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Author:

Sang, Lixia (Sang, Lixia.) (Scholars:桑丽霞) | Cai, Meng (Cai, Meng.) | Ren, Nan (Ren, Nan.) | Wu, Yuting (Wu, Yuting.) (Scholars:吴玉庭) | Burda, Clemens (Burda, Clemens.) | Ma, Chongfang (Ma, Chongfang.)

Indexed by:

EI Scopus SCIE

Abstract:

In order to meet the requirements of high temperature solar thermal power generation better, the melting point of mixed carbonates should be further reduced. Starting with ternary carbonates, we modified their composition ratios and added NaNO3 or NaOH as additives. Their new melting points, initial crystallization points, decomposition temperatures, specific heats and thermal stabilities were analyzed. While the melting points of the mixed nitrate/carbonate salts were maintained at 394.7 degrees C, the melting points of the mixed hydroxide/carbonate salts were reduced to 323.2 degrees C. Also the initial crystallization temperature of the mixed hydroxide/carbonate salts was dependent on their composition. Among the hydroxide-mixed molten salts, there are six samples with lower initial crystallization temperature. The decomposition temperature of the selected six samples was nearly 800 degrees C. Their specific heats were fitted with the quadratic polynomial of the temperature and their thermal stability was shown by the excellent repeatability of five heating curves. Only the very first heating curves showed that the initial measured value of a melting point was higher than all the later values of the molten salts due to starting with the powder. Furthermore, possible issues that arise with the addition of NaOH are discussed. (c) 2014 Elsevier B.V. All rights reserved.

Keyword:

Melting point Initial crystallization point Decomposition temperature Specific heat Thermal stability Mixed molten salts

Author Community:

  • [ 1 ] [Sang, Lixia]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 2 ] [Cai, Meng]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 3 ] [Ren, Nan]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Yuting]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 5 ] [Ma, Chongfang]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China
  • [ 6 ] [Sang, Lixia]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Cai, Meng]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 8 ] [Ren, Nan]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 9 ] [Wu, Yuting]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 10 ] [Ma, Chongfang]Beijing Univ Technol, Key Lab Heat Transfer & Energy Convers, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 11 ] [Burda, Clemens]Case Western Reserve Univ, Dept Chem, Ctr Chem Dynam & Nanomat Res, Cleveland, OH 44106 USA

Reprint Author's Address:

  • 桑丽霞

    [Sang, Lixia]Beijing Univ Technol, Minist Educ, Key Lab Enhanced Heat Transfer & Energy Conservat, Beijing 100124, Peoples R China

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Source :

SOLAR ENERGY MATERIALS AND SOLAR CELLS

ISSN: 0927-0248

Year: 2014

Volume: 124

Page: 61-66

6 . 9 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:341

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 36

SCOPUS Cited Count: 41

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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