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Abstract:
Hybrid bimodal mesoporous silica grafted 1,8-naphthalic anhydride (NA) as a luminescent tracer was modified by Eu3+ ions, whereas the influence of the interaction between europium salts with various anions (Cl-, NO3-, and CH3COO-) and NA molecules grafted onto the mesopores on their thermal decomposition behaviors and kinetic properties were studied in detail in accordance with the thermogravimetric analyzer (TGA) profiles obtained at different heating rates under flowing N-2 atmosphere. Meanwhile, Kissinger and Flynn-Wall-Ozawa algorithms were used to calculate the apparent activation energies of Eu3+-modified NA existing in the mesoporous channels and therefore the thermal decomposition mechanism was discussed on the basis of the Coats-Redfern method. Moreover, XRD, TEM, N-2 adsorption-desorption isotherms and FT-IR techniques were employed to analyze the structural characteristics and textural properties of the resultant samples. (C) 2014 Elsevier B.V. All rights reserved.
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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN: 0927-7757
Year: 2014
Volume: 453
Page: 142-148
5 . 2 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
ESI HC Threshold:258
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 4
SCOPUS Cited Count: 4
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 6
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