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Author:

Hanif, Muhammad Bilal (Hanif, Muhammad Bilal.) | Gao, Jiu-Tao (Gao, Jiu-Tao.) | Qayyum, Sana (Qayyum, Sana.) | Shaheen, Kausar (Shaheen, Kausar.) | Wang, Yue-Peng (Wang, Yue-Peng.) | Yasir, Muhammad (Yasir, Muhammad.) | Li, Chang-Jiu (Li, Chang-Jiu.) | Li, Cheng-Xin (Li, Cheng-Xin.)

Indexed by:

EI Scopus SCIE

Abstract:

The modified Pechini method was applied to prepare a highly active and novel cathode material La0.7Sr0.3Ti0.15Fe0.65Ni0.2O3-delta (LSTFN). This material was coated on the LGSM electrolyte through a screen-printing technique with variable thicknesses of 28 +/- 8, 41 +/- 8, and 62 +/- 8 mu m, respectively. Different fabrication parameters, including sintering temperature, time, coating thickness, and variations in ball-milling, which affect the electrochemical performance of the cathode material, were investigated. X-ray diffraction analysis of the cathode material suggested that it exhibits a cubic crystal structure with a LSTFN single phase. The morphological studies were conducted using scanning electron microscopy (SEM), which confirmed that the electrode material had a highly porous structure. Meanwhile, the electrochemical properties of the material were studied by electrochemical impedance spectroscopy (EIS), which revealed that by varying different parameters, the electrochemical performance of the electrode material was enhanced. The coated cathode materials with variable thicknesses were analyzed at different sintering temperatures and times. Experimental results suggest that the optimum sintering temperature and time were 950 degrees C and 3 h, respectively, at which LSTFN exhibits the minimum polarization resistance (R-P) of 0.046 Omega cm(2) when sintered at 800 degrees C for 3 h.

Keyword:

La0.7Sr0.3Ti0.15Fe0.65Ni0.2O3-delta (LSTFN) Sintering-temperature Coating thickness Polarization resistance

Author Community:

  • [ 1 ] [Hanif, Muhammad Bilal]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 2 ] [Gao, Jiu-Tao]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 3 ] [Wang, Yue-Peng]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 4 ] [Li, Chang-Jiu]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 5 ] [Li, Cheng-Xin]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China
  • [ 6 ] [Shaheen, Kausar]Beijing Univ Technol, Minist Educ, Key Lab Adv Funct Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Shaheen, Kausar]Univ Peshawar, Jinnah Coll Women, Dept Phys, Peshwar 25120, Khyber Pakhtunk, Pakistan
  • [ 8 ] [Hanif, Muhammad Bilal]Inst Space & Technol, Dept Mat Sci & Engn, Islamabad 44000, Pakistan
  • [ 9 ] [Yasir, Muhammad]Inst Space & Technol, Dept Mat Sci & Engn, Islamabad 44000, Pakistan
  • [ 10 ] [Qayyum, Sana]Lahore Univ Management Sci LUMS, Dept Chem & Chem Engn, Lahore, Pakistan

Reprint Author's Address:

  • [Li, Cheng-Xin]Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Shaanxi, Peoples R China

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Source :

CERAMICS INTERNATIONAL

ISSN: 0272-8842

Year: 2021

Issue: 8

Volume: 47

Page: 10893-10904

5 . 2 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:116

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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