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Author:

Karlsson, Max (Karlsson, Max.) | Yi, Ziyue (Yi, Ziyue.) | Reichert, Sebastian (Reichert, Sebastian.) | Luo, Xiyu (Luo, Xiyu.) | Lin, Weihua (Lin, Weihua.) | Zhang, Zeyu (Zhang, Zeyu.) | Bao, Chunxiong (Bao, Chunxiong.) | Zhang, Rui (Zhang, Rui.) | Bai, Sai (Bai, Sai.) | Zheng, Guanhaojie (Zheng, Guanhaojie.) | Teng, Pengpeng (Teng, Pengpeng.) | Duan, Lian (Duan, Lian.) | Lu, Yue (Lu, Yue.) | Zheng, Kaibo (Zheng, Kaibo.) | Pullerits, Tonu (Pullerits, Tonu.) | Deibel, Carsten (Deibel, Carsten.) | Xu, Weidong (Xu, Weidong.) | Friend, Richard (Friend, Richard.) | Gao, Feng (Gao, Feng.)

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Scopus SCIE PubMed

Abstract:

Bright and efficient blue emission is key to further development of metal halide perovskite light-emitting diodes. Although modifying bromide/chloride composition is straightforward to achieve blue emission, practical implementation of this strategy has been challenging due to poor colour stability and severe photoluminescence quenching. Both detrimental effects become increasingly prominent in perovskites with the high chloride content needed to produce blue emission. Here, we solve these critical challenges in mixed halide perovskites and demonstrate spectrally stable blue perovskite light-emitting diodes over a wide range of emission wavelengths from 490 to 451 nanometres. The emission colour is directly tuned by modifying the halide composition. Particularly, our blue and deep-blue light-emitting diodes based on three-dimensional perovskites show high EQE values of 11.0% and 5.5% with emission peaks at 477 and 467nm, respectively. These achievements are enabled by a vapour-assisted crystallization technique, which largely mitigates local compositional heterogeneity and ion migration. Achieving bright and efficient blue emission in metal halide perovskite light-emitting diodes has proven to be challenging. Here, the authors demonstrate high EQE and spectrally stable blue light-emitting diodes based on mixed halide perovskites, with emission from 490 to 451nm by using a vapour-assisted crystallization technique.

Keyword:

Author Community:

  • [ 1 ] [Karlsson, Max]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 2 ] [Yi, Ziyue]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 3 ] [Luo, Xiyu]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 4 ] [Bao, Chunxiong]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 5 ] [Zhang, Rui]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 6 ] [Bai, Sai]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 7 ] [Zheng, Guanhaojie]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 8 ] [Teng, Pengpeng]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 9 ] [Xu, Weidong]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 10 ] [Gao, Feng]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden
  • [ 11 ] [Yi, Ziyue]Univ Cambridge, Cavendish Lab, Cambridge, England
  • [ 12 ] [Friend, Richard]Univ Cambridge, Cavendish Lab, Cambridge, England
  • [ 13 ] [Reichert, Sebastian]Tech Univ Chemnitz, Inst Phys, Chemnitz, Germany
  • [ 14 ] [Deibel, Carsten]Tech Univ Chemnitz, Inst Phys, Chemnitz, Germany
  • [ 15 ] [Luo, Xiyu]Tsinghua Univ Beijing, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing, Peoples R China
  • [ 16 ] [Duan, Lian]Tsinghua Univ Beijing, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing, Peoples R China
  • [ 17 ] [Lin, Weihua]Lund Univ, Chem Phys & NanoLund, Box 124, S-22100 Lund, Sweden
  • [ 18 ] [Zheng, Kaibo]Lund Univ, Chem Phys & NanoLund, Box 124, S-22100 Lund, Sweden
  • [ 19 ] [Pullerits, Tonu]Lund Univ, Chem Phys & NanoLund, Box 124, S-22100 Lund, Sweden
  • [ 20 ] [Zhang, Zeyu]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 21 ] [Lu, Yue]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 22 ] [Zheng, Kaibo]Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark

Reprint Author's Address:

  • [Xu, Weidong]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden;;[Gao, Feng]Linkoping Univ, Dept Phys Chem & Biol IFM, Linkoping, Sweden

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Source :

NATURE COMMUNICATIONS

ISSN: 2041-1723

Year: 2021

Issue: 1

Volume: 12

1 6 . 6 0 0

JCR@2022

ESI Discipline: Multidisciplinary;

ESI HC Threshold:169

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 55

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 20 Unfold All

  • 2025-5
  • 2025-3
  • 2025-1
  • 2024-11
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  • 2024-9
  • 2024-9
  • 2024-7
  • 2024-5
  • 2024-3
  • 2024-1
  • 2023-11
  • 2023-9
  • 2023-7
  • 2023-5
  • 2023-3
  • 2023-1
  • 2022-11
  • 2022-9
  • 2022-7

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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