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Author:

Xu, M. (Xu, M..) | Meng, Y. (Meng, Y..) | Cheng, Y. Q. (Cheng, Y. Q..) | Sheng, H. W. (Sheng, H. W..) | Han, X. D. (Han, X. D..) (Scholars:韩晓东) | Ma, E. (Ma, E..)

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EI Scopus SCIE

Abstract:

Using in situ x-ray diffraction, we demonstrate a pressure-induced crystallization of as-deposited amorphous Ge2Sb2Te5 (a-GST) into a body-centered-cubic (bcc) solid solution at 28 GPa, and the back transformation from the bcc-GST to a-GST. A large hysteresis loop was observed, as the bcc-GST was retained until 15 GPa. Comparisons have been made, employing the x-ray data and the structural information obtained from ab initio molecular dynamics simulations, between the as-deposited a-GST and the a-GST obtained from the pressure-induced collapse of the rocksalt GST, both at a high hydrostatic pressure (20 GPa) prior to their crystallization to bcc. The results suggest that both routes have resulted in the same high-pressure amorphous state, which explains their crystallization into bcc-GST at similar pressures. (C) 2010 American Institute of Physics. [doi:10.1063/1.3493110]

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Author Community:

  • [ 1 ] [Xu, M.]Johns Hopkins Univ, Dept Mat Sci & Engn, Baltimore, MD 21218 USA
  • [ 2 ] [Cheng, Y. Q.]Johns Hopkins Univ, Dept Mat Sci & Engn, Baltimore, MD 21218 USA
  • [ 3 ] [Ma, E.]Johns Hopkins Univ, Dept Mat Sci & Engn, Baltimore, MD 21218 USA
  • [ 4 ] [Meng, Y.]Carnegie Inst Washington, High Pressure Collaborat Access Team, Argonne, IL 60439 USA
  • [ 5 ] [Sheng, H. W.]George Mason Univ, Dept Computat & Data Sci, Fairfax, VA 22030 USA
  • [ 6 ] [Han, X. D.]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Xu, M.]Johns Hopkins Univ, Dept Mat Sci & Engn, Baltimore, MD 21218 USA

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Source :

JOURNAL OF APPLIED PHYSICS

ISSN: 0021-8979

Year: 2010

Issue: 8

Volume: 108

3 . 2 0 0

JCR@2022

ESI Discipline: PHYSICS;

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 28

SCOPUS Cited Count: 32

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 13

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