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Author:

Wang, Heyong (Wang, Heyong.) | Chen, Zhan (Chen, Zhan.) | Hu, Jingcong (Hu, Jingcong.) | Yu, Hongling (Yu, Hongling.) | Kuang, Chaoyang (Kuang, Chaoyang.) | Qin, Jiajun (Qin, Jiajun.) | Liu, Xianjie (Liu, Xianjie.) | Lu, Yue (Lu, Yue.) (Scholars:卢岳) | Fahlman, Mats (Fahlman, Mats.) | Hou, Lintao (Hou, Lintao.) | Liu, Xiao-Ke (Liu, Xiao-Ke.) | Gao, Feng (Gao, Feng.)

Indexed by:

EI Scopus SCIE

Abstract:

Despite quick development of perovskite light-emitting diodes (PeLEDs) during the past few years, the fundamental mechanisms on how ion migration affects device efficiency and stability remain unclear. Here, it is demonstrated that the dynamic redistribution of mobile ions in the emissive layer plays a key role in the performance of PeLEDs and can explain a range of abnormal behaviours commonly observed during the device measurement. The dynamic redistribution of mobile ions changes charge-carrier injection and leads to increased recombination current; at the same time, the ion redistribution also changes charge transport and results in decreased shunt resistance current. As a result, the PeLEDs show hysteresis in external quantum efficiencies (EQEs) and radiance, that is, higher EQEs and radiance during the reverse voltage scan than during the forward scan. In addition, the changes on charge injection and transport induced by the ion redistribution also well explain the rise of the EQE/radiance values under constant driving voltages. The argument is further rationalized by adding extra formamidinium iodide (FAI) into optimized PeLEDs based on FAPbI(3), resulting in more significant hysteresis and shorter operational stability of the PeLEDs.

Keyword:

efficiency LEDs stability perovskite mobile ions

Author Community:

  • [ 1 ] [Wang, Heyong]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden
  • [ 2 ] [Chen, Zhan]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden
  • [ 3 ] [Yu, Hongling]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden
  • [ 4 ] [Kuang, Chaoyang]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden
  • [ 5 ] [Qin, Jiajun]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden
  • [ 6 ] [Liu, Xiao-Ke]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden
  • [ 7 ] [Gao, Feng]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden
  • [ 8 ] [Chen, Zhan]Jinan Univ, Dept Phys, Guangzhou Key Lab Vacuum Coating Technol & New En, Siyuan Lab, Guangzhou 510632, Peoples R China
  • [ 9 ] [Hou, Lintao]Jinan Univ, Dept Phys, Guangzhou Key Lab Vacuum Coating Technol & New En, Siyuan Lab, Guangzhou 510632, Peoples R China
  • [ 10 ] [Hu, Jingcong]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 11 ] [Lu, Yue]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 12 ] [Liu, Xianjie]Linkoping Univ, Dept Sci & Technol, Lab Organ Elect, S-60174 Norrkoping, Sweden
  • [ 13 ] [Fahlman, Mats]Linkoping Univ, Dept Sci & Technol, Lab Organ Elect, S-60174 Norrkoping, Sweden

Reprint Author's Address:

  • [Liu, Xiao-Ke]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden;;[Gao, Feng]Linkoping Univ, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2020

Issue: 8

Volume: 31

1 9 . 0 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:169

Cited Count:

WoS CC Cited Count: 34

SCOPUS Cited Count: 39

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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