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Author:

Wang, Yongtao (Wang, Yongtao.) | Guo, Xianwei (Guo, Xianwei.) | Lin, Zhiyuan (Lin, Zhiyuan.) | Yang, Yubo (Yang, Yubo.) | Wu, Lingqiao (Wu, Lingqiao.) | Liu, Huan (Liu, Huan.) | Yu, Haijun (Yu, Haijun.) (Scholars:尉海军)

Indexed by:

Scopus SCIE CSCD

Abstract:

The sphene-type solid electrolyte with high ionic conductivity has been designed for solid-state lithium metal battery. However, the practical applications of solid electrolytes are still suffered by the low relative density and long sintering time of tens of hours with large energy consumption. Here, we introduced the spark plasma sintering technology for fabricating the sphene-type Li1.125Ta0.875Zr0.125SiO5 solid electrolyte. The dense electrolyte pellet with high relative density of ca. 97.4% and ionic conductivity of ca. 1.44x 10(-5) S/cm at 30 degrees C can be obtained by spark plasma sintering process within the extremely short time of only ca. 0.1 h. Also the solid electrolyte provides stable electrochemical window of ca. 6.0 V(vs. Li+/Li) and high electrochemical interface stability toward Li metal anode. With the enhanced interfacial contacts between electrodes and electrolyte pellet by the in-situ formed polymer electrolyte, the solid-state lithium metal battery with LiFePO4 cathode can deliver the initial discharge capacity of ca. 154 mAh/g at 0.1 C and the reversible capacity of ca. 132 mAh/g after 70 cycles with high Coulombic efficiency of 99.5% at 55 degrees C. Therefore, this study demonstrates a rapid and energy efficient sintering strategy for fabricating the solid electrolyte with dense structure and high ionic conductivity that can be practically applied in solid-state lithium metal batteries with high energy densities and safeties.

Keyword:

Sphene-type solid electrolyte Ionic conductivity Dense structure Solid-state lithium metal battery Spark plasma sintering

Author Community:

  • [ 1 ] [Wang, Yongtao]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Guo, Xianwei]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Lin, Zhiyuan]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Yang, Yubo]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Wu, Lingqiao]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China
  • [ 6 ] [Liu, Huan]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Yu, Haijun]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 尉海军

    [Guo, Xianwei]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China;;[Yu, Haijun]Beijing Univ Technol, Key Lab Adv Funct Mat, Coll Mat Sci & Engn, Minist Educ, Beijing 100124, Peoples R China

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Source :

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES

ISSN: 1005-9040

Year: 2020

Issue: 3

Volume: 36

Page: 439-446

3 . 1 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:139

Cited Count:

WoS CC Cited Count: 13

SCOPUS Cited Count: 11

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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