MOF-derived　Co3SnC0.7/Co3Sn2@NC　composites　with　heterostructure　were　successfully　prepared　in　this　work.　Typically,　with　hollow　CoSn(OH)(6)　as　the　precursor,　ZIF-67　was　coated　on　its　surface　by　controlling　Co2+　concentration　and　solvent,　and　then　carbonized　to　obtain　target　products.　During　the　calcination　process,　the　hollow　precursor　interacts　with　the　MOF　material　formed　in　situ　on　its　surface,　which　not　only　realizes　the　regulation　of　product　composition,　but　also　forms　a　heterogeneous　interface　and　an　efficient　conductive　network.　Co3SnC0.7/Co3Sn2@NC　composites　showed　excellent　sodium　storage　properties　with　the　first　discharge/charge　specific　capacity　of　767/421　mAh.g(-1)　at　a　current　density　of　100　mA.g(-1)　and　reversible　specific　capacity　of　300　mAh.g(-1)　after　100　cycles.　The　heterogeneous　interface　in　the　electrode　material　could　increase　the　active　site　of　sodium　storage　and　promote　the　diffusion　rate　of　sodium　ions.　The　N-doped　MOF-derived　carbon　layer　and　the　inactive　metal　Co　in　Co3SnC0.7/Co3Sn2@NC　not　only　improve　Na+/e(-)　conduction　rates,　but　also　disperse　the　active　material　to　prevent　agglomeration.　Our　work　provides　a　new　strategy　for　rationally　designing　the　structure　and　composition　of　energy　materials.