚勃 et al. MOF基材料绿色催化CO_2还原研究进展 [J]. | 北京工业大学学报 , 2022 , 48 (03) : 261-272,305 . |
| MLA | 王英杰 et al. "MOF基材料绿色催化CO_2还原研究进展" . | 北京工业大学学报 48 . 03 (2022) : 261-272,305 . |
| APA | 王英杰 , 董辰 , 谢亚勃 , 李睿 , 李建荣 . MOF基材料绿色催化CO_2还原研究进展 . | 北京工业大学学报 , 2022 , 48 (03) , 261-272,305 . |
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Abstract ：
作为一类新型多孔材料,金属有机骨架(MOFs)常被开发作为荧光传感器用来监测水中的污染物,开发稳定且易制备的MOFs材料实现选择性检测有毒的Fe3+仍具有较高挑战.本工作中,我们报道一例水稳定的二重穿插In(Ⅲ)基MOF∶(NH2Me2)[In(fdc)2]·2H2O(BUT-205,BUT代表北京工业大学,H2fdc=呋喃-2,5-二羧酸).BUT-205的构筑采用生物质衍生配体,其结构通过单晶X射线衍射确立.这个材料可作为高效的水相Fe3+离子传感器,具有高的灵敏度和选择性.检测限达到1.3 μmol·L-1,低于美国环保局规定的饮用水中安全标准(15.7μmol·L-1),并且该传感材料可以回收利用至少4次.
Keyword ：
荧光检测 荧光检测 金属有机骨架 金属有机骨架 水安全 水安全 阴离子框架 阴离子框架 金属阳离子 金属阳离子
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| GB/T 7714 | Alamgir , 赵砚珑 , Khalid Talha et al. 一例互穿的阴离子型In(Ⅲ)金属有机骨架用于选择性检测水中Fe3+离子 [J]. | 无机化学学报 , 2022 , 38 (9) : 1817-1824 . |
| MLA | Alamgir et al. "一例互穿的阴离子型In(Ⅲ)金属有机骨架用于选择性检测水中Fe3+离子" . | 无机化学学报 38 . 9 (2022) : 1817-1824 . |
| APA | Alamgir , 赵砚珑 , Khalid Talha , 谢亚勃 , 王璐 , 谢林华 et al. 一例互穿的阴离子型In(Ⅲ)金属有机骨架用于选择性检测水中Fe3+离子 . | 无机化学学报 , 2022 , 38 (9) , 1817-1824 . |
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Abstract ：
In this study, UiO-66 was selected as sorbent media packed in the tube to selectively enrich trace levels of benzene homologues such as benzene, toluene, and xylene (BTX) in ambient air prior to thermal desorption (TD)-GC-MS determination. A series of experiments were conducted to obtain the optimal TD conditions. The results indicated that the optimal TD parameters were as follows: desorption temperature of 180 degrees C, desorption flow rate of 50 mL min(-1), and desorption time of 30 min. Furthermore, the method based on UiO-66 enrichment integrated with TD-GC-MS for trace levels of BTX was successfully developed. It exhibited a good linearity (R-2 > 0.99) in the range of 50-1000 ng, except for p, m-xylene in the range of 100-2000 ng, and achieved the recovery of 69.4-101.3%, and the relative standard deviation of 3.8-6.4%. The detection limits of BTX were 1.6-4.0 ng; according to 10 L of sampling volume, the method detection limits would be in the range of 0.16-0.40 mu g m(-3). Additionally, the method was successfully applied to determine BTX in indoor air and showed good selectivity and sensitivity. In summary, the findings in this work revealed that UiO-66 was an attractive adsorbent for selective enrichment trace levels of BTX compounds in ambient air, which was favorable for the subsequent detection by TD-GC-MS.
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| GB/T 7714 | Lin, Xing-Tao , Sun, Ge , Zhao, Jing-Qiang et al. UiO-66 Selective Enrichment Integrated with Thermal Desorption GC-MS for Detection of Benzene Homologues in Ambient Air [J]. | JOURNAL OF ANALYTICAL METHODS IN CHEMISTRY , 2021 , 2021 . |
| MLA | Lin, Xing-Tao et al. "UiO-66 Selective Enrichment Integrated with Thermal Desorption GC-MS for Detection of Benzene Homologues in Ambient Air" . | JOURNAL OF ANALYTICAL METHODS IN CHEMISTRY 2021 (2021) . |
| APA | Lin, Xing-Tao , Sun, Ge , Zhao, Jing-Qiang , Tang, Ling-Li , Li, Sheng-Hua , Xie, Ya-Bo . UiO-66 Selective Enrichment Integrated with Thermal Desorption GC-MS for Detection of Benzene Homologues in Ambient Air . | JOURNAL OF ANALYTICAL METHODS IN CHEMISTRY , 2021 , 2021 . |
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Abstract ：
金属有机框架材料对Cr(Ⅵ)离子的吸附去除研究进展
Keyword ：
吸附去除 吸附去除 多孔材料 多孔材料 金属有机框架 金属有机框架 重金属污染 重金属污染 六价铬Cr(Ⅵ) 六价铬Cr(Ⅵ)
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| GB/T 7714 | 李茹霞 , 钟文彬 , 谢林华 et al. 金属有机框架材料对Cr(Ⅵ)离子的吸附去除研究进展 [J]. | 李茹霞 , 2021 , 37 (3) : 385-400 . |
| MLA | 李茹霞 et al. "金属有机框架材料对Cr(Ⅵ)离子的吸附去除研究进展" . | 李茹霞 37 . 3 (2021) : 385-400 . |
| APA | 李茹霞 , 钟文彬 , 谢林华 , 谢亚勃 , 李建荣 , 无机化学学报 . 金属有机框架材料对Cr(Ⅵ)离子的吸附去除研究进展 . | 李茹霞 , 2021 , 37 (3) , 385-400 . |
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Abstract ：
重金属离子污染问题一直备受关注。开发利用多孔材料吸附去除水中重金属离子一直是材料、环境等相关学科领域的研究热点之一。金属有机框架材料(metal-organic frameworks,MOFs)是一类新型的多孔材料,具有结构多样、比表面积大、孔径可调、孔表面特征易设计调控等特点,在气体分离、催化、传感等领域表现出极大的应用潜力。近年来,高稳定MOF材料的构筑取得了许多重大突破,大量研究工作探索了这类材料在水中的应用,包括水中重金属离子的吸附去除。Cr(Ⅵ)离子是一类毒性大、分布广的重金属离子,不同条件下存在形态多样,其吸附去除研究具有理论和实际意义。本文主要综述了近年来利用MOF材料吸附去除水...
