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Abstract:
The morphological evolution and grain orientations of intermetallic compounds (IMCs) were investigated during the formation of full Cu3Sn joints at two soldering temperatures (310 and 430 degrees C). The mechanical properties of both types of full Cu3Sn joints were then analyzed. The experimental results showed that the morphology of interfacial IMCs varied significantly at two temperatures. At 310 degrees C, scallop-like Cu6Sn5 grains became larger but were fewer in number and the top of the scallops became rough due to the grain ripening effect. With the increase in the soldering temperature to 430 degrees C, Cu3Sn no longer grew uniformly as observed during soldering at 310 degrees C, but exhibited various growth rates. Furthermore, some eta-Cu6Sn5 transformed into eta'-Cu6Sn5 during cooling, and the following orientation groups between eta'-Cu6Sn5 and eta-Cu6Sn5, i.e., {102}eta' and {1120}eta, {112}eta' and {1010}eta, and {201}eta' and {0001}eta, were found to be near-parallel. The Cu3Sn grains were preferably oriented with [203] and [100] crystal orientations parallel to transverse direction (TD) at both temperatures. Noteworthy, the Cu3Sn grains with [203]//TD and [010]//ND grew much faster than those with other orientations at 430 degrees C. Moreover, molecular dynamics simulation showed that the diffusion coefficients of atoms in Cu3Sn crystals along [203] direction were significantly greater than those in other low-index crystal directions. After soldering, two types of full Cu3Sn joints obtained at different temperatures exhibited different shear strength and fracture mechanisms.
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INTERMETALLICS
ISSN: 0966-9795
Year: 2022
Volume: 145
4 . 4
JCR@2022
4 . 4 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:66
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 17
SCOPUS Cited Count: 18
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 6
Affiliated Colleges: