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Author:

Fei, Huilong (Fei, Huilong.) | Ye, Ruquan (Ye, Ruquan.) | Ye, Gonglan (Ye, Gonglan.) | Gong, Yongji (Gong, Yongji.) | Peng, Zhiwei (Peng, Zhiwei.) | Fan, Xiujun (Fan, Xiujun.) | Samuel, Errol L. G. (Samuel, Errol L. G..) | Ajayan, Pulickel M. (Ajayan, Pulickel M..) | Tour, James M. (Tour, James M..)

Indexed by:

EI Scopus SCIE

Abstract:

The scarcity and high cost of platinum-based electrocatalysts for the oxygen reduction reaction (ORR) has limited the commercial and scalable use of fuel cells. Heteroatom-doped nanocarbon materials have been demonstrated to be efficient alternative catalysts for ORR. Here, graphene quantum dots, synthesized from inexpensive and earth-abundant anthracite coal, were self-assembled on graphene by hydrothermal treatment to form hybrid nanoplatelets that were then codoped with nitrogen and boron by high-temperature annealing. This hybrid material combined the advantages of both components, such as abundant edges and doping sites, high electrical conductivity, and high surface area, which makes the resulting materials excellent oxygen reduction electrocatalysts with activity even higher than that of commercial Pt/C in alkaline media.

Keyword:

coal graphene quantum dots electrocatalyst oxygen reduction reaction boron nitrogen doping

Author Community:

  • [ 1 ] [Fei, Huilong]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 2 ] [Ye, Ruquan]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 3 ] [Gong, Yongji]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 4 ] [Peng, Zhiwei]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 5 ] [Samuel, Errol L. G.]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 6 ] [Ajayan, Pulickel M.]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 7 ] [Tour, James M.]Rice Univ, Dept Chem, Houston, TX 77005 USA
  • [ 8 ] [Fan, Xiujun]Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
  • [ 9 ] [Tour, James M.]Rice Univ, Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA
  • [ 10 ] [Ye, Gonglan]Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
  • [ 11 ] [Ajayan, Pulickel M.]Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
  • [ 12 ] [Tour, James M.]Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
  • [ 13 ] [Fan, Xiujun]Beijing Univ Technol, Coll Elect Informat & Control Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Ajayan, Pulickel M.]Rice Univ, Dept Chem, 6100 Main St, Houston, TX 77005 USA

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Related Keywords:

Source :

ACS NANO

ISSN: 1936-0851

Year: 2014

Issue: 10

Volume: 8

Page: 10837-10843

1 7 . 1 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:258

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 397

SCOPUS Cited Count: 422

ESI Highly Cited Papers on the List: 39 Unfold All

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WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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