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Author:

Sun, Zhirong (Sun, Zhirong.) (Scholars:孙治荣) | Zhang, Huan (Zhang, Huan.) | Wei, Xuefeng (Wei, Xuefeng.) | Du, Ran (Du, Ran.) | Hu, Xiang (Hu, Xiang.)

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EI Scopus SCIE

Abstract:

A novel Ni-Nd co-doped SnO2-Sb anode, with macroporous titanium sheet as substrate (mp-Ti/SnO2-Sb-Ni-Nd anode) was prepared by modified sol-gel method. The surface morphology, the crystal structure and the valence of the dopants were characterized by SEM, XRD and XPS, respectively. In addition, CV, LSV, EIS, chronoamperometry measurements and accelerated lifetime test were also carried out to study the electrochemical properties and stability of the anodes. The results indicated that mp-Ti/SnO2-Sb-Ni-Nd anode possessed a lower charge transfer resistance and a longer service life than other modified SnO2-Sb anodes. Electrocatalytic oxidation of phenol was studied under a constant current density of 10 mA . cm(-2) at 25 degrees C to evaluate the potential applications of the electrodes. The co-doping of Ni-Nd significantly enhanced the degradation of phenol and the total organic carbon (TOC) removal efficiency on SnO2-Sb anode, which might be attributed to the improved generation of reactive oxygen species (ROS) to the solution and the dominant action of indirect oxidation. (C) 2015 The Electrochemical Society. All rights reserved.

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Author Community:

  • [ 1 ] [Sun, Zhirong]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Huan]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wei, Xuefeng]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Du, Ran]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Hu, Xiang]Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China

Reprint Author's Address:

  • 孙治荣

    [Sun, Zhirong]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

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Source :

JOURNAL OF THE ELECTROCHEMICAL SOCIETY

ISSN: 0013-4651

Year: 2015

Issue: 9

Volume: 162

Page: H590-H596

3 . 9 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:253

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 32

SCOPUS Cited Count: 34

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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