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Author:

Yang, Yilong (Yang, Yilong.) | Li, Yongli (Li, Yongli.) | Wang, Jinshu (Wang, Jinshu.) (Scholars:王金淑) | Zhang, Yan (Zhang, Yan.) | He, Di (He, Di.) | Wu, Junshu (Wu, Junshu.) | Dai, Hongxing (Dai, Hongxing.) (Scholars:戴洪兴)

Indexed by:

EI Scopus SCIE

Abstract:

Nitrogen-doped TiO2-bronze@g-C3N4 (TiO2 (B)@g-C3N4) two-dimensional binary heterojunctions were constructed based on seeding-induced growth through a microwave-assisted solvothermal process and subsequent thermal treatment in a vacuum. The morphology of the TiO2 (B) nanosheets could be controlled by tuning the concentration of the Ti precursor, which determined the enhanced photoelectron activity. The optimal photocatalytic activity for the degradation of methyl orange (MO) under low-intensity visible-light illumination was obtained at a TiO2 (B)/g-C3N4 molar ratio of 1 : 1, which was 12.7 and 7.9 times higher than that of pure g-C3N4 and P25, respectively. The photocatalytic activity was further enhanced by about 7.7% after in situ N-doping. The improvement in photocatalytic activity of N-doped TiO2 (B)@g-C3N4 hetero-nanojunctions was attributable to the strong absorption in the visible-light region and better separation of photogenerated electron-hole pairs at the nanojunction interface, a result due to the large contact area between N-doped TiO2 (B) and g-C3N4 nanosheets. We have explained the photocatalytic degradation of MO molecules largely in terms of the direct oxidation by the photogenerated holes and partly by the contribution of the superoxide radicals.

Keyword:

Author Community:

  • [ 1 ] [Yang, Yilong]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Yongli]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Jinshu]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, Yan]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 5 ] [He, Di]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Wu, Junshu]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 8 ] [Dai, Hongxing]Beijing Univ Technol, Lab Catalysis Chem & Nanosci, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Yang, Yilong]Beijing Univ Technol, Sch Mat Sci & Engn, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China

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Source :

RSC ADVANCES

Year: 2015

Issue: 63

Volume: 5

Page: 50833-50842

3 . 9 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:253

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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