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Author:

Wang, Hong (Wang, Hong.) | Li, Hongyi (Li, Hongyi.) (Scholars:李洪义) | Wang, Jinshu (Wang, Jinshu.) (Scholars:王金淑) | Wu, Junshu (Wu, Junshu.) | Li, Dasheng (Li, Dasheng.) | Liu, Man (Liu, Man.) | Su, Penglei (Su, Penglei.)

Indexed by:

EI Scopus SCIE

Abstract:

Power conversion efficiency of dye sensitized solar cell (DSSC) is closely related to photo-anode's structure. It has been believed that titanium dioxide (TiO2) nanotube array thin film is one of the best photo-anode candidates for DSSC. However, the insufficient internal surface area and wide band gap of pure anatase limit their power conversion efficiency. Here we report a novel TiO2 nanotube array film synthesized by anodization followed by surface modification with nitrogen (N) doped TiO2 nanoparticles using a solvothermal method. The incorporation of N doped TiO2 nanoparticles along the wall of TiO2 nanotubes not only provides a large surface area for dye loading, but also increases the conductivity of the electrode, generating an overall power conversion efficiency of 2.53%, which is 68% higher than that with pure TiO2 nanotube array (with the length of 1.8 mu m) photoanode. When the length of TiO2 nanotube increased to 4.1 mu m, the overall power conversion efficiency can be improved to be 4.9%, which is higher than the previous reported results using the same length of nanotube. (C) 2014 Elsevier Ltd. All rights reserved.

Keyword:

doping surface modification DSSC TiO2 nanotube array

Author Community:

  • [ 1 ] [Wang, Hong]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Hongyi]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Jinshu]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Junshu]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Dasheng]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Liu, Man]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Su, Penglei]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 李洪义

    [Li, Hongyi]Beijing Univ Technol, Key Lab Adv Funct Mat, Sch Mat & Engn, Beijing 100124, Peoples R China

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Source :

ELECTROCHIMICA ACTA

ISSN: 0013-4686

Year: 2014

Volume: 137

Page: 744-750

6 . 6 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:258

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 35

SCOPUS Cited Count: 35

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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