Keyword ：
多孔材料 多孔材料 吸附去除 吸附去除 六价铬Cr(Ⅵ) 六价铬Cr(Ⅵ) 金属有机框架 金属有机框架 重金属污染 重金属污染
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| GB/T 7714 | 李茹霞 , 钟文彬 , 谢林华 et al. 金属有机框架材料对Cr(Ⅵ)离子的吸附去除研究进展 [J]. | 无机化学学报 , 2021 , 37 (03) : 385-400 . |
| MLA | 李茹霞 et al. "金属有机框架材料对Cr(Ⅵ)离子的吸附去除研究进展" . | 无机化学学报 37 . 03 (2021) : 385-400 . |
| APA | 李茹霞 , 钟文彬 , 谢林华 , 谢亚勃 , 李建荣 . 金属有机框架材料对Cr(Ⅵ)离子的吸附去除研究进展 . | 无机化学学报 , 2021 , 37 (03) , 385-400 . |
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Abstract ：
焦化场地包气带区土壤苯的精细化风险评估
Keyword ：
焦化场地 焦化场地 J&E模型 J&E模型 J&E-DED模型 J&E-DED模型 苯 苯 精细化风险评估 精细化风险评估 土壤气挥发通量 土壤气挥发通量
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| GB/T 7714 | 张蒙蒙 , 张超艳 , 郭晓欣 et al. 焦化场地包气带区土壤苯的精细化风险评估 [J]. | 张蒙蒙 , 2021 , 34 (5) : 1223-1230 . |
| MLA | 张蒙蒙 et al. "焦化场地包气带区土壤苯的精细化风险评估" . | 张蒙蒙 34 . 5 (2021) : 1223-1230 . |
| APA | 张蒙蒙 , 张超艳 , 郭晓欣 , 李卫东 , 闫珂 , 周友亚 et al. 焦化场地包气带区土壤苯的精细化风险评估 . | 张蒙蒙 , 2021 , 34 (5) , 1223-1230 . |
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Abstract ：
Clenbuterol (CLE) and ractopamine (RAC) are two kinds of typical β2-adrenergic agonists which pose a serious threat to the health of human beings. In this work, 10 kinds of metal-organic frameworks (MOFs) with high stability and various pore features are screened to assess adsorption performance for CLE and RAC. An Al(III)-MOF (BUT-19) with abundant ethyl groups exhibits exceptional performance in removing CLE and RAC from water. The maximum adsorption capacity for CLE and RAC are up to 294.1 and 366.3 mg/g under the optimum adsorption conditions, respectively. Meanwhile, the adsorption mechanism effects of pH, temperature, and coexisted ions are investigated systematically. It is found that the MOF pore size and weak hydrogen-bond interactions between CLE/RAC molecules and the MOF are the main causes leading to the extraordinary adsorption. This study provides a new idea for the purposeful design and synthesis of MOFs for removing environmental pollutants and sheds light on the depuration of contaminated water.
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| GB/T 7714 | Lv Jie , Chen Qiang , Liu Jing-Hao et al. Effective Removal of Clenbuterol and Ractopamine from Water with a Stable Al(III)-Based Metal-Organic Framework. [J]. | Inorganic chemistry , 2021 , 60 (3) : 1814-1822 . |
| MLA | Lv Jie et al. "Effective Removal of Clenbuterol and Ractopamine from Water with a Stable Al(III)-Based Metal-Organic Framework." . | Inorganic chemistry 60 . 3 (2021) : 1814-1822 . |
| APA | Lv Jie , Chen Qiang , Liu Jing-Hao , Yang Hao-Sen , Wang Peilong , Yu Jiamei et al. Effective Removal of Clenbuterol and Ractopamine from Water with a Stable Al(III)-Based Metal-Organic Framework. . | Inorganic chemistry , 2021 , 60 (3) , 1814-1822 . |
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