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Author:

Han Zhi-Ming (Han Zhi-Ming.) | Zhang Xin (Zhang Xin.) | Lu Qing-Mei (Lu Qing-Mei.) | Zhang Jiu-Xing (Zhang Jiu-Xing.) | Zhang Fei-Peng (Zhang Fei-Peng.)

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

n-type (Mg2Si1-xSbx)(0.4)-(Mg2Sn)(0.6) (0 <= x <= 0.0625) alloys were prepared by an induction melting and spark plasma sintering method using bulks of Mn, Si, Sn, Sb as raw materials. The analyzing results of the structure and thermoelectric properties show that the single-phase (Mg2Si1-xSbx)(0.4)-(Mg2Sn)(0.6) alloys can be obtained at 8wt% excess of Mg addition. The lattice constant increases linearly with the amount of Sb, the electrical resistivity rho firstly increases and then decreases. The electrical resistivity rho of samples (x <= 0.025) shows semi-conductor behavior, while that of the samples (x>0.025) shows the metallic behavior. The Seebeck coefficient alpha firstly increases and then decreases with the increase of x value. Compared with the non-doped sample, the thermal conductivity kappa for samples (x <= 0.025) decreases and that of the other samples (x>0.025) increases. The ZT value for (Mg2Si0.95Sb0.05)(0.4)-(Mg2Sn)(0.6) sample reaches its highest value of 1.22 at 773 K, which is much higher than that of the non-doped sample.

Keyword:

Sb doping Mg2Si base thermoelectric materials thermoelectric properties spark plasma sintering

Author Community:

  • [ 1 ] [Han Zhi-Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang Xin]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Lu Qing-Mei]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang Jiu-Xing]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang Fei-Peng]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Han Zhi-Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China

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Source :

JOURNAL OF INORGANIC MATERIALS

ISSN: 1000-324X

Year: 2012

Issue: 8

Volume: 27

Page: 822-826

1 . 7 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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