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Author:

Qin, Wenxuan (Qin, Wenxuan.) | Xi, Xiaoli (Xi, Xiaoli.) (Scholars:席晓丽) | Zhang, Liwen (Zhang, Liwen.) | Wang, Man (Wang, Man.) | Nie, Zuoren (Nie, Zuoren.)

Indexed by:

EI Scopus SCIE

Abstract:

The dense and smooth W-ZrO2 coating was prepared by electrodeposition on a copper substrate in Na2WO4-WO3ZrO2 melt at 1173 K. The coatings composition are alpha-W and monoclinic ZrO2, and the content of ZrO2 increased with the increase of current density. The effect of cathode current density on the morphology, microstructure and performance of the coating was investigated in this paper. The microstructure of the coating was a field-oriented texture type, including an equiaxed grain nucleation layer and a columnar grain growth layer. The roughness has the minimum value of 4.783 mu m at 30 mA/cm2, and the maximum value of 8.586 mu m at 60 mA/cm2. Then, the surface roughness dropped to 6.479 mu m at 80 mA/cm2. The surface micro-hardness increased with the current density increasing, and reached the maximum value of 482 HV at 60 mA/cm2. W-ZrO2 coated copper has excellent electrical conductivity and high temperature oxidation resistance at 30 mA/cm2, 40 mA/cm2, and 80 mA/cm2. The electrical conductivity of coatings prepared at 50 mA/cm2 and 60 mA/cm2 is slightly poorer due to their rough surface and strong preferred orientation. Overall, the texture of the composite material is the most influential factor for electrical conductivity. In summary, as the current density increases, the composition, morphology and microstructure of the coatings changes regularly, which further leads to a predictable change in performance.

Keyword:

Microstructure W-ZrO 2 coating Electrodeposition Molten salt Performance

Author Community:

  • [ 1 ] [Qin, Wenxuan]Beijing Univ Technol, Collaborat Innovat Ctr Capital Resource Recycling, Beijing 100124, Peoples R China
  • [ 2 ] [Xi, Xiaoli]Beijing Univ Technol, Collaborat Innovat Ctr Capital Resource Recycling, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Liwen]Beijing Univ Technol, Collaborat Innovat Ctr Capital Resource Recycling, Beijing 100124, Peoples R China
  • [ 4 ] [Wang, Man]Beijing Univ Technol, Collaborat Innovat Ctr Capital Resource Recycling, Beijing 100124, Peoples R China
  • [ 5 ] [Nie, Zuoren]Beijing Univ Technol, Collaborat Innovat Ctr Capital Resource Recycling, Beijing 100124, Peoples R China
  • [ 6 ] [Xi, Xiaoli]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 7 ] [Nie, Zuoren]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 8 ] [Zhang, Liwen]Beijing Univ Technol, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 9 ] [Wang, Man]Beijing Univ Technol, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China
  • [ 10 ] [Nie, Zuoren]Beijing Univ Technol, Natl Engn Lab Ind Big Data Applicat Technol, Beijing 100124, Peoples R China

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Source :

SURFACE & COATINGS TECHNOLOGY

ISSN: 0257-8972

Year: 2022

Volume: 440

5 . 4

JCR@2022

5 . 4 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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