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Abstract:
In the crystal structure of the title coordination polymer, {[Zn-2(C17H8O10)(C3H7NO)(2)]center dot C3H7NO}(n), the molecular building block (MBB), viz. {Zn-2(CO2)(4)(C3H7NO)(2)}, comprises two zinc atoms, each bridged by three carboxylate groups. These two Zn atoms exhibit different coordination environments: a distorted coordination intermediate between trigonal-pyramidal, and square-pyramidal formed by the two coordinated dimethylformamide molecules and three carboxylate groups, and a distorted tetrahedral coordination defined by carboxylate groups of which three are bidentate bridging and the fourth is a monodentate ligand. Thus, each ligand connects four MBBs, forming the three-dimensional polymer.
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ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
ISSN: 2056-9890
Year: 2011
Volume: 67
Page: M1406-U1018
0 . 9 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 7
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