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Abstract:
High-surface-area and well-ordered mesoporous Fe-incorporated SBA-15 (xFe-SBA-15) and SBA-15-supported FeO (x) (yFeO (x) /SBA-15) with the Fe surface density between 0.09 to 1.11 Fe-atom/nm(2) have been prepared using the one-step synthesis and incipient wetness impregnation methods, respectively. Physicochemical properties of these materials were characterized by means of numerous techniques, and their catalytic activities for the combustion of toluene were evaluated. It is found that the xFe-SBA-15 and yFeO (x) /SBA-15 samples possessed rod- or chain-like morphologies. The Fe species were of high dispersion when the Fe surface density was lower than 0.76 Fe-atom/nm(2) in xFe-SBA-15 and 0.64 Fe-atom/nm(2) in yFeO (x) /SBA-15. At a similar Fe surface density and space velocity, the xFe-SBA-15 catalysts showed better activity than the yFeO (x) /SBA-15 catalysts, in which the xFe-SBA-15 catalyst with Fe surface density 0.59 Fe-atom/nm(2) performed the best. It is concluded that the good performance of the xFe-SBA-15 sample with Fe surface density 0.59 Fe-atom/nm(2) was associated with its large surface area, high Fe species dispersion, and good low-temperature reducibility.
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CHINESE SCIENCE BULLETIN
ISSN: 1001-6538
Year: 2014
Issue: 31
Volume: 59
Page: 3993-4002
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 11
SCOPUS Cited Count: 12
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
Affiliated Colleges: