• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Wu, Haoqi (Wu, Haoqi.) | Qin, Changdong (Qin, Changdong.) | Wang, Kuan (Wang, Kuan.) | Han, Xiao (Han, Xiao.) | Sui, Manling (Sui, Manling.) (Scholars:隋曼龄) | Yan, Pengfei (Yan, Pengfei.) (Scholars:闫鹏飞)

Indexed by:

EI Scopus SCIE

Abstract:

Thorough understanding of intergranular cracking mechanism is essential and important for developing superior layered cathodes. As a chemomechanical failure, crack's nucleation and evolution are affected mainly by cycling protocols, but it is still lacking direct and accurate observations. Herein, we develop an experimental protocol to visualize the cracking evolution process by tracing the same secondary particles. Further combining large area cross-sectional observations, we identify two distinctive cracking mechanisms due to different state of charge (SOC). At low SOC, chronic fatigue cracking is dominant. At high SOC, particle bursting makes intergranular cracks quickly saturated during the initial cycles, causing battery rapid performance decay in the beginning. We further validate that cracks are nucleated at the end of charging process and it is the discharging that leads to high density of cracks. Managing individual secondary particle below the critical SOC to prevent particle bursting is essential for achieving high cycling stability of Ni-rich layered cathodes.

Keyword:

Layered cathode Cracking SEM Grain boundary Lithium ion battery

Author Community:

  • [ 1 ] [Wu, Haoqi]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 2 ] [Qin, Changdong]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Kuan]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 4 ] [Han, Xiao]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 5 ] [Sui, Manling]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 6 ] [Yan, Pengfei]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 隋曼龄 闫鹏飞

    [Sui, Manling]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China;;[Yan, Pengfei]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China

Show more details

Related Keywords:

Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2021

Volume: 503

9 . 2 0 0

JCR@2022

ESI Discipline: ENGINEERING;

ESI HC Threshold:87

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 24

SCOPUS Cited Count: 27

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

Online/Total:1159/10634764
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.