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学者姓名：梁文俊
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Abstract ：
Gasoline vapor emissions from service stations significantly affect urban atmospheric. Despite the research on the mechanisms and effectiveness of gasoline vapor removal is limited, this study innovatively investigates the static and dynamic adsorption of xylene-a typical gasoline vapor and one of the most active secondary organic aerosol (SOA) species-by commercial activated carbon (AC). The results showed that the saturation static adsorption capacity (Q(e)) of 12 ACs varied from 0.9 to 870.7 mg/g, which correlated with the specific surface area (SSA) and pore volume. Among them, 11# and 12# ACs were identified as the most effective adsorbents for typical gasoline vapor removal. The maximum dynamic Q(e) increased from 301.5 to 414.3 mg/g when the initial xylene concentration rose from 918 to 2008 mg/m(3) for 11# AC, and from 201.4 to 406.2 mg/g when the initial xylene concentration increased from 589 to 2120 mg/m(3) for 12# AC. These findings implied a direct correlation between higher initial xylene concentrations and greater dynamic Q(e) values, with static Q(e) values surpassing dynamic values. The adsorption kinetics simulation were analyzed by the pseudo-first-order (PFO) and pseudo-second-order (PSO) kinetics. The kinetics results demonstrated that the PFO was more effective in characterizing the adsorption of xylene onto ACs (R-2 > 0.989), indicating that the adsorption of typical gasoline vapor by ACs primarily involves physical adsorption. The findings of static/dynamic adsorption and kinetics provide valuable guidance for practical applications of gasoline vapor removal in service stations.
Keyword ：
Gasoline vapor Gasoline vapor Breakthrough curve Breakthrough curve Dynamic adsorption Dynamic adsorption Activated carbon Activated carbon Xylene Xylene
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| GB/T 7714 | Hu, Wei , Liang, Quanming , Lu, Dan et al. Adsorption of typical gasoline vapor emitted from service stations by commercial activated carbon: static/dynamic adsorption and kinetics simulation [J]. | FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING , 2025 , 19 (3) . |
| MLA | Hu, Wei et al. "Adsorption of typical gasoline vapor emitted from service stations by commercial activated carbon: static/dynamic adsorption and kinetics simulation" . | FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING 19 . 3 (2025) . |
| APA | Hu, Wei , Liang, Quanming , Lu, Dan , Li, Beibei , Ren, Biqi , Luan, Qingye et al. Adsorption of typical gasoline vapor emitted from service stations by commercial activated carbon: static/dynamic adsorption and kinetics simulation . | FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING , 2025 , 19 (3) . |
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Abstract ：
以改性赤泥为载体,采用浸渍方法制备低成本改性赤泥(MRM)负载Pt催化剂,并探究Pt含量对Pt/MRM催化剂催化氧化甲苯活性影响.结果表明0.4Pt/MRM表现出最佳的催化活性,在230℃时甲苯转化率为100%.当空速高达120000h~(-1)时0.4Pt/MRM催化剂依然能保持着较高的催化活性.当甲苯进口浓度为5000mg/m~3时仍可以有效氧化甲苯.采用XRD、FT-IR、BET、H_2-TPR和O_2-TPD等手段进行表征测试分析发现,MRM的比表面积较RM大幅度提高,使MRM能够更好分散活性组分Pt,成为合适的活性组分Pt的催化剂载体.同时所制备的x Pt/MRM催化剂具有较高的比表面积和良好的孔结构.改性赤泥中Fe_2O_3与活性组分Pt物种相互作用,使催化剂的总氧解吸量增大,提高了催化剂表面氧的迁移率,从而提高了催化效率.
