Chlorinated　volatile　organic　compounds　(CVOCs),　even　in　small　quantities,　can　cause　Pt-based　catalyst　poisoning.　Improving　the　low-temperature　chlorine　resistance　of　catalysts　is　of　vital　importance　for　industrial　application,　although　it　remains　challenging.　Considering　actual　industrial　production,　a　TiO2-supported　ternary　metal　catalyst　was　prepared　in　this　work　to　study　the　catalytic　oxidation　of　multicomponent　VOCs　(toluene　and　trichloroethylene　(TCE)).　Among　all　of　the　samples,　PtWRu/TiO2　and　PtWCr/TiO2　exhibited　the　best　catalytic　performance　for　toluene　oxidation.　In　the　mixed　VOC　oxidation,　the　PtWCr/TiO2　sample　showed　the　best　catalytic　activity　for　toluene　combustion　(a　toluene　conversion　of　90%　was　achieved　at　258　degrees　C　and　a　space　velocity　of　40,000　mL　g(-1)　h(-1),　and　the　specific　reaction　rate　and　turnover　frequency　at　215　degrees　C　were　44.9　x　10(-6)　mol　g(Pt)(-1)　s(-1)　and　26.2　x　10(-5)　s(-1)).　The　PtWRu/TiO2　sample　showed　the　best　catalytic　activity　for　TCE　combustion　(a　TCE　conversion　of　90%　was　achieved　at　305　degrees　C　and　a　space　velocity　of　40,000　mL　g(-1)　h(-1),　and　the　specific　reaction　rate　and　turnover　frequency　at　270　degrees　C　were　9.0　x　10(-6)　mol　g(Pt)(-1)　s(-1)　and　7.3　x　10(-5)　s(-1)).　We　concluded　that　the　ternary　metal　catalysts　could　greatly　improve　chlorine　desorption　by　increasing　the　active　lattice　oxygen　mobility　and　surface　acidity,　thus　reducing　chlorinated　byproducts　and　other　serious　environmental　pollutants.　This　work　may　serve　as　a　reasonable　design　reference　for　solving　more　practical　industrial　production　emissions　of　multicomponent　VOCs.