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Author:

赵思思 (赵思思.) | 魏学锋 (魏学锋.) | 孙治荣 (孙治荣.) (Scholars:孙治荣)

Indexed by:

CQVIP PKU CSCD

Abstract:

采用自制的钯/聚吡咯(十二烷基苯磺酸钠)/钛(Pd/PPy(SDBS)/Ti)电极对二氯酚(DCP)的6种同分异构体进行了电化学还原脱氯研究。探讨了脱氯电流、溶液初始p H和污染物初始浓度对2,5-DCP脱氯过程的影响。在脱氯电流5 m A、溶液初始p H 2.5、温度25℃、污染物初始浓度100 mg·L-1的条件下对2,3-DCP、2,4-DCP、2,5-DCP、2,6-DCP、3,4-DCP和3,5-DCP的脱氯过程进行了比较。6种DCP的脱氯产物均以苯酚为主,有少量的单氯酚产生,脱氯反应速率常数依次为4.735×10-2、4.609×10-2、4.845×10-2、4.317×10-2...

Keyword:

电化学 速率常数 反应动力学 催化还原 氯酚

Author Community:

  • [ 1 ] 北京工业大学环境与能源工程学院

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Source :

化工学报

Year: 2015

Issue: 11

Volume: 66

Page: 4452-4459

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 12

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