Keyword ：
改性赤泥 改性赤泥 Pt Pt 甲苯 甲苯 催化燃烧 催化燃烧
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| GB/T 7714 | 方宏萍 , 梁文俊 , 马琛 et al. 改性赤泥负载Pt催化剂催化氧化甲苯的性能 [J]. | 中国环境科学 , 2024 , 44 (03) : 1244-1252 . |
| MLA | 方宏萍 et al. "改性赤泥负载Pt催化剂催化氧化甲苯的性能" . | 中国环境科学 44 . 03 (2024) : 1244-1252 . |
| APA | 方宏萍 , 梁文俊 , 马琛 , 马连刚 , 李桂贤 . 改性赤泥负载Pt催化剂催化氧化甲苯的性能 . | 中国环境科学 , 2024 , 44 (03) , 1244-1252 . |
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Abstract ：
Cerium oxide (CeO2) was added to modified Ru/TiO2 catalyst by a two-step impregnation method for selective catalytic oxidation of ammonia (NH3-SCO). The low-temperature NH3 oxidation activity and N2 selectivity of the 1Ru/xCe-TiO2 catalyst were investigated with the result that both SCO activity and N2 selectivity were influenced by the amount of Ce. Specifically, the presence of 5 wt% CeO2 demonstrated a great promoting effect on both parameters, reaching an NH3 conversion and N2 selectivity of 97 % and 93 % at 180 degrees C, respectively. Various characterization methods indicated that the presence of CeO2 regulates the dispersion of the 1Ru/xCeTiO2 catalysts, changes the amount, strength and ratio of strong and weak acid sites on the catalyst surface, and promotes the formation of Ru-O-Ce bonds through the interaction between Ce and Ru species, which facilitates electron transfer and oxygen vacancy formation, thereby enhancing the oxidation ability of the catalysts. Furthermore, the results of in situ diffuse reflectance infrared Fourier transform spectroscopy indicated that the NH3-SCO reaction over the 1Ru/xCe-TiO2 catalysts follows the "internal" selective catalytic reduction (i-SCR) mechanism, involving the oxidation of NH3 into nitric oxide (NO) species and the reaction of -NH2 with in situformed NO to form N2.
Keyword ：
Ammonia slip Ammonia slip Cerium Cerium Catalysts Catalysts Surface acidity Surface acidity i-SCR mechanism i-SCR mechanism Ruthenium Ruthenium
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| GB/T 7714 | Li, Shuangye , Li, Jian , Liang, Wenjun et al. Promoting effects of cerium oxide on catalysts performance for selectivity catalytic oxidation of NH3over RuOx /TiO2 [J]. | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2024 , 12 (5) . |
| MLA | Li, Shuangye et al. "Promoting effects of cerium oxide on catalysts performance for selectivity catalytic oxidation of NH3over RuOx /TiO2" . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 12 . 5 (2024) . |
| APA | Li, Shuangye , Li, Jian , Liang, Wenjun , Cai, Jianyu , Guo, Ruixue . Promoting effects of cerium oxide on catalysts performance for selectivity catalytic oxidation of NH3over RuOx /TiO2 . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2024 , 12 (5) . |
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Abstract ：
Cubic Cu2O micro/nanocrystals were successfully synthesized by liquid-phase reduction using copper salt of CuSO4 or CuCl2.2H2O, and glucose or ascorbic acid as reducing agent, respectively. The activity of the catalysts was evaluated by light-off curves of CO self-sustained catalytic combustion via temperature-programmed oxidation of CO (CO-TPO), with the results showing the activity of catalysts following the order of Cu2O-ClGLU > Cu2O-S-GLU > Cu2O-S-AA > Cu2O-Cl-AA, (Cl denotes CuCl2.2H2O, GLU denotes glucose, S denotes CuSO4 and AA denotes ascorbic acid, respectively), corresponding to the ignition temperature of 109 degrees C, 122 degrees C, 137 degrees C and 186 degrees C, respectively. The crystal structure, elemental valence, morphology and redox property of the prepared catalysts were analyzed by using various characterization techniques. Combined with in situ infrared spectrum, the CO self-sustained catalytic combustion over Cu2O catalysts mainly follows the Mars-van-Krevelen (M-v-K) mechanism: the adsorbed and activated CO reacts with lattice oxygen to yield CO2 and oxygen vacancy, and then the oxygen vacancy can be replenished by gaseous oxygen. Combined with catalytic performance of high-concentration CO, it is found that the catalysts prepared using glucose as reducing agent are more angular compared with ascorbic acid. The Cu2O-Cl-GLU synthesized with glucose and CuCl2.2H2O exhibits the best catalytic activity among all the catalysts tested, attributing to its more obvious edge and rough crystal surface. The unique structure of Cu2O-Cl-GLU leads to the high exposure rate and coordination unsaturation of atoms on the cubic Cu2O micro/nanocrystals that can improve the ability of activating gaseous O2 and low temperature reducibility, and consequently facilitating the catalytic activity.
