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Author:

Liu, Shufeng (Liu, Shufeng.) | Zhang, Xin (Zhang, Xin.) | Yu, Yanmin (Yu, Yanmin.) | Zou, Guizheng (Zou, Guizheng.)

Indexed by:

EI Scopus SCIE

Abstract:

A promising electrochemiluminescence (ECL) sensing strategy was proposed with dual-stabilizers-capped CdSe quantum dots (QDs) as ECL emitters. The dual-stabilizers-capped CdSe QDs were covalently immobilized onto p-aminobenzoic acid modified glass carbon electrode with ethylenediamine as a link molecule. This strategy can preserve the completely passivated surface states of dual-stabilizers-capped CdSe QDs, so that the sensor demonstrated eye-visible greenish, band gap engineering and monochromatic ECL emission at 546 nm with a fwhm of 35 nm. Moreover, the proposed sensor could accurately quantify dopamine from 10.0 nM to 3.0 mu M with a detection limit of 3.0 nM in practical drug, human urine, and cerebrospinal fluid samples without any signal amplification techniques. This strategy is promising for developing ECL sensors with high sensitivity and spectral selectivity.

Keyword:

Author Community:

  • [ 1 ] [Liu, Shufeng]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
  • [ 2 ] [Zhang, Xin]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
  • [ 3 ] [Zou, Guizheng]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
  • [ 4 ] [Yu, Yanmin]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Zou, Guizheng]Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

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Source :

ANALYTICAL CHEMISTRY

ISSN: 0003-2700

Year: 2014

Issue: 5

Volume: 86

Page: 2784-2788

7 . 4 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:258

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 118

SCOPUS Cited Count: 122

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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