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Abstract:
A novel electrochemical sensor for the determination of formaldehyde is introduced based on electrodepositing nanostructured platinum-palladium alloy in Nafion film-coated glassy carbon electrode. Bimetallic Pt-Pd nanoparticles are found to be uniformly dispersed in Nafion film, as confirmed by scanning electron microscopic analysis. Energy dispersed X-ray analysis is used to characterize the composition of metal present in the nanoparticle-modified electrodes. The electrocatalytical behavior of the electrode is investigated by cyclic voltammetry and linear sweep voltammetry. Experimental results show that the electrode displays a remarked electrocatalytic activity for the oxidation of formaldehyde and exhibits a linear relationship in the range of 10 mu M to 1 mM, with a detection limit of 3 mu M in acidic solution. The low detection limit, wide linear range, and high sensitivity of the sensor make it valuable for further application.
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MICROCHIMICA ACTA
ISSN: 0026-3672
Year: 2009
Issue: 1-2
Volume: 164
Page: 133-138
5 . 7 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 102
SCOPUS Cited Count: 109
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 11
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