Keyword ：
Nanocrystals Nanocrystals Carbon monoxide Carbon monoxide Chemically adsorbed oxygen Chemically adsorbed oxygen Cu 2 O micro Cu 2 O micro Self-sustained catalytic combustion Self-sustained catalytic combustion
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| GB/T 7714 | Ma, Pandong , Zhang, Chenhang , Dou, Baojuan et al. Synthesis of Cu2O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose [J]. | CHEMOSPHERE , 2023 , 314 . |
| MLA | Ma, Pandong et al. "Synthesis of Cu2O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose" . | CHEMOSPHERE 314 (2023) . |
| APA | Ma, Pandong , Zhang, Chenhang , Dou, Baojuan , Yi, Xiaokun , Bin, Feng , Liang, Wenjun . Synthesis of Cu2O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose . | CHEMOSPHERE , 2023 , 314 . |
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Abstract ：
通过等体积浸渍法制备了一系列Mn-Ce/γ-Al_2O_3催化剂,并考察不同CeO_2负载量对MnO_2/γ-Al_2O_3催化剂催化氧化甲苯性能的影响。利用XRD、N_2吸脱附曲线、TEM、H_2-TPR、XPS和O_2-TPD等方法表征催化剂比表面积、表面形貌及氧化还原性能。结果表明，CeO_2的负载一定程度上降低了MnO_2/γ-Al_2O_3催化剂的比表面积,且催化剂仍保持介孔结构。CeO_2的存在增加了催化剂表面的化学吸附氧含量，其良好的储放氧能力促进了Mn~(3+)向Mn~(4+)的转化；Mn和Ce之间存在较强的协同作用,与MnO_x相邻的CeO_2更容易打开Ce—O键释放活性氧,加速氧化还原进程，Mn_(0.6)Ce_(0.4)/γ-Al_2O_3催化剂T10和T90与MnO_2/γ-Al_2O_3催化剂相比分别降低20和40℃。本研究可为VOCs催化氧化技术中低成本金属催化剂的开发提供参考。
Keyword ：
协同作用 协同作用 催化氧化 催化氧化 MnO_2 MnO_2 CeO_2 CeO_2 甲苯 甲苯
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| GB/T 7714 | 任思达 , 潘文 , 梁文俊 et al. Mn-Ce复合金属氧化物催化氧化甲苯性能 [J]. | 环境工程学报 , 2023 , 17 (08) : 2615-2623 . |
| MLA | 任思达 et al. "Mn-Ce复合金属氧化物催化氧化甲苯性能" . | 环境工程学报 17 . 08 (2023) : 2615-2623 . |
| APA | 任思达 , 潘文 , 梁文俊 , 闫贺 , 赵锦 , 李劲松 . Mn-Ce复合金属氧化物催化氧化甲苯性能 . | 环境工程学报 , 2023 , 17 (08) , 2615-2623 . |
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Abstract ：
本发明提供了一种改性赤泥基吸附剂及其制备方法和应用，涉及工业固废资源化利用技术领域。本发明先对赤泥进行酸碱改性(活化和焙烧)，使得赤泥转变为介孔材料，大大提高了赤泥的比表面积和孔容，从而显著提高了二氧化碳气体扩散与吸附性能，使得改性赤泥基吸附剂对二氧化碳的吸附容量明显增加。通过采用浸渍法在所得酸碱改性赤泥上负载MgO，提供了更多的碱性活性位点，对二氧化碳的吸附容量有明显的提高。酸碱改性赤泥对二氧化碳主要进行物理吸附，MgO提供碱性活性位点对二氧化碳进行化学吸附，实现了物理和化学吸附的协同作用，提高了对二氧化碳的吸附容量和吸附速率，在常温常压下即可实现吸附二氧化碳，二氧化碳的脱附温度低。
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| GB/T 7714 | 梁文俊 , 杨岚 , 方宏萍 et al. 一种改性赤泥基吸附剂及其制备方法和应用 : CN202310226566.5[P]. | 2023-03-10 . |
| MLA | 梁文俊 et al. "一种改性赤泥基吸附剂及其制备方法和应用" : CN202310226566.5. | 2023-03-10 . |
| APA | 梁文俊 , 杨岚 , 方宏萍 , 张艳 , 刘佳 . 一种改性赤泥基吸附剂及其制备方法和应用 : CN202310226566.5. | 2023-03-10 . |
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Abstract ：
Monolithic catalysts are widely used in industrial catalysis. However, in the preparation of a monolithic catalyst, the traditional methods have some drawbacks such as low washcoat uploading ratio and poor uniformity. In the present work, the effects of Pd/Ce loading and catalyst components on the catalytic abatement of toluene were investigated. The acid treatment of the substrate, the particle size of the slurry and the dispersant on the uniformity of the