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Author:

Qiu, Bin (Qiu, Bin.) | Zhao, Xiuyun (Zhao, Xiuyun.) | Xia, Dingguo (Xia, Dingguo.)

Indexed by:

EI Scopus SCIE

Abstract:

This study reports a novel strategy of preparing CoS2/reduced graphene oxides (RGO) nanocomposites by employing graphene oxides (GO) as an oxidizing agent and Na2S2O3 as a reducing agent. CoS2 can be in situ synthesized with GO being reduced. X-ray diffraction (XRD), Raman spectrometry, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical test are used to characterize the nanocomposite. The CoS2 particles with the size of 150 nm are dispersed in the networks made from thin RGO nanosheets. The CoS2/RGO nanocomposite as an anode material for lithium-ion batteries can deliver excellent reversible capacity retention (640 mA hg(-1)) after cycling 50 times when tested at 100 mA g(-1) and rate performance. The enhanced electrochemical properties can be attributed to the nanoscale particles sizes of CoS2 in addition to the effects of RGO networks in preventing the agglomeration of CoS2 and absorbing lithium polysulfides during the charge-discharge processes. (C) 2013 Elsevier B.V. All rights reserved.

Keyword:

CoS2 Lithium ion batteries Anode Reduced graphene oxides

Author Community:

  • [ 1 ] [Qiu, Bin]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhao, Xiuyun]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Xia, Dingguo]Peking Univ, Coll Engn, Key Lab Theory & Technol Adv Battery Mat, Beijing 100871, Peoples R China

Reprint Author's Address:

  • 夏定国

    [Xia, Dingguo]Peking Univ, Coll Engn, Key Lab Theory & Technol Adv Battery Mat, Beijing 100871, Peoples R China

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Source :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

Year: 2013

Volume: 579

Page: 372-376

6 . 2 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 75

SCOPUS Cited Count: 78

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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