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Author:

Sandu, Viorel (Sandu, Viorel.) | Aldica, Gheorghe (Aldica, Gheorghe.) | Damian, Raluca (Damian, Raluca.) | Guo, Zhi-Chao (Guo, Zhi-Chao.) | Suo, Hong-Li (Suo, Hong-Li.) (Scholars:索红莉)

Indexed by:

EI Scopus SCIE

Abstract:

We have studied the one-step procedure for simultaneous synthesis and sintering of SiC-doped MgB2 by the spark plasma sintering technique. Two types of composition, one in which Mg is strongly deficient, with the atomic ratio , and one in which Mg content is slightly higher than the stoichiometric value, specifically , were investigated. The amount of SiC was 12 wt.% and 9 wt.%, respectively. For comparison we also studied the way the deficit of Mg can be compensated in a second process of sintering. The sample with Mg deficit shows that SiC is left almost unreacted but the results are spectacular: the highest critical temperature, 36.5 K, the highest upper critical field and the highest self-field critical current density 6.7x10(5) A/cm(2) at 10 K. In the sample with overstoichiometric Mg, SiC is decomposed, carbon diffuses within MgB2 but the critical temperature is only of 35.8 K and the zero-field critical current density is one order of magnitude lower. The compensation of the deficit of Mg in the two-step procedure is not efficient. The critical temperature is even lower, 35.8 K, the upper critical field is also lower despite SiC decomposition and C diffusion within MgB2 and the critical current density is slightly above 10(5) A/cm(2). However, at low temperatures and fields of order 7 T the sample with overstoichiometric Mg and the sample prepared by the two-step procedure have higher critical current density.

Keyword:

SiC Critical current Carbon doping Mg-vacancies Spark plasma sintering Critical fields Scaling MgB2

Author Community:

  • [ 1 ] [Sandu, Viorel]Natl Inst Mat Phys, Magurele 077125, Romania
  • [ 2 ] [Aldica, Gheorghe]Natl Inst Mat Phys, Magurele 077125, Romania
  • [ 3 ] [Damian, Raluca]Natl Inst Mat Phys, Magurele 077125, Romania
  • [ 4 ] [Guo, Zhi-Chao]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Suo, Hong-Li]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Sandu, Viorel]Natl Inst Mat Phys, Magurele 077125, Romania

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Source :

JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM

ISSN: 1557-1939

Year: 2013

Issue: 2

Volume: 26

Page: 361-369

1 . 8 0 0

JCR@2022

ESI Discipline: PHYSICS;

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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