washcoat and the catalytic performance were also explored. Characterisation was achieved via BET, SEM, zeta potential and laser grain-size analyses. The results showed that the catalytic activity of the catalyst increased with the increasing of the Ce content. It was found that the 0.2Pd-0.3Ce/gamma-Al2O3 catalysts had the best toluene catalytic activity. The pretreatment of the cordierite with 20% HCl could improve the properties of the cordierite. It was also found that reducing the particle size of the washcoat and adding dispersant PAA could effectively improve the stability of the suspension and the uniformity of the washcoat. When 20% HCl pretreatment was used, the toluene catalytic activity of the monolith catalyst prepared by cordierite increased, in which T-10 and T-90 decreased by about 5 degrees C. Decreasing the particle size and dispersant also promoted the efficiency of catalytic degradation.
Keyword ：
Pd Pd CeO2 CeO2 monolithic catalyst monolithic catalyst catalytic performance catalytic performance
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| GB/T 7714 | Liang, Wenjun , Shi, Xiujuan , Li, Qinglei et al. Effect of Pd/Ce Loading and Catalyst Components on the Catalytic Abatement of Toluene [J]. | CATALYSTS , 2022 , 12 (2) . |
| MLA | Liang, Wenjun et al. "Effect of Pd/Ce Loading and Catalyst Components on the Catalytic Abatement of Toluene" . | CATALYSTS 12 . 2 (2022) . |
| APA | Liang, Wenjun , Shi, Xiujuan , Li, Qinglei , Ren, Sida , Yin, Guobin . Effect of Pd/Ce Loading and Catalyst Components on the Catalytic Abatement of Toluene . | CATALYSTS , 2022 , 12 (2) . |
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Abstract ：
Metal Palladium species are efficiently used to degrade volatile organic compounds (VOCs). In this paper, the adsorption properties of toluene on Pd(111) and PdO(101) surfaces were theoretically studied using the first principle calculation. Adsorption energy, charge density, density of states and electron density difference were chosen as characteristics and were calculated to evaluate the adsorption capacity of toluene on Pd(111) and PdO (101) surfaces. The results showed that the interaction of toluene on the Pd(111) surface was stronger than on the PdO(101) surface. The dissociation pathway of toluene after adsorption was also determined; the results showed that the formation of benzyl radical through the reaction with a hydroxyl group on the Pd(111) and PdO (101) surfaces was investigated using density functional theory calculations. Compared with PdO(101) (0.63 eV), the dissociation of toluene on Pd(111) (0.19 eV) has a lower energy barrier, which indicated that the reaction between toluene and Pd(111) was easier to occur. Therefore, it provides the basis for the preparation of highperformance catalysts and the calculation of catalytic oxidation reaction paths in the future.
