• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Zuo, Wen-Jing (Zuo, Wen-Jing.) | Qu, Yin-Hu (Qu, Yin-Hu.) | Qi, Pan-Hu (Qi, Pan-Hu.) | Fu, Han-Guang (Fu, Han-Guang.) (Scholars:符寒光) | Wang, Yu-Fan (Wang, Yu-Fan.) | Gao, Hao-Fei (Gao, Hao-Fei.) | Zhang, Hong (Zhang, Hong.)

Indexed by:

EI Scopus CSCD

Abstract:

Miniaturized batteries are widely utilized in microscale devices, and 3D printing technology has great advantages in the manufacture of miniaturized battery electrodes. Lithium-nickel-cobalt-manganate material (LiNi0.5Co0.2Mn0.3O2) is gradually becoming a mainstream cathode material for lithium-ion batteries due to its high energy density, high rate of performance, high stability, and low cost. In this study, we prepared lithium-ion-battery electrodes using extrusion-based three-dimensional (3D) printing technology, and we selected ternary nickel-cobalt-manganese hydride as the positive active material. Subsequently, using deionized water, hydroxyethyl cellulose, and other additives, positive inks was prepared for the lithium-ion battery that exhibited stable performance and adequate 3D printing. The effects of thickener type and content, ink viscosity, and the printing process on the rheological properties and printability of the ink were investigated using a rheometer, X-ray diffraction, a battery tester, and ANSYS simulation analysis. The results show that when the mass ratio of hydroxyethyl cellulose/hydroxypropyl cellulose is 1:1 and the mass fraction is 3%, the viscosity of the prepared ink is 20.26 Pa•s, and it shows good rheology and uniformity in printing. At present, the printing electrode has good rheology, steady ink outflow, and a smooth surface, which satisfies the printability requirements of the ink. Additionally, the simulation results show that the fluidity of the ink is significantly influenced by its viscosity. The electrode preparation process, e.g., ultrasonic dispersion, printing, or sintering, does not lead to a change in the crystal structure of the electrode material. The first-charge and discharge capacities of the electrodes are 226.5 and 119.4 mA•h•g-1, respectively. After 20 cycles, the change rates of the charge and discharge capacities in the battery decrease and then tend to become stable. Lastly, the 3D printed electrode exhibits good cycle stability. © All right reserved.

Keyword:

Nickel compounds Cobalt compounds Lithium-ion batteries 3D printers Additives Elasticity Ions Lithium compounds Deionized water Cellulose Crystal structure Viscosity Electric discharges Manganese compounds Cathodes Sintering

Author Community:

  • [ 1 ] [Zuo, Wen-Jing]School of Materials Science & Engineering, Xi'an Polytechnic University, Xi'an; 710048, China
  • [ 2 ] [Qu, Yin-Hu]School of Materials Science & Engineering, Xi'an Polytechnic University, Xi'an; 710048, China
  • [ 3 ] [Qi, Pan-Hu]School of Materials Science & Engineering, Xi'an Polytechnic University, Xi'an; 710048, China
  • [ 4 ] [Fu, Han-Guang]College of Materials Science and Engineering, Beijing University of Technology, Beijing; 100022, China
  • [ 5 ] [Wang, Yu-Fan]School of Materials Science & Engineering, Xi'an Polytechnic University, Xi'an; 710048, China
  • [ 6 ] [Gao, Hao-Fei]School of Materials Science & Engineering, Xi'an Polytechnic University, Xi'an; 710048, China
  • [ 7 ] [Zhang, Hong]School of Materials Science & Engineering, Xi'an Polytechnic University, Xi'an; 710048, China

Reprint Author's Address:

  • [qu, yin-hu]school of materials science & engineering, xi'an polytechnic university, xi'an; 710048, china

Show more details

Related Keywords:

Source :

Chinese Journal of Engineering

ISSN: 2095-9389

Year: 2020

Issue: 3

Volume: 42

Page: 358-364

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 12

Online/Total:786/10529161
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.