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Author:

Wang, Feng (Wang, Feng.) | Sun, Jihong (Sun, Jihong.) (Scholars:孙继红) | Bai, Shiyang (Bai, Shiyang.) | Wu, Xia (Wu, Xia.) | Wang, Jinpeng (Wang, Jinpeng.)

Indexed by:

EI Scopus SCIE

Abstract:

Hybrid bimodal mesoporous silica grafted 1,8-naphthalic anhydride (NA) as a luminescent tracer was modified by Eu3+ ions, whereas the influence of the interaction between europium salts with various anions (Cl-, NO3-, and CH3COO-) and NA molecules grafted onto the mesopores on their thermal decomposition behaviors and kinetic properties were studied in detail in accordance with the thermogravimetric analyzer (TGA) profiles obtained at different heating rates under flowing N-2 atmosphere. Meanwhile, Kissinger and Flynn-Wall-Ozawa algorithms were used to calculate the apparent activation energies of Eu3+-modified NA existing in the mesoporous channels and therefore the thermal decomposition mechanism was discussed on the basis of the Coats-Redfern method. Moreover, XRD, TEM, N-2 adsorption-desorption isotherms and FT-IR techniques were employed to analyze the structural characteristics and textural properties of the resultant samples. (C) 2014 Elsevier B.V. All rights reserved.

Keyword:

Apparent activation energy Eu3+ ions 1,8-Naphthalic anhydride Thermal decomposition behavior Mesoporous silica

Author Community:

  • [ 1 ] [Wang, Feng]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Sun, Jihong]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Bai, Shiyang]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Xia]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Jinpeng]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 孙继红

    [Sun, Jihong]Beijing Univ Technol, Coll Environm & Energy Engn, 100 PingLeYuan, Beijing 100124, Peoples R China

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Source :

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS

ISSN: 0927-7757

Year: 2014

Volume: 453

Page: 142-148

5 . 2 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:258

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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