Keyword ：
Pd(111) Pd(111) PdO(101) PdO(101) First principle calculation First principle calculation Toluene Toluene Dissociation Dissociation Adsorption Adsorption
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| GB/T 7714 | Liang, Wenjun , Li, Xiang , Ju, Haolin et al. Adsorption and dissociation mechanism of toluene on Pd (111) and PdO (101) surface: First principle calculation [J]. | SURFACE SCIENCE , 2022 , 720 . |
| MLA | Liang, Wenjun et al. "Adsorption and dissociation mechanism of toluene on Pd (111) and PdO (101) surface: First principle calculation" . | SURFACE SCIENCE 720 (2022) . |
| APA | Liang, Wenjun , Li, Xiang , Ju, Haolin , Ren, Sida . Adsorption and dissociation mechanism of toluene on Pd (111) and PdO (101) surface: First principle calculation . | SURFACE SCIENCE , 2022 , 720 . |
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Abstract ：
本发明公开一种强化生物滴滤塔性能的硅藻土基复合填料。将聚乙烯醇和海藻酸钠加入去离子水中，加热搅拌溶解。将所得溶液放置至室温，加入硅藻土、碳酸钙、有机肥及降解菌，搅拌均匀。将得到的硅藻土基复合填料混合溶液滴入到交联溶液中，交联溶液为含质量浓度为2％CaCl2的饱和硼酸溶液，溶剂为水。硅藻土基复合填料混合液中去离子水与交联溶液体积比为1：10。在4℃条件下固定化，取出后用去离子水冲洗三遍，制成硅藻土基复合填料。该填料具有良好的持水性能及营养缓释能力，使用周期长，能够缩短生物滴滤塔启动时间，强化生物滴滤塔抗冲击负荷及停滞能力。
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| GB/T 7714 | 刘佳 , 鲁少杰 , 李萍 et al. 一种强化生物滴滤塔性能的硅藻土基复合填料 : CN202211275873.4[P]. | 2022-10-19 . |
| MLA | 刘佳 et al. "一种强化生物滴滤塔性能的硅藻土基复合填料" : CN202211275873.4. | 2022-10-19 . |
| APA | 刘佳 , 鲁少杰 , 李萍 , 冀芊竹 , 梁文俊 . 一种强化生物滴滤塔性能的硅藻土基复合填料 : CN202211275873.4. | 2022-10-19 . |
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Abstract ：
本发明公开一种用于挥发性有机污染物去除的均质反应装置，包括圆筒管和优化元件，圆筒管的第一端与气体进口相连通，圆筒管的第二端与气体出口相连通，圆筒管包括催化段，催化段内设置催化剂，优化元件位于第一端与催化段之间。废气由气体进口进入反应装置内，经由第一端进入圆筒管内，废气经过圆筒管内的优化元件后，保证了进入后续催化段的气体的均匀性，以使废气与催化段的催化剂充分反应，提高催化效率，经过催化剂处理的气体经由第二端以及气体出口导出，提高催化效率的同时，还能够有效避免局部大量放热对催化剂以及反应装置造成的损坏，延长设备使用寿命。优化元件与催化段之间的间距能够调整，方便根据工况调整优化元件的位置。
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| GB/T 7714 | 梁文俊 , 鞠浩琳 , 石秀娟 et al. 一种用于挥发性有机污染物去除的均质反应装置 : CN202210510358.3[P]. | 2022-05-11 . |
| MLA | 梁文俊 et al. "一种用于挥发性有机污染物去除的均质反应装置" : CN202210510358.3. | 2022-05-11 . |
| APA | 梁文俊 , 鞠浩琳 , 石秀娟 , 李想 , 刘佳 . 一种用于挥发性有机污染物去除的均质反应装置 : CN202210510358.3. | 2022-05-11 . |
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